• 한국언어정보학회지:언어와정보
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• 제15권2호
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• pp.1-21
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• 2011

Of the coordination structures in Korean, the symmetric and asymmetric properties of verbal coordination have challenged both theoretical and computational approaches. This paper shows how a typed feature structure grammar, HPSG, together with the notions of 'type hierarchy' and 'constructions', can provide a robust basis for parsing (un)tensed verbal coordination as well as pseudo-coordination found in the language. We show that the analysis sketched here and computationally implemented in the existing resource grammar for Korean, Korean Resource Grammar (KRG), can yield proper syntactic structures as well as enriched semantic representations for real-time applications such as machine translation.

• International Journal of Quality Innovation
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• 제2권2호
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• pp.121-126
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• 2001

Based on the creative education theory, the study of the symmetric coordinated use of both hands is the application of both the quality education ideal and the understanding principles of the creative education to the training of using hands. In the light of relevant concepts of the 'Domain' theory and the expertise of both the Chinese and foreign specialists in this field, this article discusses the relation between the tapping of mental creativity, scientific use of hands and the animation of the right hemisphere of the brain with the aim of constructing a new concept of the symmetric coordinated use of both hands.

• 영어어문교육
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• 제9권2호
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• pp.173-192
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• 2003

The purpose of this paper is to analyze the semantic ambiguity of coordination connected by 'and' in English and show a clear explanation for the meaning of the sentence. Two sentences which are connected by 'and' can be divided into the symmetric conjunction and the asymmetric conjunction according to its meaning. Especially, in order to explain the different meaning in the asymmetric conjunctions, we introduce the theory of presupposition and entailment, which provides the solution to the ambiguity in meaning. It can be said that presupposition and entailment can logically explain the meaning of natural language.

• 한국통신학회논문지
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• 제36권4A호
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• pp.318-324
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• 2011

본 논문에서는 두 셀 대칭적 간섭 채널 환경에서 세 가지 방식의 협력적 불규칙 빔형성 방법을 분석한다. 먼저, 기지국 선택을 통한 간단한 형태의 부분 협력 빔형성 방법은 연계적 인코딩을 적용한 불규칙 빔형성 방법과 동일한 평균 합 전송률을 갖는다는 것을 증명한다. 또한, 전송 모드 선택 방법을 적용하는 경우에 시스템의 사용자가 많을 때에 부가적인 합 전송율의 이득이 발생하는 것을 증명하였다. 모의 실험 결과를 통해서 성능에 대한 분석이 유효함과 정확성을 확인하였다.

• Macromolecular Research
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• 제14권2호
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• pp.199-204
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• 2006

Remarkably high and stable separation performance for olefin/paraffin mixtures was previously reported by facilitated olefin transport through ${\pi}$-complex membranes consisting of silver ions dissolved in poly(hexamethylenevinylene) (PHMV). In this study, the ${\pi}$-complex formation of $AgBF_4,\;AgClO_4\;and\;AgCF_{3}SO_3$ with PHMV and their ionic interactions were investigated. FT-Raman spectroscopy showed that the C=C stretching bands of PHMV shifted to a lower frequency upon incorporation of silver salt, but the degree of peak shift depended on the counter-anions of salt due to different complexation strengths. The symmetric stretching modes of anions indicated the presence of only free ions up to [C=C]:[Ag]=1:1, demonstrating the unusually high solubility of silver salt in PHMV. Above the solubility limit, the ion pairs and higher-order ionic aggregates started to form. The coordination number of silver ion for C=C of PHMV was in the order $AgBF_4$ > $AgClO_4$ > $AgCF_{3}SO_3$, but became similar at [C=C]:[Ag]=1:1. The different coordination number was interpreted in terms of the different transient crosslinks of silver cations in the complex, which may be related to both the interaction strength of the polymer/silver ion and the bulkiness of the counteranion.

• Bulletin of the Korean Chemical Society
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• 제31권9호
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• pp.2598-2602
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• 2010

Two 3-D zinc framework compounds, $[Zn_6(BTB)_4(4,4'-bipy)_4(H_2O)_4]{\cdot}9H_2O$ (1) and $[Zn_3(BTB)_2(4,4'-bipy)_2(H_2O)_2]{\cdot}5H_2O$ (2) ($H_3BTB$ = 1,2,3-benzenetricarboxylic acid, 4,4'-bipy = 4,4'-bipyridine), are obtained from the diffusion method and hydrothermal reaction respectively. Though 1 and 2 has the same coordination geometries of zinc atoms and coordination mode of $BTB^{3-}$, their 2-D layers are different: mirror symmetric layers in 1; parallel ones in 2, further connecting by 4,4'-bipy into 3-D frameworks. The hydrothermal reaction of 2 results in a more stable 3-D framework than the one in 1, which is supported by the single point energy calculations. 1 and 2 show similar blue fluorescence at 417 nm, which can be assigned to LMCT.

• Bulletin of the Korean Chemical Society
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• 제30권4호
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• pp.803-809
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• 2009

Notable blue shifts of the ν2 $C{\equiv}N$ stretching, $_{v4}$ C-C stretching and $_{v8}$ CCN deformation bands of $CD_3CN$ are observed upon solvation of $InCl_3$, resulting from the donor-acceptor interaction. The Raman spectrum in the $_{v2}$ region shows further details; at least two new bands emerge on the blue side of the $_{v2}$ band of free $CD_3CN$, whose relative intensities vary with concentration, suggesting that there exist at least two different cationic species in the solution. The strong hydrogen bonds formed between the methyl group and ${InCl_4}^-$ result in a large band appearing on the red side of the ν1 $CD_3$ symmetric stretching band. The solvation number of $InCl_3$, determined from the Raman intensities of the $C{\equiv}N$ stretching bands for free and coordinated $CD_3CN$, increases from $\sim$1.5 to $\sim$1.8 with decreasing concentration.

• Bulletin of the Korean Chemical Society
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• 제29권2호
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• pp.499-502
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• 2008

• Elastomers and Composites
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• 제55권4호
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• pp.263-269
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• 2020

Novel flexible terpolymers with a reactive moiety were synthesized by coordination polymerization with a metallocene catalyst and a cocatalyst system. C2-symmetric rac-Et(Ind)2ZrCl2 and tri-iso-butylaluminum/dimethylanilinium tetrakis (pentafluorophenyl) borate were employed as the catalyst and cocatalyst, respectively. We synthesized reactive terpolymers consisting of ethylene, a high α-olefin content (1-hexene, 1-octene, 1-decene, and 1-dodecene), and divinylbenzene. The structure and composition of the terpolymers were characterized by 1H-nuclear magnetic resonance analysis. The catalytic activity, polymer yield, molecular weight, and molecular weight distribution were measured as functions of the chain length and high content of α-olefins. Furthermore, the thermal properties and crystallinity of the terpolymers were determined by differential scanning calorimetry and wide-angle X-ray scattering.

• Elastomers and Composites
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• 제48권1호
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• pp.2-9
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• 2013

rac-$Et(Ind)_2ZrCl_2$ 메탈로센 촉매와 메틸알루미늄옥산 공촉매를 이용하여 polyethylene, poly(ethylene-co-1-decene), poly(ethylene-co-p-methylstyrene) 및 poly(ethylene-ter-1-decene-ter-p-methystyrene)를 합성하였다. $^{13}C$ NMR과 $^1H$ NMR 및 FT-IR을 이용하여 삼원공중합체의 특성을 분석하였다. 삼원공중합의 최적조건을 확립하기 위해 동일한 중합조건을 유지한 채 촉매량, 공촉매/촉매 몰비, 중합 시간 및 중합 온도를 변경하여 실험하였다. 촉매량이 증가할수록 삼원공중합체의 촉매활성도 및 중량평균분자량은 증가하였으나, 중합시간이 30분을 초과하자 촉매활성도는 감소하였다. 공촉매/촉매 몰비를 증가시킨 결과 중량평균분자량은 감소하였고, 촉매활성도는 어느 정도 증가하였다. 촉매활성도는 중합온도가 증가함에 따라 상승하였으나 중량평균 분자량은 감소하였다.