• 제목/요약/키워드: Surface pollutant

검색결과 377건 처리시간 0.035초

황화물 측정용 가스센서의 연구개발 (Development and research of gas sensor for monitoring sulfur compounds)

  • 김기영;김종민;함영환;장용근;김종득;장상목
    • 센서학회지
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    • 제3권2호
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    • pp.33-39
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    • 1994
  • 냄새물질 특히, 환경오염물질의 측정을 위한 수정진동자를 이용한 센서 시스템을 수정진동자 표면에 여러가지 인지질과 활성탄 그리고 납계열 무기안료를 피막시켜 만들었다. 포스파티딜 콜린을 누적한 9MHz 수정진동자의 각종 유기가스에 대한 응답 특성을 살펴보았다. 인지질막의 특성에 기초한 서로 다른 냄새물질사이의 친화력에 대하여 설명할 수 있었다. 냄새물질은 누적한 지질막에 의존하는 공진주파수 변화 패턴과 응답면적에서 계산되어지는 상대적인 응답 세기를 서로 비교하여 확인할 수 있었다. 납계열 무기안료를 누적한 수정진동자를 이용하여 황화물의 검출이 가능함을 알 수 있었다. 이 결과, 여러가지 지질을 누적한 수정진동자를 이용하여 그 응답패턴을 비교한다면 냄새물질의 분석이 가능함을 알았다.

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소규모 시험포에서의 비료처리별 오염배출 농도 특성 비교 (Comparison of Pollutant Load Discharge Characteristics with Fertilizer Treatments from Small Scale Plot)

  • 류창원;신용철;허성구;한윤수;임경재;최중대
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2006년도 학술발표회 논문집
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    • pp.997-1001
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    • 2006
  • Organic compost has been widely applied to the cropland because it has been thought as Environmentally Sound Agriculture (ESA) in Korea. In this study, two-year indoor rainfall experiments were performed. Surface runoff and groundwater volume from 10% and 20% slope plots were measured and water quality samples were collected and analyzed for BOD, COD, T-P and T-N. Flow weighted mean concentration (FWMC) values were computed to assess effects of various fertilizer treatments. FWMC BOD values for organic compost treated plots were higher than chemical fertilizer treated plots. FWMC BOD values for 20% slope plots were higher than those from those for 10% slope plots. The similar trends were found for COD and T-P. FWMC T-N values for chemical fertilizer treated plots were higher than organic compost treated plots. FWMC T-N values for 10% slope plots were higher than those for 20% slope plots. In Korea, excessive use of organic compost has caused extremely high levels of organic matter contents at the cropland. Since organic compost is very slow in releasing its nutrients to the soil, farmers usually apply excessive organic compost for immediate effects and maximum crop yields, which has been causing soil and water quality degradations. Therefore, thorough investigations for better nutrient management plans are needed to develop the ESA strategy in Korea.

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낙동강 하구지역의 식물플랑크톤 극대역 변동에 관한 수직시뮬레이션 -II. 식물플랑크톤 극대역 변동의 수치시뮬레이션- (The numerical simulation on variation of phytoplankton maximum region in the estuary of Nakdong river -II. The numerical simulation on variation of phytoplankton maximum region-)

  • 이대인
    • 한국환경과학회지
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    • 제9권5호
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    • pp.375-384
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    • 2000
  • It is very important to interprete and simulate the variation of phytoplankton maximum region for the prediction and control of red tide. This study was composed of two parts first the hydrodynamic simulation such as residual current and salinity diffusion and second the ecological simulation such as phytoplankton distribution according to freshwater discharge and pollutant loads. Without the Nakdong river discharge residual current was stagnated in inner side of this estuary and surface distribution of salinity was over 25psu. On the contrary with summer mean discharge freshwater stretched very far outward and some waters flowed into Chinhae Bay through the Kadok channel and low salinity extended over coastal sea and salinity front occurred. From the result of contributed physical process to phytioplankton biomass the accumulation was occurred at the west part of this estuary and the Kadok channel with the Nakdong river discharge. When more increased input discharge the accumulation band was transported to outer side of this estuary. The frequently outbreak of red tide in this area is caused by accumulation of physical processes. The phytoplankton maximum region located inner side of this estuary without the Nakdong river discharge and with mean discharge of winter but it was moved to outer side when mean discharge of the Nakdong river was increased. The variation of input concentration from the land loads was not largely influenced on phytoplankton biomass and location of maximum region. When discharge was increased phytoplankton maximum region was transferred to inner side of the Kadok channel. ON the other hand when discharge was decreased phytoplankton maximum region was transferred to inner side of this estuary and chlorophyll a contents increased to over 20$\mu\textrm{g}$/L Therefore if any other conditions are favorable for growth of phytoplankton. decreas of discharge causes to increase of possibility of red tide outbreak.

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충주댐 유역의 SWAT-K와 HSPF모형에 의한 수문성분 모의특성 비교 분석 (Comparison of SWAT-K and HSPF for Hydrological Components Modeling in the Chungju Dam Watershed)

  • 김남원;신아현;김철겸
    • 한국환경과학회지
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    • 제18권6호
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    • pp.609-619
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    • 2009
  • SWAT-K model is a modified version of the original SWAT, and is known to more accurately estimate the streamflows and pollutant loadings in Korean watersheds. In this study, its hydrological components were compared with those of HSPF in order to analyse the differences in total runoff including evapotranspiration(ET), surface flow, lateral flow and groundwater flow from the Chungju Dam watershed during $2000{\sim}2006$. Averaged annual runoff with SWAT-K overestimated by 1%, and HSPF underestimated it by 3% than observed runoff. Determination coefficients($R^2$) for observed and simulated daily streamflows by both the models were relatively good(0.80 by SWAT-K and 0.82 by HSPF). Potential ET and actual ET by HSPF were lower in winter, but similar or higher than those by SWAT-K. And though there were some differences in lateral and groundwater flows by two models because of the differences in hydrological algorithms, the results were to be reasonable. From the results, it was suggested that we should utilize a proper model considering the characteristic of study area and purposes of the model application because the simulated results from same input data could be different with models used. Also we should develop a novel model appropriate to Korean watersheds by enhancing limitations of the existing models in the future.

Development of the CAP Water Quality Model and Its Application to the Geum River, Korea

  • Seo, Dong-Il;Lee, Eun-Hyoung;Reckhow, Kenneth
    • Environmental Engineering Research
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    • 제16권3호
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    • pp.121-129
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    • 2011
  • The completely mixed flow and plug flow (CAP) water quality model was developed for streams with discontinuous flows, a condition that often occurs in low base flow streams with in-stream hydraulic structures, especially during dry seasons. To consider the distinct physical properties of each reach effectively, the CAP model stream network can include both plug flow (PF) segments and completely mixed flow (CMF) segments. Many existing water quality models are capable of simulating various constituents and their interactions in surface water bodies. More complicated models do not necessarily produce more accurate results because of problems in data availability and uncertainties. Due to the complicated and even random nature of environmental forcing functions, it is not possible to construct an ideal model for every situation. Therefore, at present, many governmental level water quality standards and decisions are still based on lumped constituents, such as the carbonaceous biochemical oxygen demand (CBOD), the total nitrogen (TN) or the total phosphorus (TP). In these cases, a model dedicated to predicting the target concentration based on available data may provide as equally accurate results as a general purpose model. The CAP model assumes that its water quality constituents are independent of each other and thus can be applied for any constituent in waters that follow first order reaction kinetics. The CAP model was applied to the Geum River in Korea and tested for CBOD, TN, and TP concentrations. A trial and error method was used for parameter calibration using the field data. The results agreed well with QUAL2EU model predictions.

가축분뇨 퇴비가 시비된 밭 표면유출수의 총질소와 총인의 유출 특성 (Runoff Characteristics of Total-N and Total-P in Upland Surface Runoff Treated with Livestock Manure Compost)

  • 최진규;손재권;이현정;김영주
    • 한국농공학회논문집
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    • 제54권6호
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    • pp.29-37
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    • 2012
  • This study was carried out to runoff characteristics in an upland livestock manure compost. Irrigation, runoff and water quality data in the upland were analyzed periodically from May to November in 2011. The observed amount of rainfall, irrigation, runoff for the experimental upland during the investigation period were 1,299.7 mm, 32.0 mm, and 340.7 mm, respectively. The concentrations of T-N in compost and non-compost upland during study period were ranged from 2.09 mg/L to 6.66 mg/L and from 1.99 mg/L to 6.01 mg/L, respectively. which was generally higher than the quality standard of agricultural water (1.0 mg/L). The concentrations of T-P in compost and non-compost upland during study period were ranged from 0.069 mg/L to 0.525 mg/L and from 0.018 mg/L to 0.152 mg/L, respectively. The runoff pollutants loadings of T-N and T-P in compost upland were 10.05 kg/ha and 0.56 kg/ha, respectively. The runoff pollutants loadings of T-N and T-P in non-compost upland were 9.09 kg/ha and 0.26 kg/ha, respectively. The runoff pollutants loadings in T-N and T-P from this study were much lower values than the pollutant loadings of T-N and T-P from the upland published by the others studies. Runoff pollution loadings due to the upland field in order to identify the characteristics of various crops, farming methods and a variety of targets taking into account regional characteristics by conducting continuous monitoring runoff load estimate will be required.

해수에서 6가 크롬 제거를 위한 흡착제로서의 산처리 적니 적용성 검토 (Applicability Assessment of Acid Treated Red Mud as Adsorbent Material for Removal of Six-valent Chromium from Seawater)

  • 강구;엄병환;김영기;박성직
    • 한국농공학회논문집
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    • 제55권5호
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    • pp.17-23
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    • 2013
  • Six-valent chromium ($Cr^{6+}$) is a highly toxic pollutant, supplied in a variety of industrial activities such as leather tanning, cooling tower blowdown, and plating. Herein, we investigated the removal of $Cr^{6+}$ from aqueous phase using low-cost adsorbents. Steel slag, montmorillonite, illite, kaolinite, red mud, and acid treated red mud with 0.5, 1.0, and 2.0 M HCl were used as adsorbent for the removal of $Cr^{6+}$ and the results showed that acid treated red mud with 2.0 M HCl (ATRM-2.0 M) had higher adsorption capacity of $Cr^{6+}$ than other adsorbents used. Accordingly, $Cr^{6+}$ removal by ATRM-2.0 M were studied in a batch system with respect to changes in initial concentration of $Cr^{6+}$, initial solution pH, adsorbent dose, adsorbent mixture, and seawater. Equilibrium sorption data were described well by Freundlich isotherm model. The influence of initial solution pH on $Cr^{6+}$ adsorption was insignificant. The use of the ATRM-2.0 M alone was more effective than mixing it with other adsorbents including red mud, zeolite, oyster shell, lime stone, and montmorillonite for the removal of $Cr^{6+}$. The $Cr^{6+}$ removal of the ATRM-2.0 M was slightly less in seawater than deionized water, resulting from the presence of anions in seawater competing for the favorable adsorption site on the surface of ATRM-2.0 M. It was concluded that the ATRM-2.0 M can be used as a potential adsorbent for the removal of $Cr^{6+}$ from the aqueous solutions.

Seasonal variation of physicochemical factor and fecal pollution in the Hansan-Geojeman area, Korea

  • Park, Young Cheol;Kim, Poong Ho;Jung, Yeoun Joong;Lee, Ka Jeong;Kim, Min Seon;Go, Kyeong Ri;Park, Sang Gi;Kwon, Soon Jae;Yang, Ji Hye;Mok, Jong Soo
    • Fisheries and Aquatic Sciences
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    • 제19권4호
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    • pp.17.1-17.9
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    • 2016
  • The seasonal variation of fecal coliforms (FCs) and physicochemical factors was determined in seawaters of the Hansan-Geojeman area, including a designated area for oyster, and in inland pollution sources of its drainage basin. The mean daily loads of FCs in inland pollution sources ranged from $1.2{\times}10^9$ to $3.1{\times}10^{11}$ most probable number (MPN)/day; however, the pollutants could not be reached at the designated area. FC concentrations of seawaters were closely related to season, rainfall, and inland contaminants, however, within the regulation limit of various countries for shellfish. The highest concentrations for chemical oxygen demand (COD) and $chlorophyll-{\alpha}$ in seawaters were shown in the surface layer during August with high rainfall, whereas the lowest for dissolved oxygen (DO) in the bottom layer of the same month. Therefore, it indicates that the concentrations of FC, COD, DO, and $chlorophyll-{\alpha}$ of seawaters were closely related to season and rainfall.

액상 유기오염물질에 대한 폐커피가루의 흡착능력 평가 (Evaluation of the adsorptive capacity of spent coffee powder for the removal of aqueous organic pollutants)

  • 김슬기;나승민;손영규
    • 한국습지학회지
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    • 제18권1호
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    • pp.39-44
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    • 2016
  • 최근 커피 이용량이 증가하면서 폐커피가루의 활용에 대한 관심이 환경공학 분야에서 높아지고 있다. 본 연구에서는 폐커피가루를 재활용하여 오염물질에 대한 흡착제로서의 사용 가능성을 평가하기 위하여 액상의 유기 오염물질(메틸렌 블루)에 대한 흡착평형실험 및 흡착속도실험을 수행하였고, 입상활성탄 및 분말활성탄을 이용한 실험결과와 비교하였다. 실험 결과, 흡착평형의 경우 세 종류의 흡착제 모두 Langmuir 식에 잘 맞는 것으로 확인되었으며, 최대흡착량은 분말활성탄(178.6 mg/g), 폐커피가루(60.6 mg/g), 입상활성탄(15.6 mg/g) 순으로 확인되었다. 흡착속도실험에서도 유사 1차식 및 유사 2차식 모두에서 폐커피가루가 입상활성탄보다 우수한 것으로 확인되었다. 이는 폐커피가루의 입자 크기가 입상활성탄보다 작으며 표면이 입상 및 분말활성탄과 같이 다공성 특성을 띄고 있기 때문인 것으로 판단되었다.

섬유산업 배기가스 정화용 Electric Fume Collector 설비의 유지보수를 위한 맞춤형 세정제 (A Customized Cleaning Agent for the Maintenance of Electric Fume Collector Used for the Purification of Effluent Gas from the Textile Industry)

  • 김호태;유황율;전경민;송두리;김진배
    • 공업화학
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    • 제29권2호
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    • pp.229-236
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    • 2018
  • 섬유산업에서 배출되는 오일미스트를 함유한 배기가스를 처리하기 위해 개발되어 실제 현장에 적용되고 있는 electric fume collector (EFC) 설비의 집진판 오염에 의한 성능저하를 개선하기 위한 맞춤형 세정제를 검토하였다. 집진판 표면의 오염물질은 오일미스트가 장기간 축적되면서 심하게 탄화되어 일반 세정제로는 쉽게 제거하기 어려운 상태였다. 오염물질의 특성과 집진판 모재의 손상 등을 고려하여, 알칼리, 알코올, 글리콜 및 비이온계 계면활성제로 구성된 최적의 세정제 성분 조성을 결정하였다. 현장실증실험에는 개발된 세정제 원액을 9.1%로 희석한 용액을 이용하였으며, 단순한 분무방식으로 심하게 점착된 집진판 표면의 오염물질을 성공적으로 제거할 수 있었다. 집진판의 세척에 의하여 EFC 설비의 배기가스 정화성능 개선효과도 크게 향상되었다.