• Title/Summary/Keyword: Swelling behavior

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A Study on the Synthesis of Organophilic Intercalations-complex of [RCOOH]-Montmorillonite and on ItOs Swelling Behavior (양이온교환반응에 의한 Organophilic [RCOOH]-Montmorillonite 층간화합물의 형성과 그 팽윤거동에 관한 연구)

  • 김종옥;김택남;조성준
    • Journal of the Korean Ceramic Society
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    • v.31 no.3
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    • pp.282-290
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    • 1994
  • In this research, the organic salt [RCOOH] Br with long alkyl-chain was synthesized, and the organophilic [RCOOH]-Montmorillonite was formed by cation-exchange-reaction between Na-Montmorillonite and synthesized organic salt [RCOOH] Br. After drying of the organophilic [RCOOH]-Montmorillonite at $65^{\circ}C$ in high vaccum, the experiments for the probability of forming its complexes with various swelling-solutions as dist, water, methanol, ethanol, acetonitrile, propionitrile, butyronitrile, toluene and n-decanol were performed, and the corresponding basal spacings obtained were 17.44$\AA$, 31.86$\AA$, 34.38$\AA$, 30.37$\AA$, 32.39$\AA$, 35.04$\AA$, 14.16$\AA$ and 14.63$\AA$ respectively.

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Drug Release from Ph-sensitive Interpenetrating Polymer Net-works Hydrogel Based on Poly(ethylene glycol) Macromer and Poly (acrylic acid)Prepared by UV Cured Method

  • Kim, In-Sook;Kim, Sung-Ho;Cho, Chong-Su
    • Archives of Pharmacal Research
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    • v.19 no.1
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    • pp.18-22
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    • 1996
  • Acrylate-terminated poly (ethylene glycol) (PEG) macromer was prepared by the reaction of PEG with acryloyl chloride. Photopolymerization of PEG macromer resulted in the formation of cross-linked PEG network. Interpenetrating polymer networks (IPNs) based on PEG and poly(acrylic acid) (PAA) was obtained via template polymerization of AA to the PEG network by UV curing. The swelling degree of the IPNs hydrogel increased with an increase of pH value due to the association-dissociation between carboxylic acid of PAA and either of PEG through hydrogen bounding. The swelling-deswelling behavior proceeded reversibly for the IPNs upon changing pH. Release of indomethacin from the IPNs demonstrated "on-off" regulation with pH fluctuation.

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Effect of pH and storage time on the elution of residual monomers from polymerized composites

  • Jeon, Cheol-Min;Kwon, Hyuk-Choon
    • Proceedings of the KACD Conference
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    • 2003.11a
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    • pp.561-562
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    • 2003
  • pH varies in the oral environment and on tooth surfaces. The surface of a plaque covered resinous restoration has a low pH. In human dental plaque a number of acids are produced by bacterial metabolism. The predominant acids are acetic, propionic and lactic acids. These acids induced a surface swelling of restorative resin. The swelling cause formation of pores inside the resin matrix from which organic substances can be released, resulting in a mass loss. The purpose of this study was to qualitatively and quantitatively analyse the leached monomers of dental composites after storage in acetate buffer solution as a function of time by means of high performance liquid chromatography(HPLC) / mass spectrometer and further determine whether pH and time has any influence on the degradation behavior of composite restoration.(omitted)

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Interdiffusion at Interfaces of Polymers with Dissimilar Physical Properties

  • 정재명;박형석
    • Bulletin of the Korean Chemical Society
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    • v.18 no.7
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    • pp.720-729
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    • 1997
  • The interface between two different polymers is characterized theoretically by using a model. This model is based on the assumption that the monomeric friction coefficients of the two polymers are identical but a strong function of the matrix composition. This model predicts that the concentration profiles are highly asymmetric with substantial swelling of the slower-diffusing component by the faster component. To predict the behavior of interdiffusion, three quantities are used: distance of interface Z*(t) due to the swelling, interfacial width W(t) which is most sensitive to the detailed composition profiling, and mass transport M(t) due to interdiffusion. It is found that the more dissimilar polymer pairs, the faster the movement of the interface, the quicker its interfacial width saturates to a limiting value and the slower its mass transport. These results are in qualitative agreement with some experiments.

New CPS-PPEES blend membranes for CaCl2 and NaCl rejection

  • Chitrakar, Hegde;Arun, M. Isloor;Mahesh, Padaki;Ahmad, Fauzi Ismail;Lau, W.J.
    • Membrane and Water Treatment
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    • v.3 no.1
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    • pp.25-34
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    • 2012
  • Carboxylated polysulfone (CPS), poly (1,4-phenylene ether ethersulfone) (PPEES), membranes were prepared and used for the separation of NaCl and $CaCl_2$, in efficient way with less energy consumption. In this work, nanofiltration and reverse osmosis membranes were employed to the salt rejection behavior of the different salt solutions. The influence of applied pressure (1-12 bar), on the membrane performance was assessed. In CM series of membranes, $CM_1$ showed maximum of 97% water uptake and 36% water swelling, whereas, $CM_4$ showed 75% water uptake and 28% water swelling. In RCM series, $RCM_1$ showed 85% water uptake and 32% water swelling whereas, in $RCM_4$ it was 68% for water uptake and 20% for water swelling. Conclusively reverse osmosis membranes gave better rejection whereas nanofiltration membrane showed enhanced flux. CM1 showed 58% of rejection with 12 L/($m^2$ h) flux and $RCM_1$ showed 55% of rejection with 15 L/($m^2$ h) flux for 0.1 wt.% NaCl solution. Whereas, in 0.1 wt.% $CaCl_2$ solution, membrane $CM_1$ showed 78% of rejection with 12 L/($m^2$ h) flux and $RCM_1$ showed 63% rejection with flux of 9 L/($m^2$ h).

Effects of Kinesio Taping on Edema Control in Patients With Musculoskeletal Injuries: A Literature Review

  • Yong, Joon-hyoung;Lim, Jin-seok;Moon, Il-young;Yi, Chung-hwi
    • Physical Therapy Korea
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    • v.29 no.3
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    • pp.171-179
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    • 2022
  • Background: The application of Kinesio tape (KT) has become an alternative treatment for the reduction of edema owing to its distinct characteristics that mimic skin behavior. Although many studies have found that KT application has a positive effect on edema related to breast cancer and rehabilitation following mandibular third molar surgery, there is little evidence to support the use of KT for musculoskeletal injuries. Objects: The purpose of this study was to review the literature related to KT application for reducing edema caused by musculoskeletal disorders. Methods: A literature search (July 2022) was performed on PubMed for articles published between January 2012 and June 2022. The following keywords were used: "Kinesio taping," "Kinesio tape," "swelling," and "edema," with different combinations and derivations. Only articles available in English were included in this study. Results: Among 68 identified studies, seven met our search strategy and criteria and were included in the literature review. Five of these studies investigated musculoskeletal disorders of the knee joint; two of them reported that KT application had a positive effect on edema measured using perimetry following total knee replacement and anterior cruciate ligament reconstruction. However, the KT application did not improve swelling in patients with acute lateral ankle sprains. Pediatric patients with acute proximal phalangeal joint sprain experienced a more significant improvement in the reduction of swelling than the group using a splint. Conclusion: This literature review found discrepant evidence to support using KT for edema control in musculoskeletal disorders. Further research is needed to determine the effectiveness of KT for controlling edema following musculoskeletal injuries.

Studies on Vaginal Cytology after Induction of Estrus in the Bitch (인공적(人工的) 발정유기견(發情誘起犬)의 질세포상(膣細胞像)에 관(關)한 연구(硏究))

  • Kang, Byong-kyu;Choi, Han-sun;Na, Jin-su;Son, Chang-ho;Oh, Ki-seok;Lee, Cha-bum
    • Korean Journal of Veterinary Research
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    • v.28 no.1
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    • pp.203-211
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    • 1988
  • The present study was carried out to investigate the estrous behavior and vaginal smear after induction of estrus with exogenous hormones in the premature, metestrous and anestrous bitches. A total of 21 bitches(Mixed breed: 16, Jindo breed: 5), from 10 months to 5 years of age and weighing 8 to 15 kg was studied the change of vaginal smear and the estrous behavior before and after induction of estrus. The results obtained are as follows: 1. In the treatment A(They were given the $PGF_2{\alpha}$, estrone, estradiol-$17{\beta}$, PMSG and HCG) proestrus commenced in $10.16{\pm}1.44$($Mean{\pm}SEM$) days after treatment, The mean duration of proestrus, and estrus was $7.50{\pm}1.44$ and $13.50{\pm}3.44$ days, respectively. In the treatment B(They were given the PMSG and HCG) proestrus commenced in $5.53{\pm}0.59$ days after treatment. The mean duration of proestrus and estrus was $6.60{\pm}0.71$ and $14.60{\pm}1.14$ days, respectively. 2. All of the 6 bitches in the treatment A showed vulval swelling and vaginal discharge, 14 of the 15 bitches in the treatment B showed vulval swelling and vaginal discharge. However, all of the treatment A and B showed male acceptance. 3. The main change of vaginal smear in proestrus and estrus after induction of estrus was a increase in the proportion of anuclear and superficial cells associated with a decrease in small intermediate and parabasal cells. By the estrous behavior and vaginal smear the estrus was induced in all the premature, metestrous and anestrous bitches.

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Geotechnical shear behavior of Xanthan Gum biopolymer treated sand from direct shear testing

  • Lee, Sojeong;Chang, Ilhan;Chung, Moon-Kyung;Kim, Yunyoung;Kee, Jong
    • Geomechanics and Engineering
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    • v.12 no.5
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    • pp.831-847
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    • 2017
  • Conventional geotechnical engineering soil binders such as ordinary cement or lime have environmental issues in terms of sustainable development. Thus, environmentally friendly materials have attracted considerable interest in modern geotechnical engineering. Microbial biopolymers are being actively developed in order to improve geotechnical engineering properties such as aggregate stability, strength, and hydraulic conductivity of various soil types. This study evaluates the geotechnical engineering shear behavior of sand treated with xanthan gum biopolymer through laboratory direct shear testing. Xanthan gum-sand mixtures with various xanthan gum content (percent to the mass of sand) and gel phases (initial, dried, and re-submerged) were considered. Xanthan gum content of 1.0% sufficiently improves the inter-particle cohesion of cohesionless sands 3.8 times and more (up to 14 times for dried state) than in the untreated (natural) condition, regardless of the xanthan gum gel condition. In general, the strength of xanthan gum-treated sand shows dependency with the rheology and phase of xanthan gum gels in inter-granular pores, which decreases in order as dried (biofilm state), initial (uniform hydrogel), and re-submerged (swollen hydrogel after drying) states. As xanthan gum hydrogels are pseudo-plastic, both inter-particle friction angle and cohesion of xanthan gum-treated sand decrease with water adsorbed swelling at large strain levels. However, for 2% xanthan gum-treated sands, the re-submerged state shows a higher strength than the initial state due to the gradual and non-uniform swelling behavior of highly concentrated biofilms.

Pervaporation of Water/ethanol Mixtures Using PVA Membranes Crosslinked with Poly (styrene-maleic anhydride): Study on the Separation Behavior (Poly (styrene-maleic anhydride)로 가교된 Poly (vinyl alcohol)막을 이용한 물/에탄올 수용액의 투과증발: 분리거동에 관한 연구)

  • Kim, Sang-Gyun;Lim, Gyun-Taek;Park, Sang-Wook
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.469-474
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    • 1998
  • Poly (vinyl alcohol) (PVA) membranes crosslinked with poly (styrene-co-maleic anhydride) (PSMAn) have been prepared by the solution method. To investigate the separation behavior of the crosslinked PVA/PSMAn membranes in the pervaporation process, the selective sorption experiment and swelling measurements of the membranes in ethanol-water mixtures of 30~90 wt % ethanol contents were conducted with equipment that was able to measure the concentration and amount of the liquid absorbed in the membranes. The membranes prepared in this study exhibited good selectivity toward water component in sorption and permeation. Also, in the feed containing ethanol more than 50 wt %, the permeation selectivity of the membrane showed better correlation with the sorption selectivity than that with the swelling ratio changing toward the crosslinking content. This behavior was consistence with a solution-diffusion model correlating permeation and sorption selectivity, and led to the conclusion that the permeation selectivity was determined by sorption step rather than by diffusion step in the membrane.

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Comparison on Mechanical Properties of SSBR Composites Reinforced by Modified Carbon black, Silica, and Starch

  • Lee, Dam-Hee;Li, Xiang Xu;Cho, Ur-Ryong
    • Elastomers and Composites
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    • v.53 no.3
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    • pp.175-180
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    • 2018
  • Solution-styrene-butadiene rubber (SSBR) composites were manufactured using four kinds of fillers: silica-silane coated carbon black (SC-CB) hybrid, starch-SC-CB hybrid, pure silica, and pure starch. The influence of filler type on the mechanical properties of the rubber matrix was studied in this work. SC-CB was prepared by silane-graft-coating using vinyl triethoxy silane and carbon black, which enhanced the dispersion effect between the rubber matrix and the filler, and improved the mechanical properties of the compounds. The morphology of the composites was observed by field-emission scanning electron microscopy (FE-SEM). The thermal decomposition behavior of the composites was determined by thermogravimetric analysis (TGA), and the crosslinking behavior of the composites was tested using a rubber process analyzer (RPA). The hardness, tensile strength, swelling ratio, and gas transmittance rate of the composites were evaluated according to ASTM. The test results revealed that with the addition of SC-CB, the hybrid fillers, especially those blended with silica, showed a better reinforcement effect, the highest hardness and tensile strength, and stable thermal decomposition behavior. This implies that the silica-SC-CB hybrid filler has a notable mechanical reinforcement effect on the SSBR matrix. Because of self-crosslinking during its synthesis, the starch-SC-CB hybrid filler produced the most dense matrix, which improved the anti-gas transmittance property. The composites with the hybrid fillers had better anti-swelling properties as compared to the neat SSBR composite, which was due to the hydrophilicity of silica and starch.