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http://dx.doi.org/10.5012/bkcs.2009.30.11.2697

Tris(2-methoxyphenyl)phosphine as a Highly Active Ligand for the Synthesis of Biaryls by Suzuki Coupling Reaction  

Kang, Pill-Seong (Medigen Inc)
Ko, Sung-Bo (Medigen Inc)
Ko, Jang-Myoun (Division of Applied Chemistry and Biotechnology, Hanbat National University)
Park, Jeong-Ho (Division of Applied Chemistry and Biotechnology, Hanbat National University)
Publication Information
Bulletin of the Korean Chemical Society / v.30, no.11, 2009 , pp. 2697-2700 More about this Journal
Abstract
A $Pd(OAc)_2/(o-MeOPh)_3P$ system has been developed for the catalytic Suzuki coupling of aryl bromides with arylboronic acids. Our catalyst system covers a broad spectrum of commonly available arylboronic acids and aryl bromides to provide biaryls in very good yields. The catalyst system works very well in the synthesis of sterically hindered biaryls.
Keywords
Tris(2-methoxyphenyl)phosphine; Suzuki coupling reaction;
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