• Journal of Soil and Groundwater Environment
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• v.15 no.6
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• pp.37-45
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• 2010

Surfactant-enhanced ozone sparging (SEOS), an advanced version of SEAS (surfactant-enhance air sparging) was introduced in this study for the first time for removal of non-volatile contaminant from aquifer. The advantages of implementing SEAS, enhanced air saturation and expanded zone of sparging influence, are combined with the oxidative potential of ozone gas. Experiments conducted in this study were tow fold; 1-dimensional column experiments for the changes in the gas saturation and contaminant removal during sparging, and 2-dimensional box model experiment for the changes in the size of zone of influence and contaminant removal. An anionic surfactant (SDBS, sodium dodecylbenzene sulfonate) was used to control surface tension of water. Fluorescein sodium salt was used as a representative of watersoluble contaminants, for its fluorescence which is easy to detect when it disappears due to oxidative degradation. Three different gases (air, high-concentration ozone gas, and low-concentration ozone gas) were used for the sparging of 1-D column experiment, while two gases (air and low-concentration ozone gas) were used for 2-D box model experiment. When SEOS was performed for the column and box model, the air saturation and the zone of influence were improved significantly compared to air sparging without surface tension suppression, resulted in effective removal of the contaminant. Based on the experiments observations conducted in this study, SEOS was found to maintain the advantages of SEAS with further capability of oxidative degradation of non-volatile contaminants.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.09a
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• pp.215-218
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• 2004

The electrokinetically enhanced soil flushing had a great potential to improve the removal efficiency of polycyclic aromatic hydrocarbons (PAHs) from low permeable soils. A semi-pilot study of surfactant-enhanced electrokinetic process was investigated for the removal of phenanthrene from kaolinite. A nonionic surfactant, Tergitol 15-S-12 at 10 g/L was introduced as a flushing agent and 0.001M of sodium chloride was used as an electrolyte. When the constant voltage of 100 V was applied to the system for 25 days, only 0.66 kWh of electric power was consumed and the amount of electroosmotic flow was 6.9 L. The removal efficiency of phenanthrene was about 40 % and it can be improved by increasing the ion concentration of the flushing solution or the applied voltage.

• Journal of Environmental Science International
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• v.19 no.5
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• pp.549-563
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• 2010

The environmental behaviors of polycyclic aromatic hydrocarbons (PAHs) are mainly governed by their solubility and partitioning properties on soil media in a subsurface system. In surfactant-enhanced remediation (SER) systems, surfactant plays a critical role in remediation. In this study, sorptive behaviors and partitioning of naphthalene in soils in the presence of surfactants were investigated. Silica and kaolin with low organic carbon contents and a natural soil with relatively higher organic carbon content were used as model sorbents. A nonionic surfactant, Triton X-100, was used to enhance dissolution of naphthalene. Sorption kinetics of naphthalene onto silica, kaolin and natural soil were investigated and analyzed using several kinetic models. The two compartment first-order kinetic model (TCFOKM) was fitted better than the other models. From the results of TCFOKM, the fast sorption coefficient of naphthalene ($k_1$) was in the order of silica > kaolin > natural soil, whereas the slow sorbing fraction ($k_2$) was in the reverse order. Sorption isotherms of naphthalene were linear with organic carbon content ($f_{oc}$) in soils, while those of Triton X-100 were nonlinear and correlated with CEC and BET surface area. Sorption of Triton X-100 was higher than that of naphthalene in all soils. The effectiveness of a SER system depends on the distribution coefficient ($K_D$) of naphthalene between mobile and immobile phases. In surfactant-sorbed soils, naphthalene was adsorbed onto the soil surface and also partitioned onto the sorbed surfactant. The partition coefficient ($K_D$) of naphthalene increased with surfactant concentration. However, the $K_D$ decreased as the surfactant concentration increased above CMC in all soils. This indicates that naphthalene was partitioned competitively onto both sorbed surfactants (immobile phase) and micelles (mobile phase). For the mineral soils such as silica and kaolin, naphthalene removal by mobile phase would be better than that by immobile phase because the distribution of naphthalene onto the micelles ($K_{mic}$) increased with the nonionic surfactant concentration (Triton X-100). For the natural soil with relatively higher organic carbon content, however, the naphthalene removal by immobile phase would be better than that by mobile phase, because a high amount of Triton X-100 could be sorbed onto the natural soil and the sorbed surfactant also could sorb the relatively higher amount of naphthalene.

• Journal of Environmental Science International
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• v.19 no.2
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• pp.247-254
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• 2010

Ultrasound and Surfactant aided soil washing process has been shown to be an effective method to remove diesel from soils. The use of surfactants can improve the mobility of diesel in soil-water systems by increasing solubility of adsorbed diesel into surfactant micelles. However, a large amount of surfactant is required for treatment. In addition, synthetic surfactants, specially anionic, are more toxic and the surfactant wastewater is hard to treat by conventional wastewater treatments even by AOPs. Ultrasound improves desorption of the diesel adsorbed on to soil. The mechanisms are based on physical breakage of bonds by hot spot, directly impact onto soil particle surface, the fragmentation of long-chain hydrocarbons by micro-jet and microstreaming in the soil pores. The use of ultrasound as an enhancement method in both anionic and nonionic surfactant aided soil-washing processes were studied. And all experiments were examined proceeded under CMC surfactant concentration, frequency 35 khz, power 400 W, Soil-water ratio 1:3(wt%), particle size 0.24 ~ 2mm and initial diesel concentration. 20,000 mg/kg. Combination with ultrasound showed significant enhancements on all the processes. Especially, nonionic surfactant Triton-X100 with ultrasound showed remarkable enhancements and diesel removal rate enhanced by ultrasound helps desorpting of surfactant adsorbed onto soils which prevented decreasing surfactant activity.

• Proceedings of the Korean Geotechical Society Conference
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• 1999.10a
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• pp.241-246
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• 1999

In this research, electrokinetic remediation test was experimented with contaminated kaoline specimen at below, above the cation-exchange capacity of the mineral. The changes of the flow in electro-osmosis with open electrodes and current were presented, and lead removal results were evaluated through the extraction test. As a result, it was showed that removal efficiency was 20-30%, 67-87% In the anode As lead transport continues, the lead precipitation within a narrow zone very close to the cathode can go significantly high. This high lead precipitation near the cathode could block the flow path, decrease the conductivity, and thus the electroosmotic flow. The net effect will cause a decrease in the efficiency of electrokinetic processing. Therefore, in this study, citric acid and surfactant solution was used at the cathode as enhancement techniques.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1999.10a
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• pp.12-15
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• 1999

Soils collected from an agricultural field in Youngdong, Chungbuk province were intentionally: contaminated with lead and copper. The efficiencies of soil washing with HCl, SDS and Tween 80 were investigated through the column mode experiments. Washing with 0.1 N HCl obtained the best result for lead and copper removal (95.04 %, 95.94 %). In case of SDS, lead and copper removal rate was such poor as 7.1 % and copper was 24.04 %, respectively. Meanwhile, washing of contaminated soil with Tween 80, did not show any significant removal effect. It was found that the washing efficiency was dependent on pH of washing agent.

• Journal of Korea Soil Environment Society
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• v.4 no.2
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• pp.77-86
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• 1999

Partitioning of two hydrophobic organic compounds (HOCs), phenanthrene and naphthalene, to kaolinite and sorbed surfactants was studied to evaluate the feasibility of surfactant-enhanced remediation (SER) of contaminated subsurface systems. Sorbed surfactant partition coefficients. $K_ss$, showed a strong dependence on the surfactant sorption isotherms at low sorbed surfactant levels $K_ss$ values were at their highest and then decreased with increasing surfactant sorption densities. $K_ss$ values for SDS were always larger than corresponding $K_mic$values. For Tween 80, however. $K_ss$ values $K_mic$ were higher than $K_mic$ values only at the lower sorbed surfactant densities. HOC distribution between immobile and mobile phases varied with surfactant dose distribution coefficients increased initially with increasing surfactant concentrations and then decreased at higher doses. This observation shows directly the competition between sorbed and micellar surfactants for HOC partitioning. Overall results of this study demonstrate that surfactant sorption to the solid phase can lead to increases in HOC retardation in some SER applications. Therefore, before an SER process is selected, appropriate consideration of surfactant sorption and HOC partitioning to immobile versus mobile phases pertinent to a specific subsurface system must be contemplated.

• Journal of Soil and Groundwater Environment
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• v.14 no.6
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• pp.87-94
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• 2009

Surfactant-enhanced air sparging (SEAS) was developed to suppress the surface tension of groundwater prior to air sparging resulting in higher air saturation and larger contact area between NAPL and gas during air sparging. Larger contacting interface between NAPL and gas means faster mass transfer of contaminants from NAPL to gas phase. This new technique, however, is limited to relatively volatile contaminants because vaporization is its basic mechanism of mass transfer. In this study, SEAS was tested at an elevated temperature for a semi-volatile n-decane, which is expected not to be a good candidate of SEAS application due to its low vapor pressure at ambient temperature. Three sparging experiments were conducted using 1-dimensional column (5 cm id, 80 cm length) packed with sand; (1) ambient temperature ($23^{\circ}C$), column saturated with distilled water, (2) SEAS at ambient temperature ($23^{\circ}C$), for n-decane contaminated sand, (3) SEAS at elevated temperature ($73^{\circ}C$), for n-decane contaminated sand. Higher air saturation was achieved by SEAS compared to that by air sparging without surfactant application. The n-decane removal efficiency of SEAS at elevated temperature was significantly higher(> 10 times) than that of ambient SEAS. The n-decane concentrations in the gas effluent from column during SEAS at $73^{\circ}C$ are found to be 10 times of those measured at ambient temperature. Thus, SEAS technique can be applied for removal of semi-volatile contaminants provided that an appropriate technique for elevating aquifer temperature is available.

• Membrane and Water Treatment
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• v.2 no.3
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• pp.137-145
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• 2011

Membrane processes are major breakthrough for the removal of organic pollutants in water remediation. The separations of solutes depend on nature of the membranes and solutes. The separation performance depends on the nature of the solutes (i.e., molecular volume, polarity, and hydrophobicity) for the same membrane. As 4-chlorophenol is of more dipolemoment compared to 2-chlorophenol, the orientation of the molecule enables it pass through the pores of the membrane, which is of negatively charged and thus separation order follows: 2-chlorophenol > 4-chlorophenol. Hydrophobicity factor also supports the order. Addition of sodium dodecyl sulfate (SDS) to chlorophenol solution shows remarkable increase in separation performance of the membrane. The improvement in separation is 1.8 and 1.5 times for 4- and 2- chlorophenol consecutively in case of 0.0082 M SDS (1cmc = 0.0082 M) in the solution. 4-chlorophenol has better attachment tendency with SDS because of its relatively more hydrophobic nature and thus reflects in performance i.e. the separation performance of 4-chlorophenol with SDS through the membrane is better compared to 2-chlorophenol.

• Journal of Soil and Groundwater Environment
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• v.16 no.4
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• pp.31-37
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• 2011

The feasibility study of soil flushing was investigated to remediate lubricant oil and zinc contaminated railway soil. In this study, mixed washing agents of surfactant and inorganic acid/base were used for the simultaneous removal. The mixed washing agent of non-ionic surfactant and HCl removed 15% of the lubricant oil and 40% of zinc, respectively. Alkaline-enhanced soil washing process increased the removal of lubricant oil up to 40%. This is because alkaline solution reduced the interfacial tension between water phase and lubricant oil phase due to the soap formation reaction. To simulate in-situ soil flushing for the remediation of railroad-related contamination, two dimensional soil flushing was carried out based on the results of batch soil washing. In the soil flushing, the removal efficiencies of lubricant oil and zinc were 34% and 16%, respectively. Even though the removal efficiency was low, the mixed washing agent can remove metal and lubricant oil simultaneously.