• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.189.2-189.2
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• 2014

The most stable adsorption structures and energies of four tautomerized forms (keto-1, enol-1, keto-2, and enol-2) of 3-methyl 5-pyrazolone (MP) adsorbed on Ge(100) surfaces have been investigated by Density Functional Theory (DFT) calculation method. Among its four tautomerized forms, we confirmed three tautomerized forms except keto-1 form show the stable adsorption structures when they adsorbed on the Ge(100)-$2{\times}1$ surface as we calculate the respective stable adsorption structures, activation barrier, transition state energy, and reaction pathways. Moreover, among three possible adsorption structures, we acquired that enol-2 form has most stable adsorption structure with O-H dissociated N-H dissociation bonding structure.

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.9
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• pp.2089-2104
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• 1995

A novel and efficient cutter path planning method for machining intricately shaped curved surfaces, called the steepest directed tree method, is presented. The curved surface is defined by triangular facets, the density and structure of which are determined by the intricacy and form accuracy of the surface. Geometrical form definition and recognition of the topological features are used to connect the nodes of the triangulated surface meshes for the successive and interconnected steepest pathways, which makes good use of end milling characteristics. The planetary cutter centers are determined to locate along smoothly changing paths and then the height values of the cutter are adjusted to avoid surface interference. Several machined examples of intersecting and intricate surfaces are presented to illustrate the benefits of the new approach. It is shown that due to more consistent geometry matching between cutter and surface(in comparison with the current CC Cartesian method) surface finish can be typically improved. Moreover, the material in concave fillets which is difficult to be removed by ball mills can be removed efficiently. The built-in positioning of cutter to avoid interference runs minutely in the sharp and discontinuous regions. The steepest upward movement of the cutter gives a stable dynamic cutting state and allows increase in the feedrate and spindle speed while remaining the stable cutting state.

• 한국연소학회:학술대회논문집
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• 2004.11a
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• pp.62-69
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• 2004

Zone conditional formulations for the Reynolds average reaction progress variable are used to derive an asymptotic expression for turbulent burning velocity. New DNS runs are performed for validation in a statistically one dimensional steady state configuration. Parametric study is performed with respect to turbulent intensity, integral length scale, density ratio and laminar flame speed. Results show good agreement between DNS results and the asymptotic expression in terms of measured maximum flame surface density and estimated turbulent diffusivity in unburned gas.

• Journal of the Korean Society of Combustion
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• v.9 no.4
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• pp.1-8
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• 2004

Zone conditional formulation for the Reynolds average reaction progress variable is used to derive an asymptotic expression for turbulent burning velocity. New DNS runs are performed for validation in a statistically one dimensional steady state configuration. Parametric study is performed with respect to turbulent intensity, integral length scale, density ratio and laminar flame speed. Results show good agreement between DNS results and the asymptotic expression in terms of measured maximum flame surface density and estimated turbulent diffusivity in unburned gas.

• Electrical & Electronic Materials
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• v.1 no.1
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• pp.70-77
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• 1988

This paper describes the influence of the electrode materials, moisture content, electrolyte density, temperature, surface state, ion absorbent on the C.T.I of phenolic resin by the I.E,C, 112 method. C.T.I are increased for electrode materials with low hydrogen overvoltage and high soluble point. Increusing moisture content of samples increased by logarithmical on the droplet number to tracking breakdown. Increasing electrolyte temperature region above 70-80(.deg.C) decreased hydrogen over-voltage, following the density changes are decreased by C.T.I=1/aD$^{2}$-bD+C.

• Bulletin of the Korean Chemical Society
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• v.35 no.3
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• pp.875-880
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• 2014

Adsorption of 4,4'-bis(mercaptomethyl)biphenyl (44BMBP) on silver nanoparticles has been investigated by surface-enhanced Raman scattering (SERS) spectroscopy. In addition, the Raman spectra of 44BMBP in solid state and in basic condition have been obtained for comparative study to elicit the characteristics of adsorption. The observed Raman and SERS spectra were analyzed comparing with the normal modes and vibrational frequencies from density functional theory (DFT) calculations performed for the feasible structures of 44BMBP molecule. On the basis of excellent agreement between the calculated and the experimental results, the molecule is found to have both the cis- and trans-forms for the mercaptomethyl groups in the solid state as well as in the basic condition. In contrast, the molecule is found to be chemisorbed on the silver surface by forming two Ag-S linkages only in the cis-form but not in the trans-form due to the steric interruption, which indicates the parallel orientation of molecules on the surface. Particularly, the spectral features in the SERS spectra such as the absence of the C-H stretching band and enhancement for the out-of-plane skeletal modes are confirmatory for the parallel geometry through ${\pi}$ interaction between the phenyl rings and the metal surface, based on the electromagnetic surface selection rule.

• Korean Journal of Materials Research
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• v.32 no.9
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• pp.396-402
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• 2022

In this study, surface roughness and interfacial defect characteristics were analyzed after forming a high-k oxide film on the surface of a prime wafer and a test wafer, to study the possibility of improving the quality of the test wafer. As a result of checking the roughness, the deviation in the test after raising the oxide film was 0.1 nm, which was twice as large as that of the Prime. As a result of current-voltage analysis, Prime after PMA was 1.07 × 10 A/cm² and Test was 5.61 × 10 A/cm², which was about 5 times lower than Prime. As a result of analyzing the defects inside the oxide film using the capacitance-voltage characteristic, before PMA Prime showed a higher electrical defect of 0.85 × 10¹² cm^-2 in slow state density and 0.41 × 10¹³ cm^-2 in fixed oxide charge. However, after PMA, it was confirmed that Prime had a lower defect of 4.79 × 10¹¹ cm^-2 in slow state density and 1.33 × 10¹² cm^-2 in fixed oxide charge. The above results confirm the difference in surface roughness and defects between the Test and Prime wafer.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.21 no.6
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• pp.530-537
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• 2008

This paper describes the results of a study on the tracking performance of outdoor insulating materials based on the rotating wheel dip test(RWDT). And, the influence of surface degradation was evaluated through such as measurement of the flashover voltage after and before tracking test, also aspects of surface degradation using scanning electron microscopy. The time to tracking breakdown of treated filled specimen is longer than untreated filled specimen. And, after the RWDT, the surface of specimen by adding untreated filler appeared heavy erosion. It was found that the addition to surface treated filler, the better tracking resistance. In the RWDT, the breakdown specimen is not affected by the dry flashover voltage, despite the fact that the surface degradation of tracking test has different state on each specimen. This suggests that wet flashover voltage play an important role in evaluating of tracking and erosion on the surface degradation in tracking test. And, the flashover voltage of specimen under wet conditions are greatly affected by the salt concentration and degree of degradation by the RWDT Because of hydrophobicity and degree of degradation by the RWDT, the flashover voltage of treated filled specimen is higher than that of untreated filled specimen. Different types of specimen may have different hydrophobicity and their surface state under contaminated conditions may not be the same.

• Water Engineering Research
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• v.3 no.1
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• pp.9-22
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• 2002

In general, two dimensionless numbers are used in predicting the front propagation rate of density currents: the densimetric Froude number and the dimensionless front velocity. The former expresses the front speed in terms of the characteristic length and reduced gravitational acceleration. Previous papers report that the range of this dimensionless number is wide. The other is the dimensionless front velocity, which is a function of the buoyancy flux per unit width. This paper presents the state of the art review of the dimensionless numbers for the front propagation rate of density currents. Values of the densimetric Froude number are found to be consistent when the proper characteristic length is used for normalization. Then, the densimetric Froude number and the dimensionless front velocity are compared by using the experimental data of density currents over a horizontal surface.

• Elastomers and Composites
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• v.36 no.3
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• pp.195-200
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• 2001

Ultraviolet photografting of acrylic acid onto low density polyethylene was characterized using XPS and contact angle measurement. Effects of surface modification at LDPE and aluminum on LDPE/Al laminate were also investigated. Contact angle decreased significantly at initial state arid tends to level off with increasing UV irradiation time. The improvement of hydrophilicity was due to the presence of acrylic acid on LDPE surface. Graft of acrylic acid onto LDPE was also identified from O1s/C1s ratios in XPS spectrum. Adhesion strength of LDPE-g-AAc/Al laminate showed about 30 times higher than LDPE/A1 system and it could be attributed to the increase of polarity of LDPE surface. Chemical treatment of Al surface using sulfuric acid/sodium dichromate also increased the adhesion strength of LDPE/Al laminate. Adhesion strength of LDPE/Al laminate decreased significantly under acetic acid.