• Title/Summary/Keyword: Swelling behavior

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Prediction of Long-term Behavior of Tunnel in the Presence of Geological Anomalies (지질이상대가 존재하는 구간에서의 터널의 장기거동 예측)

  • Hoki Ban;Heesu Kim;Jungkuk Kim;Donggyou Kim
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.8
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    • pp.13-20
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    • 2023
  • Tunnelling through the geological anomalies has widely known to have many difficulties such as bottom heave, crack of lining, squeezing and so on. To stabilize the tunnel during the construction or after construction, various reinforcing methods have been introduced and applied such as micropiling at the bottom of tunnel to prevent the bottom heave. In this study, long-term behavior of tunnel in the presence of geological anomalies was predicted using numerical analyses. To this end, material properties for swelling rock model capable of representing the rock swelling behavior was obtained using matching process with measured data to validate the adopted model. After the model validation, simulations were performed to predict the long-term behavior of tunnel in the geological anomalies.

Influence of the Type of Curing Agent on Swelling Behavior of Natural Rubber Foam (가교제의 종류가 천연고무 발포체의 팽윤거동에 미치는 효과)

  • Lee, Hwan-Kwang;Chung, Tea-Kyung;Kim, Sung-Chan;Kim, Hyun-Gi;Choi, Kyung-Man;Kim, Young-Min;Han, Dong-Hun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.6
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    • pp.1775-1781
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    • 2008
  • The effects of the type of curing agent on the swelling of the natural rubber(NR) sponge applicable to the self-sealing layer of a helicopter fuel tank were investigated. The curing systems employed were peroxide and mixed ones of sulfur and peroxide. The NR compounds were prepared in a kneader and a roll-mill. The compounds were partially cured in a press at high pressure and subsequently cured fully with expansion in another press at atmospheric pressure. The apparent density of the NR sponge was measured and the cell structure was observed with scanning electron microscopy. The swelling experiments were performed at room temperature using toluene, iso-octane, and an aircraft fuel as a solvent. More rapid volume swelling of the NR sponge cured by peroxide was achieved than cured by sulfur and peroxide with similar amount of curing agent added in rubber compounds. The apparent density and cell structure of the sponge were extremely sensitive to the amount of peroxide, which influences again the swelling behavior of the NR sponge. It is important to control properly two reactions of decomposition of foaming agent and crosslinking of NR in the mold to obtain rapid swelling of the NR sponge on contact of the fuel.

AN ANALYSIS OF THE THERMAL AND MECHANICAL BEHAVIOR OF ENGINEERED BARRIERS IN A HIGH-LEVEL RADIOACTIVE WASTE REPOSITORY

  • Kwon, S.;Cho, W.J.;Lee, J.O.
    • Nuclear Engineering and Technology
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    • v.45 no.1
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    • pp.41-52
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    • 2013
  • Adequate design of engineered barriers, including canister, buffer and backfill, is important for the safe disposal of high-level radioactive waste. Three-dimensional computer simulations were carried out under different condition to examine the thermal and mechanical behavior of engineered barriers and rock mass. The research looked at five areas of importance, the effect of the swelling pressure, water content of buffer, density of compacted bentonite, emplacement type and the selection of failure criteria. The results highlighted the need to consider tensile stress in the outer shell of a canister due to thermal expansion of the canister and the swelling pressure from the buffer for a more reliable design of an underground repository system. In addition, an adequate failure criterion should be used for the buffer and backfill.

A novel hydrogel-dispersed composite membrane of poly(N-isopropylacrylamide) in gelatin matrix and its thermally actuated permeation of 4-acetamidophen

  • Chun, Suk-Won;Kim, Jong-Duk
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.04a
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    • pp.50-51
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    • 1995
  • The swelling behavior of hyddrogels has been interested in many applications of drug carriers. These gels show reversible swelling changes in response to pH, electric currcnt, and temperature. Among others, the temperature-responsive behavior of poly(N-isopropylacrylanxide) (p(NIPAAm)) was studied, because a lower critical solution temperature(LCST) is in the vicinity of 32$\circ$C, and remarkable temperature-response can be obtained. We propose a novel composite membrane, which is appropriate for transporting drug ingredients above the transition temperature. Our object was to design a high permeation system above the shrinking temperature of p(NIPAAm). The membrane was composed of a matrix polymer and thermosensitive p(NIPAAm) hydrogel. The flux pattern of 4-acctamidophen through membrane in response of temperature was opposite to that of p(NIPAAm) membrane.

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Synthesis and Characterization of N,O-Carboxymethylchitosan Hydrogel Crosslinked by γ-ray Irradiation

  • Gwon, Hui-Jeong;Lim, Youn-Mook;An, Sung-Jun;Youn, Min-Ho;Nho, Young-Chang
    • Journal of Radiation Industry
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    • v.2 no.1
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    • pp.15-19
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    • 2008
  • In order to develop a water-solubility and biocompatibility, chemically modified chitosan, N,O-carboxymethylchitosan (NOCC), was synthesized and the NOCC hydrogels were prepared by using ${\gamma}-ray$ irradiation instead of chemical reagents. The FT-IR spectroscopy, swelling behavior, gel content and mechanical property such as gel strength of the hydrogel were measured. When the NOCC solution concentration was 15 wt% and the dose of irradiation was less than 50 kGy, the NOCC hydrogels had an excellent hydrophilicity and exhibited a good swelling behavior and mechanical properties.

Cholesteric Gels form Hydroxypropyl Cellulose(HPC) : Effect of Molecular Characteristics of HPC and Crosslinking Agent on Cholesteric Pitch and Swelling Behavior (Hydroxypropyl Cellulose (HPC)를 이용하여 제조한 Cholesteric Gels : HPC와 가교제의 분자특성이 Cholesteric Pitch와 팽윤거동에 미치는 영향)

  • Kim, Kyung-Hee;Jeong, Seung-Yong;Ma, Yung-Dae
    • Polymer(Korea)
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    • v.25 no.4
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    • pp.545-557
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    • 2001
  • The crosslinked films retaining cholesteric liquid-crystalline order were prepared by casting the liquid crystalline solutions of hydroxypropyl cellulose (HPC) in methanol with the two kinds of aliphatic dicarboxylic acid chlorides (succinyl chloride and suberoyl chloride). The temperature dependence on the cholesteric pitch of the crosslinked films and the swelling behavior of the films in both water and methanol were investigated. The films displayed fingerprint patterns charateristic of cholesteric liquid-crystalline phase, and their pitches, as well as HPC itself, increased with temperature. However, the pitch of all crosslinked samples was much greater than that of HPC at the same temperature and increased with increasing concentration and chain length of the crosslinker. The crosslinked samples exhibited an anisotropic swelling in both solvents. The degree of anisotropy slightly depended on the solvent and crosslinker species, but hardly on the crosslinker concentration investigated.

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A Concise Design for the Irradiation of U-10Zr Metallic Fuel at a Very Low Burnup

  • Guo, Haibing;Zhou, Wei;Sun, Yong;Qian, Dazhi;Ma, Jimin;Leng, Jun;Huo, Heyong;Wang, Shaohua
    • Nuclear Engineering and Technology
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    • v.49 no.4
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    • pp.734-743
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    • 2017
  • In order to investigate the swelling behavior and fuel-cladding interaction mechanism of U-10Zr alloy metallic fuel at very low burnup, an irradiation experiment was concisely designed and conducted on the China Mianyang Research Reactor. Two types of irradiation samples were designed for studying free swelling without restraint and the fuel-cladding interaction mechanism. A new bonding material, namely, pure aluminum powder, was used to fill the gap between the fuel slug and sample shell for reducing thermal resistance and allowing the expansion of the fuel slug. In this paper, the concise irradiation rig design is introduced, and the neutronic and thermal-hydraulic analyses, which were carried out mainly using MCNP (Monte Carlo N-Particle) and FLUENT codes, are presented. Out-of-pile tests were conducted prior to irradiation to verify the manufacturing quality and hydraulic performance of the rig. Nondestructive postirradiation examinations using cold neutron radiography technology were conducted to check fuel cladding integrity and swelling behavior. The results of the preliminary examinations confirmed the safety and effectiveness of the design.

pH-Sensitive Curdlan Acetate Microspheres를 이용한 Indomethacin의 방출 특성

  • Lee, Chang-Mun;Lee, Yeong-Jin;Lee, Gi-Yeong;Choe, Chun-Sun
    • 한국생물공학회:학술대회논문집
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    • 2003.04a
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    • pp.739-742
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    • 2003
  • Curdlan acetate was prepared from hydrophilic curdlan by chemical modification and it was used for pH-sensitive drug delivery system. Curdlan acetate microspheres were prepared by the solvent evaporation method. The size of the curdlan acetate microspheres was below $200\;{\mu}m$. The drug loading efficiency of microspheres was approximately 58.44%. In the swelling test, curdlan acetate microspheres were showed pH-sensitive behavior. The swelling capacity of microspheres at pH 7.4 was much greater than at pH 1.4. Also, Release rate of indomethacin (IND) at pH 7.4 from curdlan acetate microspheres was faster than that at pH 1.4. A pH-sensitive drug release pattern was due to the disintegrating after swelling.

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One-dimensional modeling of flat sheet casting or rectangular Fiber spinning process and the effect of normal stresses

  • Kwon, Youngdon
    • Korea-Australia Rheology Journal
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    • v.11 no.3
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    • pp.225-232
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    • 1999
  • This study presents 1-dimensional simple model for sheet casting or rectangular fiber spinning process. In order to achieve this goal, we introduce the concept of force flux balance at the die exit, which assigns for the extensional flow outside the die the initial condition containing the information of shear flow history inside the die. With the Leonov constitutive equation that predicts non-vanishing second normal stress difference in shear flow, we are able to describe the anisotropic swelling behavior of the extrudate at least qualitatively. In other words, the negative value of the second normal stress difference causes thickness swelling much higher than width of extrudate. This result implies the importance of choosing the rheological model in the analysis of polymer processing operations, since the constitutive equation with the vanishing second normal stress difference is shown to exhibit the characteristic of isotropic swelling, that is, the thickness swell ratio always equal to the ratio in width direction.

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Numerical Simulations of the Moisture Movement in Unsaturated Bentonite Under a Thermal Gradient

  • Park, J.W.;K. Chang;Kim, C.L.
    • Nuclear Engineering and Technology
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    • v.33 no.1
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    • pp.62-72
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    • 2001
  • The one-dimensional finite element program was developed to analyze the coupled behavior of heat, moisture, and air transfer in unsaturated porous media. By using this program, the simulation results were compared with those from the laboratory infiltration tests under isothermal condition and temperature gradient condition, respectively. The discrepancy of water uptake was found in the upper region of a bentonite sample under isothermal condition between numerical simulation and laboratory experiment. This indicated that air pressure was built up in the bentonite sample which could retard the infiltration velocity of liquid. In order to consider the swelling phenomena of compacted bentonite which cause the discrepancy of the distribution of water content and temperature, swelling and shrinkage factors were incorporated into the finite element formulation. It was found that these factors could be effective to represent the moisture diffusivity and unsaturated hydraulic conductivity due to volume change of bentonite sample.

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