• Title/Summary/Keyword: Swelling effect

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Effect of Water-Soluble Carriers on Water-Absorption and Swelling of Polydimethylsiloxane-5-Fluorouracil Devices

  • O, Sung-Il;Lee, Chi-Young;Kim, Sung-Ho
    • Journal of Pharmaceutical Investigation
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    • v.16 no.3
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    • pp.101-105
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    • 1986
  • The changes of water absorption and surface area of polydimethylsiloxane-5-fluorouracil devices containing different water soluble additives such as sodium chloride, glycerine, poly-propylene glycol(PPG 400), and polyethylene oxide(PEO 400, 400 and 2000) were investigated. It was confirmed that carriers controlled water absorption and swelling of the devices in the aqueous solutions. The water absorption and the swelling were affected by the osmotic pressure and ionic strength of the aqueous solutions.

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Analysis of highway reflection noise reduction using transparent noise barrier types

  • Lee, Jaiyeop;Kim, Ilho;Chang, Seoil
    • Environmental Engineering Research
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    • v.20 no.4
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    • pp.383-391
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    • 2015
  • Transparent type noise barrier is a desirable facility since it provides a secure view to drivers and passengers. However, reflection from this type of barrier could annoy dwellers on the sides of the road. To reduce reflection noise by transparent type barrier, modification can be made to the shapes on the front side and hence get effects by distortion of sound transmission. To achieve this, we have conducted simulation by which the effects of patterned screens of noise barrier on high-ways were investigated. The reduction effects of reflected sounds were evaluated for swelling, swelling with curved, rectangular and V-shaped screen type barriers, compared to the planar panel. The emitting noise was generated by 6-lane road and the patterned noise barriers had shown the reduction effects, especially in swelling and swelling with curved type for middle height dwellers, and the V-shaped screen type for higher elevation dweller. The swelling-type showed a decrease of 0.7~1.2 dB, performing the best diminution effect among the tested noise barriers.

Influence of Nanodispersed Organoclay on Rheological and Swelling Properties of Ethylene Propylene Diene Terpolymer

  • Acharya Himadri;Srivastava Suneel K.
    • Macromolecular Research
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    • v.14 no.2
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    • pp.132-139
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    • 2006
  • The dispersion of organoclay in ethylene propylene diene terpolymer (EPDM) matrix was correlated with the rheological and swelling properties of nanocomposites. X-ray diffraction pattern (XRD) and transmission electron microscopic (TEM) analysis exhibited the disordered-intercalated structure of EPDM/organoclay nanocomposite. The extent of the disordered phase increased with increasing organoclay content up to a limiting value of 3 wt% after which equilibrium tended towards intercalation. The dispersion effect of organoclay in EPDM matrix was clarified by the physicochemical properties like rheological response and swelling thermodynamics in toluene. The increase in viscoelastic properties of EPDM nanocomposite with increasing organoclay content up to 3 wt%, followed by a subsequent decrease up to 4 wt%, was correlated in terms of the disordered and ordered states of the dispersed nano-clay sheets. Swelling measurements revealed that the change in entropy of the swelling increased with the increase in disorder level but decreased with the increase in intercalation level of organoclay in the disordered-intercalated nanocomposite. The increase in solvent uptake was comparable with the free volume in EPDM matrix upon inclusion of silicate particles, whereas the inhibition in solvent uptake for higher organoclay loading was described by bridging flocculation.

The Effects of Cryotherapy Treatment with Leg Elevation on Swelling of Patient Who had an TKA (슬관절 전치환술(TKA) 환자를 대상으로 다리거상과 냉치료 적용이 부종에 미치는 영향)

  • Lee, Jae-hong;Lee, Jin-hwan;Min, Dong-ki;Lee, Jae-kwang;Kim, Jong-woo
    • The Journal of Korean Academy of Orthopedic Manual Physical Therapy
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    • v.23 no.2
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    • pp.45-49
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    • 2017
  • Background: The purpose of this study was to investigate the effect of structured cryotherapy on edema of patients who had a total knee arthroplasty (TKA). Methods: The subjects were 58 patients who were diagnosed with osteoarthritis and had total knee arthroplasty in D hospital. In total, 29 people were in the leg elevation cryotherapy group (LECTG), 29 people were in the control group (CTG). After TKA, the patients' swelling on post operation days (POD) 3 were checked. After the post OP checking, LECTG was treated with cryotherapy with leg elevation for 12 days but CTG was cryo therapy with sit on chair. Results: Swelling show significant difference within the group (p<.05), but did not show signigicant difference between groups (p>.05). Conclusions: Base on the results, it was found the cryo therapy of $-78^{\circ}C$ improved swelling after TKA. Accordingly, it is thought that cryo therapy of $-78^{\circ}C$ has positive effect on swelling in the process of recovery after operation. but It did not approve that the leg elevation was even more effective. For this study, the reserch developed to enhance the effectiveness of the cryotherapy, would make it possible to apply to an effective cryotherapy posture.

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Noninvasive study of the swelling effect for biopolymers using NMR Microimaging (핵자기공명 현미영상법을 이용한 생체고분자의 팽윤현상에 대한 비파괴연구)

  • Lee, D.H.;Ko, R.K.;Cho, Z.H.;Kim, S.S.
    • Proceedings of the KOSOMBE Conference
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    • v.1995 no.05
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    • pp.223-226
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    • 1995
  • Polymers have been developed and applied in many biomedical areas as well as engineering and industrial fields. The first essential to achieve successful development and applications is that properties of such polymer materials would be investigated. In many cases, such investigations are accomplished by observing polymeric behavior arising from the environmental changes such as pH, temperature, and ionic concentration. It has long been known that NMR is extremely sensitive to many biochemical and physical changes occurring in the polymer samples. In the present study we focus our study on NMR Microimaging, which is one of the important NMR applications, to characterize the swelling effect by observing the time dependent spatial variations of polymer specimens. For the samples three kinds of polyvinyl alcohol (PVA) specimens are prepared with different degrees of cross linking density. $^1H$ NMR microimages are acquired as a function of time to visualize the swelling behavior as well as volumetric changes occurring in the specimens. From the acquired time dependent images, the swelling process is exploited.

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Numerical Simulations of the Moisture Movement in Unsaturated Bentonite Under a Thermal Gradient

  • Park, J.W.;K. Chang;Kim, C.L.
    • Nuclear Engineering and Technology
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    • v.33 no.1
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    • pp.62-72
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    • 2001
  • The one-dimensional finite element program was developed to analyze the coupled behavior of heat, moisture, and air transfer in unsaturated porous media. By using this program, the simulation results were compared with those from the laboratory infiltration tests under isothermal condition and temperature gradient condition, respectively. The discrepancy of water uptake was found in the upper region of a bentonite sample under isothermal condition between numerical simulation and laboratory experiment. This indicated that air pressure was built up in the bentonite sample which could retard the infiltration velocity of liquid. In order to consider the swelling phenomena of compacted bentonite which cause the discrepancy of the distribution of water content and temperature, swelling and shrinkage factors were incorporated into the finite element formulation. It was found that these factors could be effective to represent the moisture diffusivity and unsaturated hydraulic conductivity due to volume change of bentonite sample.

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Investigation on effect of neutron irradiation on welding residual stresses in core shroud of pressurized water reactor

  • Jong-Sung Kim;Young-Chan Kim;Wan Yoo
    • Nuclear Engineering and Technology
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    • v.55 no.1
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    • pp.80-99
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    • 2023
  • This paper presents the results of investigating the change in welding residual stresses of the core shroud, which is one of subcomponents in reactor vessel internals, performing finite element analysis. First, the welding residual stresses of the core shroud were calculated by applying the heat conduction based lumped pass technique and finite element elastic-plastic stress analysis. Second, the temperature distribution of the core shroud during the normal operation was calculated by performing finite element temperature analysis considering gamma heating. Third, through the finite element viscoelastic-plastic stress analysis using the calculated temperature distribution and setting the calculated residual stresses as the initial stress state, the variation of the welding residual stresses was derived according to repeating the normal operation. In the viscoelastic-plastic stress analysis, the effects of neutron irradiation on mechanical properties during the cyclic normal operations were considered by using the previously developed user subroutines for the irradiation agings such as irradiation hardening/embrittlement, irradiation-induced creep, and void swelling. Finally, the effect of neutron irradiation on the welding residual stresses was analysed for each irradiation aging. As a result, it is found that as the normal operation is repeated, the welding residual stresses decrease and show insignificant magnitudes after the 10th refueling cycle. In addition, the irradiation-induced creep/void swelling has significant mitigation effect on the residual stresses whereas the irradiation hardening/embrittlement has no effect on those.

Partially Hydrolyzed Crosslinked Alginate-graft-Polymethacrylamide as a Novel Biopolymer-Based Superabsorbent Hydrogel Having pH - Responsive Properties

  • Pourjavadi A.;Amini-Fazi M. S.;Hosseinzadeh H.
    • Macromolecular Research
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    • v.13 no.1
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    • pp.45-53
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    • 2005
  • In this study, a series of highly swelling hydrogels based on sodium alginate (NaAlg) and polymethacryl­amide (PMAM) was prepared through free radical polymerization. The graft copolymerization reaction was performed in a homogeneous medium and in the presence of ammonium persulfate (APS) as an initiator and N,N'-methylenebis­acrylamide (MBA) as a crosslinker. The crosslinked graft copolymer, alginate-graft-polymethacrylamide (Alg-g­PMAM), was then partially hydrolyzed by NaOH solution to yield a hydrogel, hydrolyzed alginate-graft-poly­methacrylamide (H-Alg-g-PMAM). During alkaline hydrolysis, the carboxamide groups of Alg-g-PMAM were converted into hydrophilic carboxylate anions. Either the Alg-g-PMAM or the H-Alg-g-PMAM was characterized by FTIR spectroscopy. The effects of the grafting variables (i.e., concentration of MBA, MAM, and APS) and the alkaline hydrolysis conditions (i.e., NaOH concentration, hydrolysis time, and temperature) were optimized systematically to achieve a hydrogel having the maximum swelling capacity. Measurements of the absorbency in various aqueous salt solutions indicated that the swelling capacity decreased upon increasing the ionic strength of the swelling medium. This behavior could be attributed to a charge screening effect for monovalent cations, as well as ionic cross-linking for multivalent cations. Because of the high swelling capacity in salt solutions, however, the hydrogels might be considered as anti-salt superabsorbents. The swelling behavior of the superabsorbing hydrogels was also measured in solutions having values of pH ranging from 1 to 13. Furthermore, the pH reversibility and on/off switching behavior, measured at pH 2.0 and 8.0, suggested that the synthesized hydrogels were excellent candidates for the controlled delivery of bioactive agents. Finally, we performed preliminary investigations of the swelling kinetics of the synthesized hydrogels at various particle sizes.

pH-Sensitive Dynamic Swelling Behavior of Glucose-containing Anionic Hydrogels (글루코스를 함유한 음이온 하이드로젤의 pH 감응성 동적 팽윤거동)

  • Kim, Bumsang
    • Korean Chemical Engineering Research
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    • v.43 no.2
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    • pp.299-304
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    • 2005
  • There have been many efforts to use anionic hydrogels as oral protein delivery carriers due to their pH-responsive swelling behavior. The dynamic swelling behavior of poly(methacrylic acid-co-methacryloxyethyl glucoside) [P(MAA-co-MEG)] hydrogels was investigated to determine the mechanism of water transport through these anionic hydrogels. The exponential relation $M_t/M_{\infty}=kt^n$ was used to calculate the exponent, n, describing the Fickian or non-Fickian behavior of swelling polymer networks. The mechanism of water transport through these gels was significantly affected by the pH of the swelling medium. The mechanism of water transport became more relaxation-controlled in the swelling medium of pH 7.0 that was higher than the $pK_a$ of the gels. Experimental results of time-dependent swelling behavior of the gels were analyzed with several mathematical models. Using ATR-FTIR spectroscopy, the effect of ionization of the carboxylic acid groups in the polymer networks on the water transport mechanism was investigated.

Lyotropic Mesomorphisms of a Lamellar Liquid Crystalline Phase in Non-hydrous Condition: A Phospholipid Hydrated by Different Polar Solvents

  • Lee, Dong-Kyu;Jeong, Kwan-Young
    • Bulletin of the Korean Chemical Society
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    • v.31 no.5
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    • pp.1165-1171
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    • 2010
  • The lyotropic mesomorphism of lamellar liquid crystalline phase was examined by observing the swelling behavior of Distearoylphosphatidylcholine(DSPC) in glycerin and panthenol without water. The lyotropic mesomorphism was examined by using DSC, XRDs and Cryo-SEM. Increase of two polar solvents under non-hydrous condition showed distinctive differences in the lyotropic mesomorphism from forming different anisotropic structures with DSPC. Glycerin did not affect to the crystalline region of lamellar phase, whereas typical swelling mesomorphism was shown in the noncrystalline region. In contrast, panthenol showed some effect on the crystalline region, but common swelling mesomorphism was found in the non-crystalline region. In this case, the isopropyl and propyl groups in panthenol were the main factor to affect to the lipophilic domain in the crystalline region of lamellar phase. Also, it was found that the formation of well-arranged lamellar structure only by introducing glycerin and panthenol as a solvent without water, was possible. These results were confirmed by examination of the swelling mesomorphism of liquid crystal membrane triggered by introducing the two polar solvents.