• Title/Summary/Keyword: Surface segregation

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Effect of applied magnetic fields on oxygen transport in magnetic Czochralski growth of silicon (Czochralski 방법에 의한 실리콘 단결정 성장에서 자장에 의한 산소의 전달 현상 제어)

  • Chang Nyung Kim
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.4 no.3
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    • pp.210-222
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    • 1994
  • The characteristics of flows, temperatures, and concentrations of oxygen are numerically studies in the Czochralski furnace with a uniform axial magnetic field. Important governing factors to the flow fields include buoyancy, thermocapillarity, centrifugal force, magnetic force, diffusion and segregation coefficients of the oxygen, evaporation coefficient in the form of SiO, and ablation rate of crucible wall. With an assumption that the flow fields have reached the steady state, which means that two velocity components in the meridional plane and circumferential velocity, temperatures, electric current intensity become non-transient, then unsteady concentration field of oxygen has been analyzed with an initially uniform oxygen concentration. Oxygen transports due to convection and diffusion in the Czochralski flow field and oxygen flux through the growing crystal surface has been investigated.

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Inheritance of Diterpenes in Nicotiana tabacum L. (연초(Nicotiana tabacum L.)의 Diterpene류의 유전)

  • 금완수;정윤화;조명조
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.40 no.5
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    • pp.644-648
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    • 1995
  • This study was conducted to determine the inheritance of duvatrienediol(DVTs) and cis-abienol concentration from flesh tobacco leaves. NC744, which has a very low levels of DVTs and no cis-abienol was used as a parent in cross to TI 1068 producing a normal amount of DVTs and cis-abienol. Presence of DVTs and cis-abienol on the leaf surface was determined using thin layer chromatography(TLC). Segregation pattern from F$_2$ and BC$_2$[ (TI 1068 $\times$ NC744) $\times$ NC744J generations revealed that TI 1068 have a single dominant gene controlling DVTs and cis-abienol production. And DVTs production was inherited independently of the ability to produce cis-abienol.

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Distribution of Baryonic Matter in Dark Matter Halos: Effect of Dynamical Friction

  • Bae, Yeong-Bok;Lee, Hyung-Mok
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.1
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    • pp.47.1-47.1
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    • 2011
  • We studied the evolution of the two mass components system with NFW initial density distribution by direct integration of the Fokker-Planck equations. The low mass component is regarded the dark matter particles while the high mass component is assumed to be conglomerates of baryonic matter in order to depict the 'stars'. While the true mass ratio between these two types of particles should be extremely large, our adopted mass ratio is about 1000 beyond which the dynamical evolution and density distribution tend to converge. Since the dynamical evolution is dominated by the dynamical friction, the high mass component slowly moves toward the central part, and eventually undergoes the core collapse. The system reaches the core-collapse at about $7.1{\times}10^{-3}$ $t_{fh}$ in NFW models, where $t_{fh}$is the dynamical friction time at half-mass radius. The distribution of the high mass component is well fitted by the Sersic profiles or modified Hubble profile when the mass segregation is established. From these results, the surface brightness of elliptical galaxies may be explained by the high mass component experiencing dynamical friction by the dark matter particles. In order for the mass segregation to be effective within Hubble time, the mass of the luminous component should be greater than $10^5M_{\bigodot}$.

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Microstructure and Mechanical Properties of Twin-Roll Strip-Cast Al-5.5Mg-0.02Ti Alloy Sheet (쌍롤 박판주조법으로 제조된 Al-5.5Mg-0.02Ti합금의 미세조직 및 기계적 특성)

  • Cheon, Boo-Hyeon;Han, Jun-Hyun;Kim, Hyoung-Wook;Lee, Jae-Chul
    • Korean Journal of Metals and Materials
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    • v.48 no.5
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    • pp.387-393
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    • 2010
  • High-strength aluminum alloy sheets with high magnesium contents were fabricated by a strip caster equipped with an asymmetric nozzle, which has been proven to be effective for reducing surface defects and internal segregation. 4 mm thick as-cast sheets consisting of fine dendrites and minor $Al_{8}Mg_{5}$ segregation were hot-rolled successfully to 1 mm sheets and subsequently annealed at various temperatures. The sheet revealed the tensile strength and elongation of 306 MPa and 34%, respectively, when it was rolled at 250${^{\circ}C}$ and subsequently annealed at 475${^{\circ}C}$, which exhibits the feasibility of the practical application for autobodies. The observed mechanical properties were explained on the basis of the microstructural characteristics of the alloy sheets.

Effect of Cu on the Microstructure of Al-8Zn-2.5Mg-xCu Alloys Fabricated by Twin roll casting (박판주조법으로 제조한 Al-8Zn-2.5Mg-xCu 합금 판재의 미세조직에 미치는 Cu의 영향)

  • Dong-Guk Kim;Yong hee Jo;Yun-Soo Lee;Yong-You Kim;Hyoung-Wook Kim;Jung-Ki Kim
    • Korean Journal of Metals and Materials
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    • v.60 no.4
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    • pp.329-339
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    • 2022
  • The effect of Cu content on the microstructure and mechanical properties of Al-8.0Zn-2.5Mg-xCu (x: 0, 1, 2, 3) aluminum alloys manufactured by the twin-roll casting process was investigated. The Al-8.0Zn-2.5Mg-xCu alloy showed an increase in surface defects with increasing Cu content. This is because the amount of residual liquid in the final solidification region increased from 9.6 wt.% to 18.3 wt.% as the Cu content increased from 0Cu to 3 Cu alloy. For the 3Cu alloy, as the amount of residual liquid in the final solidification region exceeded the critical point, a large number of surface defects and internal shrinkage defect were observed. The main secondary phases of the four alloys were the T(Mg32(Al, Zn)49) and η(MgZn2) phases, and their fraction increased with Cu content. These secondary phases mainly existed in the center segregation band, and a fine η(MgZn2) phase was additionally observed. In terms of mechanical properties, as the Cu content increased, the hardness of the center matrix, secondary phase, and overall hardness increased respectively. Although the yield strength increased, the tensile strength and elongation decreased because the center segregation band was widened from 684 ㎛ to 790 ㎛ with increasing Cu content.

Influences of the Irradiation of Intense Pulsed ion Beam (IPIB) on the Surface of Ni$_3$Al Base Alloy IC6

  • Le, X.Y.;Yan, S.;Zhao, W.J.;Han, B.H.;Wang, Y.G.;Xue, J.M.;Zhang, H.T.
    • Journal of Korean Vacuum Science & Technology
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    • v.6 no.2
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    • pp.92-96
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    • 2002
  • In this paper, we treated the Ni$_3$Al based alloy samples with intense pulsed ion beams (IPIB) at the beam parameters of 250KV acceleration voltage, 100 - 200 A/cm$^2$ current density and 60 u pulse duration. We simulated the thermal-mechanical process near the surface of Ni$_3$Al based alloy with our STEIPIB codes. The surface morphology and the cross-section microstructures of samples were observed with SEM, the composition of the sample surface layer was determined by X-ray Energy Dispersive Spectrometry (XEDS) and the microstructure on the surface was observed by Transmission Electron Microscope (TEM). The results show that heating rate increases with the current density of IPIB and cooling rate reached highest value less than 150 A/cm$^2$. The irradiation of IPIB induced the segregation of Mo and adequate beam parameter can improve anti-oxidation properly of IC6 alloy. Some craters come from extraneous debris and liquid droplets, and some maybe due to the melting of the intersection region of interphase. Increasing the pulse number enlarges average size of craters and decreases number density of craters.

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Preparation of Bismuth Thin Films by RF Magnetron Sputtering and Study on Their Electrical Transport Properties (RF 마그네트론 스퍼터링을 이용한 Bismuth 박막의 제조와 그 전기적 특성 연구)

  • Kim Dong-Ho;Lee Gun-Hwan
    • Journal of Surface Science and Engineering
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    • v.38 no.1
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    • pp.7-13
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    • 2005
  • Bismuth thin films were prepared on glass substrate with RF magnetron sputtering and effects of substrate temperature on surface morphology and their electrical transport properties were investigated. Grain growth of bismuth after nucleation and the onset of coalescense of grains at 393 K were observed with field emission secondary electron microscopy. Continuous thin films could not be obtained above 473 K because of grain segregation and island formation. Hall effect measurements showed that substrate heating yields the decrease of carrier density and the increase of mobility. Resistivity of bismuth film has its minimum (about 0.7 x 10/sup -3/ Ωcm) in range of 403~433 K. Annealing of bismuth films deposited at room temperature was carried out in a radiation furnace with flowing hydrogen gas. The change of resistivity was not significant due to cancellation of the decrease of carrier density and the increase of mobility. The abrupt change of electrical properties of film annealed above 523 K was found to be caused by partial oxidation of bismuth layer in x-ray diffraction analysis.

Microstructure Characterization of the Solders Deposited by Thermal Evaporation for Flip Chip Bonding (진공 증발법에 의해 제조된 플립 칩 본딩용 솔더의 미세 구조분석)

  • 이충식;김영호;권오경;한학수;주관종;김동구
    • Journal of Surface Science and Engineering
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    • v.28 no.2
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    • pp.67-76
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    • 1995
  • The microstructure of 95wt.%Pb/5wt.%Sn and 63wt.%Sn/37wt.%Pb solders for flip chip bonding process has been characterized. Solders were deposited by thermal evaporation and reflowed in the conventional furnace or by rapid thermal annealing(RTA) process. As-deposited films show columnar structure. The microstructure of furnace cooled 63Sn/37Pb solder shows typical lamellar form, but that of RTA treated solder has the structure showing an uniform dispersion of Pb-rich phase in Sn matrix. The grain size of 95Pb/5Sn solder reflowed in the furnace is about $5\mu\textrm{m}$, but the grain size of RTA treated solder is too small to be observed. The microstructure in 63Sn/37Pb solder bump shows the segregation of Pb phase in the Sn rich matrix regardless of reflowing method. The 63Sn/37Pb solder bump formed by RTA process shows more uniform microstructure. These result are related to the heat dissipation in the solder bump.

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Microscopic Study on the Laser Surface-Melted Alloy 600

  • Lim, Yun-Soo;Cho, Hai-Dong;Kuk, Il-Hiun;Kim, Joung-Soo
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05c
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    • pp.347-352
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    • 1996
  • Studies on tile microstructural and compositional changes in sensitized Ni base Alloy 600 by laser surface melting have been carried out using TEM equipped with EDXA. The microstructure of the laser melted zone was mainly consisted of fine cells, and along the cell and grain boundaries, Cr enrichment due to its segregation was observed. Cr carbides having formed along the grain bundaries during the sensitization treatment have been completely dissloved. The cell walls were decorated with dislocations and the very tiny precipitates, found to be Ti(CN) type, were distributed randomly along the cell walls with tangled dislocations around them.

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A Brief Comment on Atom Probe Tomography Applications

  • Seol, Jae-Bok;Kim, Young-Tae;Park, Chan-Gyung
    • Applied Microscopy
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    • v.46 no.3
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    • pp.127-133
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    • 2016
  • Atom probe tomography is a time-of-flight mass spectrometry-based microanalysis technique based on the field evaporation of surface atoms of a tip-shaped specimen under an extremely high surface electric field. It enables three-dimensional characterization for deeper understanding of chemical nature in conductive materials at nanometer/atomic level, because of its high depth and spatial resolutions and ppm-level sensitivity. Indeed, the technique has been widely used to investigate the elemental partitioning in the complex microstructures, the segregation of solute atoms to the boundaries, interfaces, and dislocations as well as following of the evolution of precipitation staring from the early stage of cluster formation to the final stage of the equilibrium precipitates. The current review article aims at giving a comment to first atom probe users regarding the limitation of the techniques, providing a brief perspective on how we correctly interprets atom probe data for targeted applications.