• Title/Summary/Keyword: Surface treatment of Cu

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The Dissolution Characteristics of Metal Compounds in Soil Application Experiment using Sewage Treatment Sludge mixed with Oyster shells (하수슬러지 및 굴껍질의 토지주입시 금속성분의 용출특성에 관한 연구)

  • Kim, Chul;Moon, Jong-Ik;Shin, Nam-Cheol;Ha, Sang-An;Sung, Nak-Chang;Huh, Mock
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.2
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    • pp.71-76
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    • 2001
  • Recently, sludge disposal becomes one of the most serious environmental problems. Because the landfilling and ocean dumping of sludge materials will be prohibited in the near future, the proper treatment?disposal methods should be investigated. Also, oyster shells, piled at the coast, cause adverse effects in coastal fishery, public water surface, natural landscape, public health and so on. Thus, the purpose of this study is to evaluate the dissolution characteristic of metal compounds during soil application experiment using sewage treatment sludge mixed with oyster shells. The dissolution experiment conducted 100days under artificial rainfall and farming soil, mixed with sewage treatment sludge and oyster shells, was put into the pots(approx. 0.5L). The results from dissolution experiment as follows. 1. K, Na was $5{\sim}20mg/{\ell}$, and Ca was less than $90mg/{\ell}$. 2. Heavy metals such as Cd, Cu, As, Pb, Cr, Hg are dissoluted far less than the soil pollution guideline. The application of sewage sludge mixed with oyster shells increases pH(soil acidity)and buffer capacity(CEC) of farming soil, and heavy metals are thought to be attached to soil as insoluble forms.

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Effect of the Retained Austenite Content on the Wear Resistance of Austempered Ductile Iron (오스템퍼드 구상흑연주철의 마멸 특성에 미치는 잔류 오스테나이트 영향에 관한 연구)

  • Kim, Hong-Beom;Joo, Do-Jae;Choi, Chang-Ock
    • Journal of Korea Foundry Society
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    • v.16 no.6
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    • pp.503-512
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    • 1996
  • Austempered ductile irons(ADI) are characterized by their relatively high retained austenite content which has a significant effect on mechanical properties and performance, such as ductility, toughness, wear resistance and machinability. Austenitising treatment at $900^{\circ}C$ for $1{\sim}2hours$, and austempering treatment within the temperature range $240{\sim}400^{\circ}C$ on ductile cast iron alloyed with Cu and Mo were carried out, and the effects of retained austenite content on the mechanical properties and wear resistance were investigated. In consequence, the amount of retained austenite was found to be 13.5% at the austempering temperature of $240^{\circ}C$, and was increased 28% at $400^{\circ}C$. Tensile strength and hardness of austempered ductile iron were decreased as the retained austenite content increased, but elongation was increased. The retained austenite content at the austenitising time of 2hours was more than at 1hour. The amounts of rolling wear loss were increased as the retained austenite content increased, and the wear surface was become to be rough.

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Removal of Heavy Metals Through Conventional Water Treatment Processes (정수처리 과정에서의 중금속제거에 관한 연구)

  • 김중구;고영송;남상호
    • Journal of Environmental Health Sciences
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    • v.20 no.4
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    • pp.36-44
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    • 1994
  • A study was carried out in order to investigate the removal efficiencies and removal characteristics of heaw metals such as Pb, Cd, Cr, Cu in raw water by one of conventional water treatment processes. The coagulants used in this study were Alum and PAC. Three kinds of water samples were provided: kaolin water, kaolin water mixed with humic acid and raw water from Han River mixed with suspended matter deposited on raw water inlet pipe. Heaw metals were added to the water samples with their respective turbidity, and jar tests were performed. In the results from heaw metal removal studies, lead might be adsorbed or exchanged on the particle surface (SS) rather than react with organic matter added. Cadmium was affected on the dissolved organic matter. Chromium was affected by the both dissolved organic matter and SS concentration, and the restabilization and the enmeshment appeared at moderate (50~80 NTU) and high (100 NTU) turbidity as defined in this experimenL The removal efficiency of copper was relatively little affected by the dissolved organic matter but by SS concentration in comparison with other heavy metals. In these studies as to the raw water turbidities and concentration of heaw metals, it is proved out that the removal efficiency on heaw metals in both cases of PAC and Alum as coagulants was not significantly different.

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Fabrication of the interface-treated ramp-edge Josephson junctions using Sr$_2AlTaO_6$ insulating layers (Sr$_2AlTaO_6$ 절연막을 이용한 계면처리된 경사형 모서리 조셉슨 접합의 제작)

  • Choi, Chi-Hong;Sung, Gun-Yong;Han, Seok-Kil;Suh, Jeong-Dae;Kang, Kwang-Yong
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.63-66
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    • 1999
  • We fabricated ramp-edge Josephson junctions with barriers formed by interface treatments instead of epitaxially grown barrier layers. Low-dielectric Sr$_2AITaO_6$(SAT) layer was used as an ion-milling mask as well as an insulating layer for the ramp-edge junctions. An ion-milled YBa$_2Cu_3O_{7-x}$ (YBCO)-edge surface was not exposed to solvent through all fabrication procedures. The barriers were produced by structural modification at the bottom YBCO edge using plasma treatment prior to deposition of the top YBCO electrode. We investigated the effects of pre-annealing and post-annealing on the characteristics of the interface-treated Josephson junctions. The junction parameters were improved by using in-situ RF plasma cleaning treatment.

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Fabrication of TFA-MOD YBCO Films Using Y2Ba1Cu1Ox Process (Y2Ba1Cu1Ox공정을 이용한 TFA-MOC YBCO 박막 공정 개발)

  • Lim, Jun-Hyung;Jang, Seok-Hern;Kim, Kyu-Tae;Lee, Jin-Sung;Yoon, Kyung-Min;Ha, Hong-Soo;Joo, Jinho;Nah, Wansoo
    • Journal of the Korean Ceramic Society
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    • v.43 no.2 s.285
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    • pp.98-105
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    • 2006
  • YBCO film was synthesized by using a new approach to the TFA-MOD method. In the fabrication process, $Y_2Ba_1Cu_1O_x\;and\;Ba_3Cu_5O_8$ powders were used as precursors (the so called '211 process'), instead of Y-, Ba-, and Cu-based acetates, and dissolved in trifluoroacetic acid followed by calcining and firing heat treatment. Consequently, we successfully fabricated YBCO film and evaluated the phase formation, texture evolution, and critical properties as a function of the calcining and firing temperature and humidity, in order to explore its possible application in coated conductor fabrication. The films were calcined at $430-460^{\circ}C$ and then fired at $750-800^{\circ}C\;in\;a\;0-20\%$ humidified $Ar-O_2$ atmosphere. We observed that $BaF_2$ phase was effectively reduced and that a sharp and strong biaxial texture formed under humidified atmosphere leading to increased critical properties. In addition, we found that the microstructure varied significantly with the firing temperature: the grain grew further, the film became denser, and the degree of texture and phase purity varied as the firing temperature increased. For the film fired at $775^{\circ}C$ after calcining at $460^{\circ}C$, the critical current was obtained to be 39 A/cm-width (corresponding critical current density is $2.0\;MA/cm^2$ which was probably attributed to such factors as the enhanced phase purity and out-of-plane texture, the moderate film density and grain size, and crack-free surface.

A Preliminary Study on the Feasibility of Copper Mesh as an Off-Gas Iodine Capturing Medium for Pyroprocessing (파이로프로세싱 배기체 요오드 포집을 위한 구리메쉬 적용 가능성에 대한 기초연구)

  • Jeon, Min Ku;Lee, Tae Kyo;Choi, Yong Taek;Eun, Hee-Chul;Choi, Jung Hoon;Park, Hwan-Seo;Hur, Jin-Mok;Ahn, Do-Hee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.13 no.3
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    • pp.235-242
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    • 2015
  • A commercially available copper mesh was investigated as an iodine off-gas capturing medium for pyroprocessing, with an aim to replace costly silver based adsorbents. Theoretical calculation results suggested that the reaction between metallic copper and gaseous iodine will occur spontaneously to produce copper iodide in the temperature range of 100 ~ 500℃. The effect of the reaction temperature on iodine capturing efficiency was investigated by experimentation, and it was found that 5 and 6 wt% of iodine (initial mass 2.0 g) was captured by a single copper mesh (0.26 g) at 300 and 400℃, respectively. The repeated experimental results also suggested that copper utilization can be increased with the help of the spontaneous detachment of the reaction product (CuI) from a copper mesh. The formation of the CuI phase was confirmed using the X-ray diffraction technique, and the surface morphology of the reaction product was observed using scanning electron microscopy.

Development of a COD(Chemical Oxygen Demand) Sensor Using an Electrode-surface Grinding Unit (전극표면 연마 유니트를 이용한 전기화학적 COD측정용 센서의 개발)

  • Yoon, Seok-Min;Choi, Chang-Ho;Park, Byung-Sun;Jin, Gil-Joo;Jeong, Bong-Geun;Hyun, Moon-Sik;Park, Jong-Man;Lee, Seung-Sun;Yi, Dong-Heui;Kim, Hyung-Joo
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.4
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    • pp.453-458
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    • 2006
  • An electrochemical COD(Chemical Oxygen Demand) sensor using an electrode-surface finding unit has been constructed. The electrolyzing(oxidizing) action of copper on the organic species was used as the basis of the COD measuring sensor. Using a simple three electrode cell, organic species which has been activated by the catalytic action of copper is oxidized at a working electrode, poised at a positive potential. A novel modification of the above method allowed for extended use of the electrode, in which the action of the electrode is regenerated by an electrode-surface grinding unit. When samples obtained from a wastewater treatment factory were measured, a linear correlation($r^2=0.93$) between the measured value(EOD) and $COD_{Mn}$ of the samples was observed. Overall results indicated that the electrochemical sensor with grinding unit could be applied for continuous measurements of COD in practical fields.

Comparison of Pollutant Removal Efficiency in Road Sediment with Media Using Filter Separator (필터 분리기를 이용한 여재별 도로퇴적물의 오염물질 제거효율 비교)

  • Bang, Ki-Woong;Lee, Jun-Ho;Choi, Chang-Su;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.3
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    • pp.332-340
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    • 2007
  • Storm runoff from road contains significant loads of particulate and dissolved solids, organic constituents and metal elements. Micro particle is important when considering pollution mitigation because pollutant metal and organics have similar behavior with particles. The objective of this research is to evaluate the hydrodynamic filter separator performance for road storm runoff treatment. A various types of media such as perlite, granular activated carbon, zeolite were used for column test packing media and filter separator, and to determine the removal efficiency with various surface loading rate. As the results of column test, the highest SS removal efficiency was using mixed media(granular activated carbon, zeolite and perlite), and granular activated carbon mixed with zeolite has higher heavy metal removal efficiency than perlite. In laboratory scale hydrodynamic filter separator study, the operation ranges of surface loading rates were from 192 to 1,469 $m^3/m^2/day$. The estimated overall removal efficiencies of hydrodynamic filter separator for typical storm runoff were SS 48.1%, BOD 31.9%, COD 32.6%, TN 15.5%, and TP 17.3%, respectively. For the case of heavy metals, overall removal efficiencies were Fe 26.0%, Cu 19.4%, Cr 25.7, Zn 16.6%, and Pb 15.0%, respectively. The most appropriate medium for hydrodynamic filter separator was perlite mixed with granular activated carbon to treatment of road storm runoff.

The Effect of Mordant on the Mechanical Properties and Primary Hand Values of Fabrics Dyed with Bamboo and Pine Leaf Extracts (매염제 처리가 대나무잎과 솔잎 추출물로 염색한 직물의 물성 및 태에 미치는 영향)

  • Lee, Jung-Soon;Woo, Hyo-Jung;Jung, Go-Eun
    • Fashion & Textile Research Journal
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    • v.14 no.4
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    • pp.648-659
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    • 2012
  • This research categorizes fundamental data needed to develop eco-friendly fabrics treated with bamboo leaf & pine leaf extracts. The effect of mordant on those fabrics was analyzed through the measurement of mechanical properties and the estimation of primary hand values for cotton and silk fabrics dyed with bamboo leaf and pine leaf extracts that were later treated with various mordants. When cotton was dyed with bamboo leaves and pine leaves extracts, EM, WT, 2HB, 2HG, 2HG5, LC, T, and W increased however, RT, SMD, and RC decreased compared to raw cotton fabric. The B, G, and MIU increased after mordant treatment to the dyed cotton and resulted in a stiffer and rougher cotton's hand. EM, WT, RT, MIU, WC, T, and W increased (in terms of silk); however, LT, B, 2HB, G, 2HG, 2HG5, MMD, SMD, and LC decreased compared to raw silk fabric. Similar to the dyed cotton, mordant treatment increased the MIU and LC of dyed silk subsequently, the hand became stiffer and rougher. A greater tannin adsorption results in an increased mechanical property and the primary hand value. For both fabrics, mordant treatment made its smoothness drop. However, the scale of drop for cotton was significant, while the scale of the drop for silk was minor. In terms of type of mordant, femordant and natural-mordant treatment influenced the tensile, shear, surface properties of fabrics, and primary hand values more than Cu-mordant and synthetic-mordant in addition, this increased the stiffness, hardness, and roughness of fabrics.

Effect of heating rate on calcination heat treatment of YBCO thin films by DCA-MOD method (DCA-MOD 법으로 YBCO 박막 제조시 하소열처리의 승온속도 효과)

  • Kim, Byeong-Joo;Kim, Hye-Jin;Cho, Han-Woo;Kwon, Youn-Kyung;Ryu, Jung-Hee;Lee, Hee-Gyoun;Hong, Gye-Won
    • Progress in Superconductivity
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    • v.8 no.2
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    • pp.186-192
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    • 2007
  • High $J_c\;YBa_2Cu_3O_{7-x}$ superconducting films have been fabricated $LaAlO_3(100)$ substrate by MOD method using dichloroacetic acid(DCA) as chelating solvent for preparing precursor solution. Heating rate was varied in order to optimize the calcination heat treatment condition in DCA-MOD method. Coated films were calcined at lower temperature up to $500^{\circ}C$ in flowing humid oxygen atmosphere. The heating rate was calcined from $13.3^{\circ}C/min\;to\;0.28^{\circ}C/min$. Conversion heat treatment was performed $800^{\circ}C$ for 2 h in flowing Ar gas containing 1000 ppm oxygen with a humidity of 9.45%. Surface and cross sectional SEM microstructures showed that particle sizes were increased with heating rate at a calcination step. The amount of pores was increased with heating rate in the calcined films. Dense microstructure and sharp texture were developed in an YBCO films after conversion heat treatment. A high critical current density (Jc) of $1.26MA/cm^2$ (@77 K and self-field) was obtained for the YBCO film which was prepared with a heating rate of $0.28^{\circ}C/min$.

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