• Title/Summary/Keyword: Suspension viscosity

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Effect of Carbon Black Concentration and Monomer Compositional Ratio on the Flow Behavior of Copoly(styrene/butyl methacrylate) Particles (카본블랙의 농도 및 단량체 구성비에 따른 스티렌-부틸메타크릴레이트 공중합체 입자의 유동성)

  • Park, Moon-Soo;Moon, Ji-Yeon
    • Elastomers and Composites
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    • v.45 no.2
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    • pp.122-128
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    • 2010
  • We measured shear viscosity of copoly(styrene(St)/butyl methacrylate(BMA)) (co-PSB) particles, with a capillary rheometer at $170^{\circ}C$, prepared by suspension polymerization with hydrophobic silica as a stabilizer. co-PSB particles with the weight average molecular weights of lower than 74,800 g/mol displayed a Newtonian behavior at low shear rates. With the weight average molecular weight exceeding 136,800 g/mol, co-PSB particles showed shear thinning against shear rates and the absolute value of the slopes between shear viscosity vs. shear rate increased. When the ratio between St and BMA changed from 7/3 to 5/5 to 3/7, shear viscosity and glass transition decreased despite similar molecular weights. When the ratio was 1/9, it showed a large increase in initial shear viscosity despite reduced glass transition. Shear viscosity exhibited an increase in proportion to carbon black concentration. The effect of carbon black concentration on the shear viscosity of co-PSB composites was less pronounced compared to varying molecular weights and/or compositional ratio.

Evaluation of the Groutability through Microcrack and Viscosity Measurement Methods for Grouting Materials (미세균열 그라우팅 주입성능 및 재료의 점도 측정방법 평가)

  • Jin, Hyun-Woo;Ryu, Byung-Hyun;Lee, Jang-Guen
    • Journal of the Korean Geotechnical Society
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    • v.33 no.9
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    • pp.23-34
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    • 2017
  • In order to develop urban underground spaces, even microcracks should be reinforced. In this paper, the grouting injection performance for microcracks was investigated considering the viscosity and particle size of the grouting materials, injection pressure, and crack width. There are two types of typical grouting materials used for filling micro-cracks. One is a chemical liquid grouting material which is a solution type and the other is a cementitious grouting material which is a suspension type. The injection performance of the grouting materials for microcracks is generally influenced by the viscosity, and the injection performance of the cementitious grouting material is additionally affected by the particle size. From laboratory tests, the viscosity was calculated inversely to provide a suitable viscosity measurement method for each grouting material. The groutability ratio based on the relationship between the crack width and the particle size was evaluated to estimate the grouting feasibility of the cementitous grouting material through microcracks.

Control Performance Investigation of MR Fluid Damper using Herschel-Bulkley Shear Model (Herschel-Bulkley 모델을 이용한 MR 댐퍼 승용차의 제어 성능 고찰)

  • 이덕영;황우석
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.05a
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    • pp.323-328
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    • 2002
  • The control performance of a vehicle installed with an MR(magnetorheological) fluid-based damper is investigated on the basis of Herschel-Bulkley shear model. Generally, most of MR fluid damper has been analyzed based on a simple Bingham-plastic shear model. However, the Bingham-plastic shear model can not well describe the behavior of the damper on the condition of high velocity and high current field input. Therefore, in this study, the Herschel-Bulkley shear model in which the constant post-yield plastic viscosity in Bingham model is replaced with a power law model dependent on shear rate is used to assess control performance of a vehicle with MR fluid damper suspension system. This study deals with a two-degree-of-freedom suspension using the MR fluid damper for a quarter car model. The response for the bump input to identify the fastness of MR fluid damper embedded skyhook controller and requested magnetic field are investigated.

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Electrorhelological Properties of Monodispersed Submicron-sized Hollow Polyaniline Adipate Suspension

  • Sung, Bo-Hyun;Choi, Ung-Su
    • KSTLE International Journal
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    • v.6 no.1
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    • pp.28-32
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    • 2005
  • The electrorheoloRical (ER) fluids are composed of a colloidal dispersion of polarizable particles in insulating oil, and it's the rheological property changes by the applied electric field. These changed are reversible and occur fast within a fewmilliseconds. The ER properties of the ER fluid such as increment of viscosity and yield stress come from the particle chain structure induced by electric fleld. When formulating the ER fluid for a speciflc application, some requirement must besatisfled, which are high yield stress under electric field, rapid response, and dispersion stability. While this characteristic makes valuable ER fluids in valious industrial applications, their lung term and quiescent application has been limited because ofproblems with particle sedimentation. In an effort to overcome sedimentation problem of ER fluids, the anhydrous ER materials of monodispersed hollow polyaniline (PANI) and adipate derivative respectively with submicron-sized suspension providing wide operating temperature range and other advantage were synthesized in a four-step procedure. The ER fluidswere characterized by FT-lR, TGA, DLS, SEM, and TEM. Stability of the suspensions was examined by an UV spectroscopy.The rheological and electrical properties of the suspension were investigated Couette-type rheometer with a high voltagegenerator, current density, and conductivity. And the behavior of ER suspensions was observed by a video camera attached toan optical microscope under 3kV/mm. The suspensions showed good ER properties, durability, and particle dispersion.

Effects of Carbon Fiber on Mechanical Behaviour of Al2O3 Porous Ceramics

  • Basnet, Bijay;Lim, Hyung Mi;Lee, Kee Sung;Kim, Ik Jin
    • Journal of the Korean Ceramic Society
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    • v.56 no.5
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    • pp.513-520
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    • 2019
  • This study reports the improvement of mechanical properties of Al2O3 porous ceramics from colloidal suspension with the addition of carbon fiber by direct foaming. The initial colloidal suspension of Al2O3 was partially hydrophobized by surfactant to stabilize wet foam with the addition of carbon fiber from 2 to 8 wt% as stabilizer. The influence of carbon fiber on the air content, bubble size, pore size and pore distribution in terms of wet foam stability and physical properties of porous ceramics were discussed. The viscosity of the colloidal suspension was increased giving solid like properties with the increased in carbon fiber content. The mechanical properties of the sintered porous samples were investigated by Hertzian indentation test. The results show the wet foam stability of more than 90% corresponds to compressive loading of 156.48 N and elastic modulus of 57.44 MPa of sintered sample with 8 wt% of carbon fiber content.

Preparation and Characterization of Dense Suspension of Aloe Gel Microcapsule (알로에 겔 마이크로캡슐의 고농도 현탁액의 제조 및 특성)

  • Go, Nam Kyung;Lee, Jin Sil;Lee, Shin Young;Hur, Won
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.39 no.1
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    • pp.47-54
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    • 2013
  • Aloe gel microcapsule was prepared by dehydrating dispersed aloe gel droplets in the form of W/O emulsion using a vacuum evaporator. The microcapsules remained in stable suspensions after washing with mineral oil and had a homogeneous spherical structure with diameter less than 6.4 ${\mu}m$. The microcapsule suspension in mineral oil (> 41%) exhibited a step increase in viscosity and shear-thinning but not showed thixotropic behavior with a yield stress higher than 300 Pa. The dense suspension appeared to be semi-solid as the microcapsule fraction increases and to be stable after heat treatment at $105^{\circ}C$ for 15 min. In conclusion, the dense suspension composed of gel microcapsules is expected to provide a basic cosmetic formulation that can be applied to develop various types of aloe gel cosmetic products.

Electrical and Rheological Properties of Colloidal of Alumina Suspensions

  • Wang, Xu-Hong;Yoshihiro Hirata
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 2000.06a
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    • pp.215-232
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    • 2000
  • The Valence(Z) of positively and negatively charged alumina particles in the dilute suspensions was analyzed with the electrical conductivity of the suspensions. The mobility of negative particles was lower than that of positive particles at a similar Z value because of the stronger effect of chemical bonding over the hydrated particle surfaces. The apparent viscosity of acidic suspensions of 1-40 vol % solid was lower than that of basic suspensions. This result was discussed based on the three important effects of the valence, concentration and nature of hydrated surface of alumina particles. The density of alumina compacts consolidated by filtration through gypsum molds became lower for the basic suspensions than for the acidic suspensions. This result was correlated to the properties of the colloidal alumina suspensions.

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Effects of Suspension Composition on Defects in Aqueous Tape Casting of Alumina Ceramics: A Rheological Study

  • Shin, Hyo-Soon
    • Journal of the Korean Ceramic Society
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    • v.42 no.1
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    • pp.1-6
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    • 2005
  • In aqueous alumina tape casting, the effects of altering the composition of the suspensions, the binders and the casting thickness were studied. The rheological behavior of the suspensions and the defects of the dried tapes were examined and the relationships between them are discussed. The changes in the defect regions reported in the previous paper were related with the rheological properties with variations of the binder, the composition and the casting thickness. The shear thinning factor increased with the organic content and the solid content (the decrease of water content). The apparent viscosity increased with the shear thinning factor. The relation between the shear thinning factor and the log apparent viscosity was similar for all binder types. In the relation between the defect free region and the rheological properties, the defect free region became narrower with increasing casting thickness. The defect free region is independent of binder type. Therefore, the thicker tape is more difficult to produce in aqueous alumina tape casting. Knowledge of the rheological properties of the suspensions could help Predict the defect type and the possibility of defect free dried tapes.

Numerical simulation of dynamic segregation of self-consolidating concrete (SCC) in T-box set-up

  • Hosseinpoor, Masoud;Khayat, Kamal H.;Yahia, Ammar
    • Computers and Concrete
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    • v.20 no.3
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    • pp.297-310
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    • 2017
  • A CFD software was used to simulate free surface flow of SCC in the T-Box test. In total, seven simulations were developed to study the effect of rheological parameters on the non-restricted flow performance of SCC in both horizontal and vertical directions. Different suspending fluids having five plastic viscosity values between 10 and 50 Pa.s, three yield stress values between 14 and 75 Pa, one density of $2500kg/m^3$, and one shear elasticity modulus of 100 Pa were considered for suspension of 178 spherical particles of 20-mm diameter and $2500kg/m^3$ density. The results of the simulations are found to correlate well to changes in rheological parameters of the suspending fluid. Plastic viscosity was shown to be the most dominant parameter affecting flowability and dynamic stability compared to the yield stress. A new approach was proposed to evaluate performability of SCC based on a trade-off between flowability and dynamic stability.

Micro Plishing using Electorheological fluid (ER유체를 이용한 미세 연마 가공)

  • 김욱배;이성재;박철우;이상조
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.11a
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    • pp.850-853
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    • 2000
  • It is well-known that Electro-rheological(ER) fluid is a material(suspension) which shows the dramatic change of rheological properties under an electric field. Using these properties, the concept that variable apparent viscosity of ER fluid could be applicable to the polishing for micro parts was introduced. It was investigated that how it works for polishing and how it affects ER effect when abrasives were mixed with an ER fluid. Therefore a few structures for polishing using ER fluid was suggested and evaluated by means of experiments. In this paper, fundamental mechanism and experimental results are described.

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