• 청정기술
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• 제17권1호
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• pp.13-18
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• 2011

포스핀(phosphine) 리간드(ligand)가 도포된 메조포러스 실리카(mesoporous silicas)에 팔라듐 나노입자를 도입하여 새로운 팔라듐(Pd) 불균일 촉매(heterogeneous catalyst)를 제조하였다. 제조된 촉매는 브롬화벤젠 유도체(bromobenzene derivatives)들의 Suzuki cross-coupling 반응에 대하여 뛰어난 촉매활성을 나타내었고 촉매를 두 번째 사용하였을 때는 수율이 감소하였다.

• Bulletin of the Korean Chemical Society
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• 제30권11호
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• pp.2697-2700
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• 2009

A $Pd(OAc)_2/(o-MeOPh)_3P$ system has been developed for the catalytic Suzuki coupling of aryl bromides with arylboronic acids. Our catalyst system covers a broad spectrum of commonly available arylboronic acids and aryl bromides to provide biaryls in very good yields. The catalyst system works very well in the synthesis of sterically hindered biaryls.

• Bulletin of the Korean Chemical Society
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• 제34권5호
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• pp.1477-1480
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• 2013

The Suzuki cross-coupling reactions proceeded in excellent yields when it was catalyzed by magnetically recyclable nanocatalyst. This nanocatalyst provided very high catalytic activity with low loading level (1 mol %), because the palladium nanoparticles were so small in size (~2 nm) and located on the surface of the nanocomposite. It was also easily recovered from the reaction mixture using a magnet and reused for six consecutive cycles.

• Bulletin of the Korean Chemical Society
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• 제32권1호
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• pp.359-362
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• 2011

• Bulletin of the Korean Chemical Society
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• 제25권1호
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• pp.29-30
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• 2004

• Bulletin of the Korean Chemical Society
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• 제24권11호
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• pp.1632-1636
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• 2003

Palladium-catalyzed cross-coupling reactions of neopentyloxysulfonylphenyl bromides with arylboronic acids provided a variety of neopentyl biphenylsulfonates in good yields. 2-Bromo- and 4-bromobenzenesulfonates underwent the coupling reaction more rapidly than 3-bromobenzenesulfonate, while chlorobenzenesulfonate did not produce the coupling product under the standard reaction conditions.

• Bulletin of the Korean Chemical Society
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• 제24권12호
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• pp.1832-1834
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• 2003

• Bulletin of the Korean Chemical Society
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• 제23권5호
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• pp.663-664
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• 2002

• 대한화학회지
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• 제57권3호
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• pp.361-364
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• 2013

A modified synthetic approach to the synthesis of heterocyclic food mutagens, 2-amino-1-methyl-6-phenylimidazo[4,5-b]pyridine (PHIP) and 2-amino-1,6-dimethylimidazo[4,5-b]pyridine (DMIP) is reported. This route highlights an optimized palladium catalysed Buchwald cross-coupling of 2-halo-1-methyl-imidazo[4,5-b]pyridine with benzophenoneimine followed by acidic hydrolysis to yield compound 7. Using finely tailored conditions, Suzuki cross-coupling reactions with highly efficient catalytic systems were performed as the final step on 8 to introduce the aryl group and methyl group on the heterocyclic core.

• Bulletin of the Korean Chemical Society
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• 제32권spc8호
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• pp.2897-2898
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• 2011