Browse > Article
http://dx.doi.org/10.5012/bkcs.2010.31.9.2598

Two Novel 3-D Zinc Compounds with Mixture Ligands of H3BTB and 4,4'-Bipy: Crystal Structures, Blue Fluorescence and Single Point Energy Calculation  

Zhang, Xiu-Cheng (College of Science, Northeast Forestry University)
Xu, Ling (Department of Chemistry, Sungkyunkwan University)
Liu, Wen-Guang (College of Science, Northeast Forestry University)
Liu, Bing (Department of Chemistry, University of Aveiro, CICECO, Campus Universitario de Santiago)
Publication Information
Bulletin of the Korean Chemical Society / v.31, no.9, 2010 , pp. 2598-2602 More about this Journal
Abstract
Two 3-D zinc framework compounds, $[Zn_6(BTB)_4(4,4 (1) and $[Zn_3(BTB)_2(4,4 (2) ($H_3BTB$ = 1,2,3-benzenetricarboxylic acid, 4,4'-bipy = 4,4'-bipyridine), are obtained from the diffusion method and hydrothermal reaction respectively. Though 1 and 2 has the same coordination geometries of zinc atoms and coordination mode of $BTB^{3-}$, their 2-D layers are different: mirror symmetric layers in 1; parallel ones in 2, further connecting by 4,4'-bipy into 3-D frameworks. The hydrothermal reaction of 2 results in a more stable 3-D framework than the one in 1, which is supported by the single point energy calculations. 1 and 2 show similar blue fluorescence at 417 nm, which can be assigned to LMCT.
Keywords
1,2,3-Benzenetricarboxylic acid; Crystal structure; Fluorescence; Single point energy calculation;
Citations & Related Records

Times Cited By Web Of Science : 1  (Related Records In Web of Science)
Times Cited By SCOPUS : 2
연도 인용수 순위
1 Brown, I. D.; Altermatt, D. Acta Crystallogr., Sect. B 1985, 41, 244.   DOI
2 Spek, A. L. Acta Crystallogr. 1990, A46, C43.
3 Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 270.   DOI
4 Lu, J. Y. Coord. Chem. Rev. 2003, 246, 327.   DOI
5 Leininger, S.; Olenyuk, B.; Stang, P. J. Chem. Rev. 2000, 100, 853.   DOI
6 Melanie, A. P.; Darren, W. J. Chem. Soc. Rev. 2007, 36, 1441.   DOI
7 Fruhauf, H. W. Chem. Rev. 1997, 97, 523.   DOI
8 Fujita, M.; Tominag, A. M.; Hori, A.; Therrien, B. Acc. Chem. Res. 2005, 38, 371.
9 Streubel, R.; Bode, M.; Frantzius, G. V.; Hrib, C.; Jones, P. G.; Monsees, A. Organometallics 2007, 26, 1371.   DOI
10 Carlucci, L.; Ciani, G.; Proserpio, D. M. Coord. Chem. Rev. 2003, 246, 247.   DOI   ScienceOn
11 Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem. Int. Ed. 1999, 38, 2638.   DOI
12 Fujita, M. Acc. Chem. Res. 1998, 32, 53.   DOI
13 Ye, B. H.; Tong, M. L.; Chen, X. M. Coord. Chem. Rev. 2005, 249, 545.   DOI
14 Liu, G. X.; Zhu, K.; Chen, H.; Huang, R. Y.; Ren, X. M. Cryst. Eng. Comm. 2008, 10, 1527.   DOI
15 Chui, S. S. Y.; Lo, S. M.; Charmant, J. P. H.; Orpen, A. G.; Williams, I. D. Science 1999, 283, 1148.   DOI   ScienceOn
16 Suh, M. P.; Ko, J. W.; Choi, H. J. J. Am. Chem. Soc. 2002, 124 10976.   DOI
17 Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Montgomery, J. A.; Vreven, J. T.; Kudin, K. N.; Burant, J. C.; Millam, J. M.; Iyengar, S. S.; Tomasi, J.; Barone, V.; Mennucci, B.; Cossi, M.; Scalmani, G.; Rega, N.; Petersson, G. A.; Nakatsuji, H.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Klene, M.; Li, X.; Knox, J. E.; Hratchian, H. P.; Cross, J. B.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Ayala, P. Y.; Morokuma, K.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Zakrzewski, V. G.; Dapprich, S.; Daniels, A. D.; Strain, M. C.; Farkas, O.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Ortiz, J. V.; Cui, Q.; Baboul, A. G.; Clifford, S.; Cioslowski, J.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Challacombe, M.; Gill, P. M. W.; Johnson, B.; Chen, W.; Wong, M. W.; Gonzalez, C.; Pople, J. A. Gaussian, Inc., Pittsburgh PA, 2003.
18 Meijerink, A.; Blasse, G.; Glasbeek, M. J. Phys. Condense. Matter. 1990, 2, 6303.   DOI
19 Bertoncello, R.; Bettinelli, M.; Casarin, M.; Gulino, A.; Tondello, E.; Vittadini, A. Inorg. Chem. 1992, 31, 1558.   DOI
20 Pan, L.; Woodlock, E. B.; Wang, X. T.; Zheng, C. Inorg. Chem. 2000, 39, 4174.   DOI
21 Hu, J. Y.; Li, J. P.; Zhao, J. A.; Hou, H. W.; Fan, Y. T. Inorg. Chem. Acta 2009, 362, 5023.   DOI
22 Luo, G. G.; Sun, D.; Zhang, N.; Xu, Q. J.; Lin, L. R.; Huang, R. B.; Zheng, L. S. Inorg. Chem. Commun. 2010, 13, 10.   DOI
23 Fu, Y.; Su, J.; Yang, S. H.; Li, G. B.; Liao, F. H.; Xiong, M.; Lin, J. H. Inorg. Chem. Acta 2010, 363, 645.   DOI
24 Gutschke, S. O. H.; Price, D. J.; Powell, A. K.; Wood, P. T. Angew. Chem., Int. Ed. Engl. 2001, 40, 1920.   DOI
25 Zheng, Y. Z.; Tong, M. L.; Chen, X. M. New. J. Chem. 2004, 28, 1412.   DOI   ScienceOn
26 Xu, L.; Liu, B.; Guo, G. C.; Shun, J. S. Inorg. Chem. Commun. 2006, 9, 220.   DOI
27 Zhang, Z. J.; Liu, H. Y.; Zhang, S. Y.; Shi, W.; Cheng, P. Inorg. Chem. Commun. 2009, 12, 223.   DOI
28 Zheng, Y. Z.; Zhang, Y. B.; Tong, M. L.; Xue, W.; Chen, X. M. Dalton Trans. 2009, 1396.
29 Liu, B.; Xu, L. Inorg. Chem. Commun. 2006, 9, 364.   DOI
30 Rigaku, CrystalClear 1.3.6, Software User's Guide for the Rigaku. R-Axis, Mercury and Jupiter CCD Automated X-ray Imaging System. Rigaku Molecular Structure Corporation, 2002, Utah, USA.
31 Siemens, SHELXTLTM Version 5 Reference Manual, Siemens Engergy & Automation Inc. Madison, Wisconsin, 1994, USA.
32 Yaghi, O. M.; Li, G. M.; Li, H. L. Nature 1995, 378, 703.   DOI
33 Prior, T. J.; Rosseinsky, M. j. Inorg. Chem. 2003, 42, 1564.   DOI
34 Cotton, F. A.; Lin, C.; Murillo, C. A. Inorg. Chem. 2001, 40, 6413.   DOI
35 Dimos, A.; Michaelides, A.; Skoulika, S. Chem. Mater. 2000, 12, 3256.   DOI