• 제목/요약/키워드: Surface scaling

검색결과 254건 처리시간 0.024초

Corrosion Resistance of Stainless Steels Analyzed by Fractal Geometry

  • Kim, Eun-Ji;Park, Su-Jin;Heo, Jung-Ho;Shin, Heon-Cheol
    • Journal of Electrochemical Science and Technology
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    • 제1권2호
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    • pp.112-116
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    • 2010
  • Fractal property of the passivated steel surface was investigated on the basis of scaling analysis with a special focus on its relationship with corrosion resistance. For this purpose, the surface of stainless steel was intentionally oxidized under a variety of passivation conditions and its scaling property was analyzed by a triangulation method. The morphology of the passivated steel surface was satisfactorily evaluated with fractal dimension. From the chronoamperometry and impedance measurement, it proved that lower fractal dimension leads to more enhanced corrosion resistance. The higher passivity of the steel surface with lower fractal dimension was discussed in terms of active area and structural imperfection.

임계 축척 이론을 이용한 카타야마 식의 수정 (Katayama Equation Modified on the Basis of Critical-Scaling Theory)

  • 임경희
    • 한국응용과학기술학회지
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    • 제23권3호
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    • pp.185-191
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    • 2006
  • It is desirable to have an accurate expression on the temperature dependence of surface(or interfacial) tension ${\sigma}$, because most of the interfacial thermodynamic functions can be derived from it. There have been proposed several equations on the temperature dependence of the surface tension, ${\sigma}(T)$. Among them $E{\ddot{o}}tv{\ddot{o}}s$ equation and the one modified by Katayama, which is called Katayama equation, for improving accuracies of $E{\ddot{o}}tv{\ddot{o}}s$ equation close to critical points, have been most well-known. In this article Katayama equation is interpreted on the basis of the cell model to understand the nature of the equation. The cell model results in an expression very similar to Katayama equation. This implies that, although $E{\ddot{o}}tv{\ddot{o}}s$ and Katayama equations were obtained on the basis of experimental results, they have a sound theoretical background. The Katayama equation is also modified with the phase volume replaced with a critical scaling expression. The modified Katayama equation becomes a power-law equation with the exponent slightly different from the value obtained by critical-scaling theory. This implies that Katayama equation can be replaced by a critical-scaling equation which is proven to be accurate.

Carbonate scale reduction in reverse osmosis membrane by CO2 in wastewater reclamation

  • Shahid, Muhammad Kashif;Pyo, Minsu;Choi, Young-Gyun
    • Membrane and Water Treatment
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    • 제8권2호
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    • pp.125-136
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    • 2017
  • Reverse osmosis technology is being used on large scale for treatment of ground water, brackish water, wastewater and sea water. The most challenging issue in RO process is carbonate scaling which is directly linked with the efficiency and economy. Considering the natural phenomena of carbonate scaling different adaptations have been made to control scaling on the surface of RO membrane including acid dosage and antiscalant addition. As carbonate scaling is directly related with pH level of feed water, present study describes an experimental approach to reduce scaling on RO membrane by lowering the feed water pH by purging $CO_2$. In this comparative study four different conditions including control process (without any scale inhibitor), with dosage of antiscalant, with purging of $CO_2$ and with co addition of antiscalant and $CO_2$ in a feed stream line; it was established that $CO_2$ is a better appliance to reduce carbonate scaling on the membrane surface by reduce pH of feed stream. It was also observed that $CO_2$ and antiscalant mutually function better for scale control.

구연산과 염산트라싸이클린이 치근면 탈회에 미치는 효과에 대한 주사전자현미경적 연구 (SCANNING ELECTRON-MICROSCOPIC STUDY OF THE EFFECT OF CITRIC ACID AND TETRACYCLINE HCL CONDITIONING ON DISEASED ROOT SURFACE)

  • 김영;권영혁;이만섭
    • Journal of Periodontal and Implant Science
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    • 제25권1호
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    • pp.24-34
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    • 1995
  • The purpose of this study was to compare effects of demineralization of citric acid and tetracycline HCI on periodontally involved root surface. Twelve periodontally involved single rooted teeth were used. After scaling and root planing, root conditioning with citric acid and tetracycline HCI were carried and the teeth were processed scanning electron microscopic observation.The results were as follows: The scaled root surface was covered by much debris and calculus. The effect of demineralization of citric acid and tetracycline HCI was more reduced on scaling group than root planing group, because of hypermineralization of cementum surface and demineralization effect on root surface of tetracycline HCI showed tendency to reduction. The root planed group displayed more smooth root surface than scaling group, the surface was covered by smear layer, thus no exposure of dentinal tubule opening and collagen fiber, especially after root planing, citric acid and tetracycline HCl treated group showed exposure of dentinal tubule and collagen fiber, thus it was thought that new connective tissue attachment could be acquired.

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광물질혼화재를 적용한 콘크리트의 스케일링 저항성 평가 (Scaling Resistance of Cement Concrete Incorporating Mineral Admixtures)

  • 이승태;박세호
    • 한국도로학회논문집
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    • 제17권2호
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    • pp.47-53
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    • 2015
  • PURPOSES: The scaling of a concrete surface caused by the combined effects of frost and de-icing salts is one of the main reasons for the need to repair transportation infrastructures in cold-climate regions. This study describes the results of attempts to determine the scaling resistance of concrete incorporating mineral admixtures such as fly ash, GGBFS, and silica fume, and subjected to the actions of frost and salt. METHODS : Conventionally, to evaluate the fundamental properties of concrete, flexural and compressive strength measurements are regularly performed. Based on the ASTM C 672 standard, concrete is subjected to 2%, 4%, and 8% $CaCl_2$ salt solutions along with repeated sets of 50 freeze/thaw cycles, and the scaling resistance was evaluated based on the mass of the scale and a visual examination. RESULTS : It was observed that silica fume is very effective in enhancing the scaling resistance of concrete. Meanwhile, concrete incorporating GGBFS exhibited poor resistance to scaling, especially in the first ten freeze/thaw cycles. However, fly ash concrete generally exhibited the maximum amount of damage as a result of the frost-salt attack, regardless of the concentrations of the solutions. CONCLUSIONS: It can be concluded that the scaling resistance of concrete is highly dependent on the type of the mineral admixture used in the concrete. Therefore, to provide a durable concrete pavement for use in cold-climate regions, the selection of a suitable binder is essential.

침투형 Nano-Coat를 이용한 콘크리트 열화 방지 적용성 평가 (Evaluation of Applicability of penetrating-type Nano-Coat for Preventing Deterioration of Concrete)

  • 이준희;김조순;심양모;이승우
    • 한국도로학회논문집
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    • 제19권2호
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    • pp.7-15
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    • 2017
  • PURPOSES : Infiltration of moisture, polluted material, and deicer into concrete, accompanied by freeze and thaw can cause significant deterioration of concrete pavement. In order to protect concrete from deterioration, it is necessary to prevent the infiltration of these concrete external materials. The moisture-repellent agent, which is a surface treatment and maintenance material added to concrete structures to render them water resistant, has advantages such as prevention of water infiltration and security against air permeation. Nano-coat, which is referred to as silicon hydride, is typically used as a moisture-repellent agent. Therefore, in this study, an attempt is made to use penetration-type Nano-coat as an alternative in order to evaluate its applicability through environmental resistance tests. METHODS : This study aimed to evaluate the applicability of penetration-type Nano-coat, which can provide water repellency to concrete, in concrete pavements, through various environmental resistance tests such as freezing and thawing resistance, chloride ion penetration resistance, and surface scaling resistance tests. The applicability of penetration-type Nano-coat was demonstrated based on the specification of KS F 2711, KS F 2456, and ASTM C 672. RESULTS :In the case of penetration-type Nano-coat applied on sound concrete, an increase in concrete durability was demonstrated by the negligible chloride ion penetrability and the absence of scaling, as revealed by visual observation of the surface, after 50 cycles of scaling resistance test. In addition, test result of the application of penetration-type Nano-coat on deteriorated concrete established that concrete surface pretreated by grinding provided improved durability than non-treated concrete. CONCLUSIONS :This study indicates that penetration-type Nano-coat is applicable as an effective alternative, to increase the durability of concrete structures. In addition, it was known that pretreatment of deteriorated concrete surface, such as grinding, is required to improve the long-term performance of concrete pavement.

아르곤 레이저 조사시 치근면 변화에 관한 주사 전자 현미경적 연구 (The Effects of the Argon Laser Irradiation on the Root Surface : A Scanning Electronic Microscopic Study)

  • 은희종;임성빈;정진형
    • Journal of Periodontal and Implant Science
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    • 제29권4호
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    • pp.861-872
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    • 1999
  • Since pathologic changes of exposed root surface inhibit cell attachment and new attachment of connective tissue have been made, many efforts were apply to change the exposed root surface condition. Scaling and root planing can not remove the endotoxin completely and forms the smear layer which prohibits the new attachment of connective tissue. Therefore, many kinds of chemicals were used for controlling the pathologic change of the root surface. The purposes of this study was to compare and observe the changes of the exposed root surface treated by scaling and root planning, Tetracycline HCl and Argon Laser. After the scaling and root planning of ten extracted premolars, the differences & the root surface among groups were observed under SEM. Control group showed smear layer and irregular amorphous surface. The dentinal tubule was not exposed. The debris and scale like texture were also observed. Tetracycline HCl treated group showed relatively smooth surface and the collagen fiber was observed in the dentinal tubule. Argon Laser treated group showed the most effective results under the conditions of 0.8 to 1.0w irradiation for 0.5 to 1.0 sec with pulse wave. The results of this study showed that the root surface change was associated with the intensity and the duration of Argon Laser irradiation. Further investigation for the surface change with the Argon Laser irradiation is recommended for understanding of clinical effect.

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Application of the Scaling Law for Swept Shock/Boundary-Layer Interactions

  • Lee, Yeol
    • Journal of Mechanical Science and Technology
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    • 제17권12호
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    • pp.2116-2124
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    • 2003
  • An experimental study providing additional knowledge of quasi-conical symmetry in swept shock wave/turbulent boundary-layer interactions is described. When a turbulent boundary layer on the flat plate is subjected to interact with a swept planar shock wave, the interaction flowfield far from fin leading edge has a nature of conical symmetry, which topological features of the interaction flow appear to emanate from a virtual conical origin. Surface streakline patterns obtained from the kerosene-lampblack tracings have been utilized to obtain representative surface features of the flow, including the location of the virtual conical origin. The scaling law for the sharp-fin interactions suggested by previous investigators has been reexamined for different freestream Mach numbers. It is noticed that the scaling law reasonably agrees with the present experimental data, however, that the law is not appropriate to estimate the location of the virtual conical origin. Further knowledge of the correlation for the virtual conical origin has thus been proposed.

햅틱인터페이스를 이용한 나노스케일 가상표면에서의 나노리소그래피 (Nanolithography Using Haptic Interface in a Nanoscale Virtual Surface)

  • 김성관
    • 한국표면공학회지
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    • 제39권2호
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    • pp.64-69
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    • 2006
  • Nanoscale task such as nanolithography and nanoindenting is a challenging work that is beyond the capabilities of human sensing and precision. Since surface forces and intermolecular forces dominate over gravitational and other more intuitive forces of the macro world at the nanoscale, a user is not familiar with these novel nanoforce effects. In order to overcome this scaling barrier, haptic interfaces that consist of visual and force feedback at the macro world have been used with an Atomic Force Microscope (AFM) as a manipulator at the nanoscale. In this paper, a nanoscale virtual coupling (NSVC) concept is introduced and the relationship between performance and impedance scaling factors of velocity (or position) and force are explicitly represented. Experiments have been performed for nanoindenting and nanolithography with different materials in the nanoscale virtual surface. The interaction forces (non contact and contact nanoforces) between the AFM tip and the nano sample are transmitted to the operator through the haptic interface.

Tethered DNA shear dynamics in the flow gradient plane: application to double tethering

  • Lueth, Christopher A.;Shaqfeh, Eric S.G.
    • Korea-Australia Rheology Journal
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    • 제19권3호
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    • pp.141-146
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    • 2007
  • We examine the wall contact of a $3\;{\mu}m$ tethered DNA chain's free end under shear with a focus on developing schemes for double-tethering in the application of making scaffolds for molecular wires. At this scale our results are found to be highly dependent on small length scale rigidity. Chain-end-wall contact frequency, mean fractional extension deficit upon contact, and standard deviation in extension upon contact are examined for scaling with dimensionless flow strength, Wi. Predictions made using a one dimensional approximation to the Smoluchowski equation for a dumbbell and three dimensional dumbbell simulations produce extension deficit, standard deviation, and frequency scaling exponents of -1/3, -1/3, and 2/3, respectively whereas more fine-grained Kratky-Porod (KP) simulations produce scaling exponents of -0.48, -0.42, and 0.76. The contact frequency scaling of 2/3 is derived from the known results regarding cyclic dynamics Analytical scaling predictions are in agreement with those previously proposed for ${\lambda}-DNA$. [Ladoux and Doyle, 2000, Doyle et al., 2000]. Our results suggest that the differences between the dumbbell and the KP model are associated with the addition of chain discretization and the correct bending potential in the latter. These scaling results will aide future exploration in double tethering of DNA to a surface.