• 제목/요약/키워드: Surfactant etc

검색결과 51건 처리시간 0.023초

계면활성제 농도가 빙결정의 입자크기에 미치는 영향 (Growth of Ice Crystal with Concentration of Surfactant in Water Solution)

  • 박기원;;오후류
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제26권2호
    • /
    • pp.240-247
    • /
    • 2002
  • Recently, a thermal energy storage system has been developed actively fur the purpose of saving energy and reducing the peak electrical demand. Especially, ice slurry is a promising working fluid for low temperature energy storage systems. A flow of ice crystals has a large cooling capacity as a result of the involvement of latent heat. However, there are still problems related to the recrystallization of ice crystals for realizing long term storage and long distance transportation. To find improvements fur this, a method for the creation of ice crystals resistant to recrystallization has been proposed and researched by the use of an antifreeze protein (AFP) solution etc. In the present study, it has been investigated the growth of ice crystal in several kinds of water solution added non-ionic surfactant. The results shows that size of ice crystal was smaller with increasing in added surfactant. And ice crystal was not increased with added surfactant.

다이아몬드 분말상에 무전해 Ni-B 도금을 위한 계면활성제의 영향 (Effect of Surfactant in Electroless Ni-B Plating for Coating on the Diamond Powder)

  • 양창열;유시영;문환균;이정호;유봉영
    • 한국표면공학회지
    • /
    • 제50권3호
    • /
    • pp.177-182
    • /
    • 2017
  • The properties of electroless Ni-B thin film on diamond powder with different parameters (temperature, pH, surfactant etc.) were studied. The surface morphology, structure and composition distribution of the Ni-B film were observed by field effect scanning electron microscope (FE-SEM), energy-dispersive spectrometer (EDS), X-ray diffraction (XRD) and Auger electron spectroscopy (AES). The growth rate of Ni-B film was increased with increase of bath temperature. The B content in Ni-B film was reduced with increase of bath pH. As a result the structure of Ni-B film was changed from amorphous to crystalline structure. The PVP in solution plays multi-functional roles as a dispersant and a stabilizer. The Ni-B film deposited with adding 0.1 mM-PVP was strongly introduced an amorphous structure with higher B content (25 at.%). Also the crystallite size of Ni-B film was reduced from 12.7 nm to 5.4 nm.

Formation of hydrophilic polymer films by DC-plasma of monomer and reactive gases

  • Kim, Ki-Hwan;Park, Sung-Chang;doo-Jin choi;Jung, Hyung-Jin;Koh, Seok-Keun
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 1999년도 제17회 학술발표회 논문개요집
    • /
    • pp.161-161
    • /
    • 1999
  • In the field of material science, the interests and efforts to modify the surface of materials in agreement with the need of usage have been extensively increasing. he modification to improve the wettability of surface is very important is terms of adhesion, printing, etc. It is very difficult to modify metal surface into hydrophilic one. therefore, surfactant coating has been generally used in many cases. However, surfactant has disadvantages such as environmental problem, soluble in water. in this study, hydrophilic polymer films as alternative of surfactant were deposited on metal substrate by DC plasma polymerization. Hydrophilic polymer films deposited by DC plasma show many merits such as good wettability, stone adhesion to substrate, high resistance to most chemicals. Monomer gas and reactive gas were used as source plasma polymerization. Plasma polymerized films were fabricated with process parameters of deposition time, ratio of gas mixture, current, pressure, etc. Effects of these variables on wettability of plasma polymer films will be discussed. With XPS and FT-IR analyses of plasma polymeric films, the relation between wettability and chemical state of polymer films by DC plasma was investigated.

  • PDF

분해성 계면활성제에 관한 연구(제2보);1, 3-Dioxlane고리를 갖는 분해성계면활성제의 합성 (Studies on the Destructible Surfactants(2);Surface-Active Properties of Cleavable Surfactant with 1, 3-Dioxolane Ring)

  • 김진현;하재웅;정노희;남기대
    • 한국응용과학기술학회지
    • /
    • 제12권1호
    • /
    • pp.101-107
    • /
    • 1995
  • 케탈이나 아세탈반응에 의하여 이루어진 1, 3-디옥솔란 고리가 산수용액 중에서 불안정해 쉽게 가수분해되는 성질을 이용하여 소수부로는 지방산의 탄화수소사슬을 친수부로는 소디움 카르복시산(Soap)을 도입하여 분해 후 계면활성을 띠지 않는 분해성 계면활성제이다. 이 화합물의 수용액에 대한 표면장력은 31dyne/cm였고, 임계미셀농도는 $1.0{\times}10^{-3}mol/L$이었다. 기포력은 비교적 좋지 않았으며, 유화력은 콩기름보다 벤젠에서 양호하였다. 또한 이 화합물의 산분해 특성을 1wt% 수용액과 벤젠 사이의 계면장력 변화에 의하여 측정한 결과 pH 1 ${\sim}$ 4범위에서 약 300분 안에 모두 가수분해됨을 확인하였다.

저공해 합성세제의 성분 분석 및 생분해성 (Ingredient Analysis & Biodegradability to the Low Pollution Synthetic Detergent)

  • 김용인;소희준;선일식
    • 한국응용과학기술학회지
    • /
    • 제8권2호
    • /
    • pp.133-143
    • /
    • 1991
  • As the result of the qualitative and quantitative analysis of the surfactant mixture, the main surfactant of the fast biodegradable detergent which were derived from vegetable oil was Sodium Lauryl Sulfate. The Detergents contained sodium lauryl sulfate, nonionic surfactant, soap, etc, as the rest sufactants. Linear Alkylbenzene Sulfonate and ${alpha}-Olefin$ Sulfonate which were derived from petroleum were not detected. The biodegradation rate of the detergent prepared from vegetable oil was faster than that of the detergent derived from petroleum stood in 7 days.

자성 유체의 특성 및 응용 (What is Magnetic Fluid\ulcorner)

  • 이효숙
    • 한국재료학회지
    • /
    • 제12권4호
    • /
    • pp.264-268
    • /
    • 2002
  • Magnetic fluid is a very stable colloid that is attracted by magnetic force as wholly. The magnetic fluids is composed with 10 nm magnetic materials such as magnetite, iron etc., which is dispersed homogeneously in solvent by coating surfactant on their surface. Also this colloid is not separated into magnetic particles and solvent even under magnetic field, centrifugal force, gravity. Due to these properties, the magnetic fluids is used in high vacuum seal, exclusion seal, damper, etc. I would like to introduce the specific properties and applications of the magnetic fluids.

계면활성제 유발 건성피부의 기저층, 피지선에 대한 Chamomile, Thyme essential oil의 유효성 연구 (A Study on Efficiency of Chamomile and Thyme Essential Oil About the Basal Layer & Sebaceous Gland in Dry-skin Induced by Surfactant)

  • 장명옥;최정숙
    • 한국패션뷰티학회지
    • /
    • 제3권2호
    • /
    • pp.12-17
    • /
    • 2005
  • Efficiency study of chamomile and Thyme essential oil about the basal layer & sebaceous gland in dry-skin induced by surfactant is as following : 1. Formal observation of outer skin layer and basal layer There was refreshing effects about Surfactant induction skin inflammation in Chamomile, Thyme essential oil processing group but effect in surface layer appeared by higher thing in Chamomile essential oil and it could know that thing which do not use Thyme essential oil in case Thyme essential oil is ultraviolet rays allergy at skin care because Melanocyte appear on the surface is bigger than Chamomile essential oil that it was usefully reaction in basal layer. 2. Formal observation result of sebaceous glands. There are few damages in all group but there is recuperative through excessive water damage by excessive a sebaceous gland made of mulberry bark secretion because Thyme essential oil application group cause chapped skin phenomenon after surface-active agent processing but is seen that difference does not exist greatly and Thyme essential oil that general skin is strong in permeation is effective, but Surfactant induction skin inflammation estimates that Chamomile essential oil is effective. Therefore, it was considered that use of Chamomile essential oil is effectiveness than Thyme essential oil by essential oil used for recovery after damage of inflammation etc..

  • PDF

식물유계 EP그리스의 생분해도 평가에 관한 연구 (A study on Biodegradability of Vegetable Oil based EP Grease)

  • 남경임;김영운;정근우;조원오;전인식;정용미
    • 한국윤활학회:학술대회논문집
    • /
    • 한국윤활학회 2003년도 학술대회지
    • /
    • pp.139-148
    • /
    • 2003
  • In this study, biodegradable base Li-greases were prepared by using Li-soap thickener and vegetable oils such as soybean oil, rapeseed oil, castor oil and synthetic ester. Also, EP-greases were formulated by blending base Li-greases, anti-wear additives, EP additives, anti-oxidants and corrosion inhibitor etc. And EP-greases were characterized by analysing physical properties such as worked penetration, dropping point, 4-ball wear, extreme pressure, thermal properties etc. Biodegradability of base Li-greases and EP-greases were evaluated by CEC-L-33-A-93 method using several inoculums of domestic sewage treatment plant. As the results, biodegradability of vegetable oils were shown at the range of 97.1 to $98.4\%$. And biodegradability of base Li-greases and EP-greases were $86.2\%\;\~\;89.3\%\;and\;83.4\%\;\~\;90.0\%$ which were lower value than those o( vegetable oils due to effect of Li-soap thickener, respectively. Therefore, the EP-greases prepared in this study were easily biodegraded by microorgnism.

  • PDF

분해성계면활성제에 관한 연구(제1보);1,3-Dioxlane고리를 갖는 분해성계면활성제의 합성 (Studies on the Destructible Surfactants(1);Synthesis of Cleavable Surfactant with Dioxolane Ring)

  • 하재웅;정노희;김진현;남기대
    • 한국응용과학기술학회지
    • /
    • 제12권1호
    • /
    • pp.93-99
    • /
    • 1995
  • 미셀반응, 유화중합, 상간이동촉매반응 등에 이용되는 계면활성제가 갖고 있는 문제점을 해결하기 위하여 반응 후 분해되는 분해성 계면활성제를 합성하였다. 케탈이나 아세탈반응에 의하여 이루워진 1,3-디옥솔란 고리가 산수용액 중에서 불안정해 쉽게 가수분해로 계면활성을 띠지 않는 분해성 계면활성제를 합성하였다. 합성된 화합물은 백색결정상태로 얻었으며 수율은 90% 이상이었다. 그리고 이 화합물과 중간생성물은 얇은막 크로마토그래피와 컬럼 크로마토그래피로 분리하여 적외선과 수소핵자기공명 및 원소분석 스텍트라로 그 화합물들의 구조를 확인하였다.

Organic Precipitate Flotation of Trace Metallic Elements with Ammonium Pyrrolidinedithiocarbamate (II). Application of Solvent Sublation for Determination of Trace Cd, Co, Cu and Ni in Water Samples

  • 김영상;정용준;최희선
    • Bulletin of the Korean Chemical Society
    • /
    • 제19권1호
    • /
    • pp.50-56
    • /
    • 1998
  • A solvent sublation was studied for the determination of trace Cd, Co, Cu and Ni in water samples. Ammonium pyrrolidine dithiocarbamate (APDC) was used as a complexing agent. Experimental conditions such as pH of solution, amounts of APDC, the type and amount of surfactant, the type of solvent, etc. were optimized for the effective sublation of analytes. After metal-PDC complexes were formed in sample solutions of pH 2.5, the precipitate-type complexes were floated in a flotation cell with an aid of sodium lauryl sulfate as a surfactant and by bubbling with nitrogen gas. The precipitates were dissolved and separated into the surface layer of methyl iso-butyl ketone (MIBK). The analytes preconcentrated were determined by a graphite furnace atomic absorption spectrophotometry (GF-AAS). Extractability of each element was 88% for Cd(Ⅱ), 86% for Co(Ⅱ), 95% for Cu(Ⅱ) and 76% for Ni(Ⅱ), respectively. And this procedure was applied to the analysis of real samples. From the recoveries of more than 92%, it was concluded that this method could be simple and applicable for the determination of trace elements in various water samples of a large volume.