• Title/Summary/Keyword: Swelling behavior

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Development of a Mechanistic Fission Gas Release Model for LWR $UO_2$ Fuel Under Steady-State Conditions

  • Koo, Yang-Hyun;Sohn, Dong-Seong
    • Nuclear Engineering and Technology
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    • v.28 no.3
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    • pp.229-246
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    • 1996
  • A mechanistic model has been developed to predict the release behavior of fission gas during steady-state irradiation of LWR UO$_2$ fuel. Under the assumption that UO$_2$ grain surface is composed of fourteen identical circular faces and grain edge bubble can be represented by a triangulated tube around the circumference of three circular grain faces, it introduces the concept of continuous formation of open grain edges tunnels that is proportional to grain edge swelling. In addition, it takes into account the interaction between the gas release from matrix to grain boundary and the reintroduction of gas atoms into the matrix by the irradiation-induced re-solution of grain face bubbles. It also treats analytically the behavior of intragranular, intergranular, and grain edge bubbles under the assumption that both intragranular and intergranular bubbles are uniform in both radius and number density. Comparison of the present model with experimental data shows that the model's prediction produces reasonable agreement for fuel with centerline temperatures of 1000 to 140$0^{\circ}C$, wide scatter band for fuel with centerline temperatures lower than 100$0^{\circ}C$, and underprediction for fuel with centerline temperatures higher than 140$0^{\circ}C$.

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Effect of lipid contents on the physicochemical characteristics of acorn starch (지방함량 변화에 따른 도토리전분의 이화학적 특성)

  • Ahn, Ho-Kyoung;Kil, Hun-Bae;Yoo, Hae-Euy;Oh, Doo-Hwan
    • Applied Biological Chemistry
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    • v.33 no.4
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    • pp.293-300
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    • 1990
  • The physical and chemical properties of dry acorn starch(DS), defatted acorn starch (DFS) and reincorporated acorn starch(RIS) were investigated. Swelling power and solubility of all starch sample, were exhibited two stage behavior. It had a little change on the pasting temperature of DS and DFS but the peak viscosity and breakdown value of DFS was somewhat higher than those of DS and RIS. Flow behavior of gelatinized starch pastes showed a pseudoplastic behavior and flow behavior index was lower than unit The consistency coefficient showed concentration and temperature dependency. The activation energies of DS, DFS and RIS were from $1.70Kca1/g\;{\cdot}\;mol$ to $3.75Kca1/g\;{\cdot}\;mol$.

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High Deformable Concrete (HDC) element: An experimental and numerical study

  • Kesejini, Yasser Alilou;Bahramifar, Amir;Afshin, Hassan;Tabrizi, Mehrdad Emami
    • Advances in concrete construction
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    • v.11 no.5
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    • pp.357-365
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    • 2021
  • High deformable concrete (HDC) elements have compressive strength rates equal to conventional concrete and have got a high compressive strain at about 20% to 50%. These types of concrete elements as prefabricated parts have an abundance of applications in the construction industry which is the most used in the construction of tunnels in squeezing grounds, tunnel passwords from fault zones or swelling soils as soft supports. HDC elements after reaching to compressive yield stress, in nonlinear behavior have hardening combined with increasing strain and compressive strength. The main aim of this laboratory and numerical research is to construct concrete elements with the above properties so the compressive stress-strain behavior of different concrete elements with four categories of mix designs have been discussed and finally one of them has been defined as HDC element mix design. Furthermore, two columns with and without implementing of HDC elements have been made and stress-strain curves of them have been investigated experimentally. An analysis model is presented for columns using finite element method adopted by ABAQUS. The results obtained from the ABAQUS finite element method are compared with experimental data. The main comparison is made for stress-strain curve. The stress-strain curves from the finite element method agree well with experimental results. The results show that the dimension of the HDC samples is significant in the stress-strain behavior. The use of the element greatly increases energy absorption and ductility.

Alleviating Effects of Vitamin C on the GRamoxone Toxicity in Rat Liver (흰쥐 간조직에 미치는 제초제 Gramoxone 독성에 대한 비타민 C의 완화 효과)

  • Un-Bock Jo;Sung-Ro Kim
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.23 no.3
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    • pp.380-386
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    • 1994
  • The behavior of glycogen and histological changes of hepatic tissues in the liver of rats, aged 6 to 7 weeks, fed 18% casein diet under control, gramoxone and gramoxone + vitamin C(Vt. C) diets has been investigated in a comined histropathological and histochemical studies. Cloudy swelling and fat changes of hepatic cells were observed in the gramoxone group with the duration of feeding time. Fat changes of hepatic cells were observed more obviously than cloudy welling, especially in the hepatic cells of periportal area. The number of Kupffer's cells increased signifciantly in the gramoxone group fed for 4weeks. The cloudy swelling and fat changes decreased obviously in the gramxone + Vt. C group. Glycogen content of heaptic cells tended to increase slightly in the gramoxone group as compared with the control group . moreover, glycogen depositons were higher in the hepatic cells where fat changes were obvious. It seems to be that Vt.C alleviating effects on the gramoxone toxicity in the patterns of glycogen distribution and histological structure of heaptic tissues.

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Organized Hematoma in the Maxillary Sinus (상악동에 발생한 organized hematoma)

  • Kim, Jae-Jin
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.32 no.5
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    • pp.473-477
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    • 2010
  • Organized hematoma of the maxillary sinus is a rare, nonneoplastic benign lesion with locally destructive behavior that may mimic a malignancy. Clinically, symptoms do not usually occur while the lesion remains localized to the maxillary sinus. Because there is gradual enlargement of the lesion causing erosion and displacement of the adjacent bony structures, symptoms such as epistaxis, cheek swelling, nasal obstruc-tion, headache, and exophthalmos become manifest. Radiologically, unilateral cases are much more fre-quent than bilateral, and Waters' view shows complete opacity of the expanded maxillary sinus and some masses. CT scan shows a large heterogeneous enhancing mass causing considerable expansion of the max-illary sinus with bony erosion. On MR imaging, the mass usually has a variable signal intensity on T1- and T2- weighted images, ranging from low to high. After contrast administration, discrete areas of enhance-ment are present within the mass. Although the disease is essentially benign and nonneoplastic, differen-tial diagnosis from neoplastic disease including malignancy both clinically and radiologically has been always problematic. Accurate preoperative diagnosis of organized hematoma of the maxillary sinus is important to avoid unnecessary extensive surgery, because this condition is curative with a simple, conservative surgical approach and rarely recur. Organized hematoma of the maxillary sinus should be included in the differential diagnosis when patients have recurrent epistaxis, slow-growing mass of the cheek, nasal obstruction, and expansile mass in the maxillary sinus. A 33-year-old man was referred to the department of oral and maxillofacial surgery with a three-month history of slowly growing painful swelling of the left cheek. The mass of the maxillary sinus was resected by a Caldwell-Luc approach. Histopahtoly showed only a fibous encapsulated organized hematoma. To our knowledge, organized hematoma of the maxillary sinus has not been previously described in the Korean literature of the oral and maxillofacial surgery. We report a case of organized hematoma of the maxillary sinus presenting with an enlarging maxillary sinus mass.

Effect of pH-Sensitive P(MAA-co-PEGMA) Hydrogels on Release and Stability of Albumin (pH 감응성 P(MAA-co-PEGMA) 수화젤이 알부민의 방출과 안정성에 미치는 영향)

  • Yang, Juseung;Kim, Bumsang
    • Polymer(Korea)
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    • v.37 no.3
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    • pp.262-268
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    • 2013
  • pH-sensitive P(MAA-co-PEGMA) hydrogel particles were prepared and their feasibility as smart delivery carriers for cosmetic ingredients was evaluated. P(MAA-co-PEGMA) hydrogel particles having an average size of approx. $2{\mu}m$ were synthesized via dispersion photopolymerization. There was a drastic change in the swelling ratio of P(MAA-co-PEGMA) particles at a pH of around 5 due to the ionization of MAA in the hydrogel and as the amount of MAA in the hydrogel increased, the swelling ratio increased at a pH above 5. The P(MAA-co-PEGMA) hydrogel particles showed a pH-sensitive release behavior. Thus, at pH 4 almost none of the albumin permeated through the skin while at pH 6 relatively high skin permeability was obtained. The albumin loaded in the P(MAA-co-PEGMA) hydrogel particles was hardly degraded in the presence of pepsin and its stability was maintained.

Miscible Blend and Semi-IPN Gel of Poly(hydroxyethyl aspartamide) with Poly(N-vinyl pyrrolidone) (폴리아스팔트아미드와 폴리(비닐 피롤리돈)의 상용블렌드 및 Semi-IPN 젤 제조)

  • Meng, Fan;Jeon, Young-Sil;Chung, Dong-June;Kim, Ji-Heung
    • Polymer(Korea)
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    • v.36 no.5
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    • pp.617-621
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    • 2012
  • PHEAs [${\alpha}$,${\beta}$-poly(2-hydroxyethyl-DL-aspartamides)], a class of poly(amino acid), have been widely studied as biodegradable and biocompatible polymers for potential biomedical and pharmaceutical applications. In this study, we investigated a homogeneous blend of PHEA with poly(N-vinyl pyrrolidone) (PNVP) and its semi-IPN (semi-interpenetrating polymer network) gels. Blend films were prepared by a solution casting method. The resulting blends were totally transparent over the whole composition ranges and the single $T_g$, changing monotonously with composition, was observed by DSC to confirm the miscibility between these two polymers. FTIR was used to discuss the possible hydrogen-bonding interaction between polymers. In addition, semi-IPN type gels were prepared by chemical crosslinking of PHEA/PNVP blend solution using hexamethylene diisocyanate (HMDI) as a crosslinking reagent. The prepared gel was characterized by their swelling property and morphology.

Release Characteristics of Sulfadiazine Using Chitosan Matrices (키토산 매트릭스를 이용한 Sulfadiazine의 방출 특성)

  • 문일식;나재운
    • KSBB Journal
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    • v.11 no.6
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    • pp.676-680
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    • 1996
  • The characteristics of controlled drug release were studied for a biodegradable drug delivery system. A biodegradable chitosan matrix was prepared after swelling chitosan with 10%-acetic acid and adding sulfadiazine. The release behavior of sulfadiazine from the chitosan matrix was studied using the Higuchi's diffusion controlled model in phosphate buffer solutions of pH 7.4 and pH 1.2. The drug release time was delayed by increasing the content of sulfadiazine. The drug release at pH 7.4 was more delayed than that at pH 1.2. The reason is that chitosan has greater swelling abilities at low pH than at high pH. The apparent release rate constant(K) increased as the concentration of drug increased. In shoat, the formulation the biodegradable chitosan matrix to suppress the burst effect of drug release mechanism, which led to a sustained release pattern.

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A Study of the Effect of Degree of Cure on the Physical Properties of Rubber Compounds (가교정도에 따른 고무복합체의 물리적 특성에 관한 연구)

  • Kim, Hyeon-Jae;Kaang, Shin-Young;Nah, Chang-Woon
    • Elastomers and Composites
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    • v.33 no.4
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    • pp.281-289
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    • 1998
  • Tensile properties including Young's modulus and tear strength were measured for four different rubber compounds; natural rubber(NR), styrene-butadiene copolymer(SBR), ethylene-propylene diene monomer (EPDM), and brominated isobutylene-p-methyl-styrene copolymer(BIMS) as a function of temperature and degree of cure. To see the effect of over cure, a measurement was made of the tensile strength and swelling behavior of the over-cured rubber compounds. Young's modulus, E, was found to have linear dependency on the degree of cure for all rubber compounds. EPDM and BIMS showed the highest and lowest slopes, respectively. The slope of NR and SBR lay between EPDM and BIMS. Tear strength, Gc, decreased in the order of NR>BIMS>SBR>EPDM. As the cure time was extended the degree of cure of NR and SBR decreased, while that of BIMS increased. EPDM showed little change in the degree of cure.

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Analysis of Number of Elastically Cross-links to Predict the Mechanical Properties of 3D Networked Poly(sodium acrylate) Gel (폴리아크릴산나트륨 3차원 네트워크 겔의 물성 예측을 위한 가교개수밀도 분석)

  • Kim, Sang Jin;Jeong, Hye-Won;Shin, Sung Gyu;Cho, Sung Woo;Jeong, Jae Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.1
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    • pp.300-308
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    • 2021
  • In this study, 3D networked poly(sodium acrylate) gel was polymerized and controlled with the crosslinking environment to evaluate the mechanical properties and swelling behavior. In general, as the degree of crosslinking in a pre-gelled solution increases, the swelling ratio of the 3D networked gel decrease while the mechanical strength of the gel increases. Interestingly, this study demonstrates that the polymerization and crosslinking efficiency in gelling process could be depended on the crosslinking environment by evaluating the number of elastically cross-links in 3D networked gel. As a result, the number of elastically corss-links would be changed with 3.6 times as varying of the crosslinking environment while keeping the degree of crosslinking. It is expected that the 3D networked gel would be optimized as an effective absorbing agent for VOCs by using the gel evaluation method based on the number of elastically cross-links.