• 제목/요약/키워드: Surface phase change

검색결과 560건 처리시간 0.03초

졸겔공법을 이용한 복합상변화물질의 열성능 평가 (Thermal Performance Evaluation of Composite Phase Change Material Developed Through Sol-Gel Process)

  • 김성한;헤이더 무하마드 지샨;박민우;허종완
    • 대한토목학회논문집
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    • 제43권5호
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    • pp.555-566
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    • 2023
  • 본 연구에서는 콘크리트 부재에 저온 적용을 위해 SOL-GEL 기법을 이용하여 제조된 열에너지 저장 복합상변화물질(CPCM)를 개발하였다. 코어는 테트라데칸, 지지재는 활성탄(AC)을 각각 사용하였다. 진공 함침법을 이용하여 AC의 다공성 구조에 테트라데칸 상변화 물질(PCM)을 함침시키고, 테트라에틸오르토실리케이트(TEOS)를 사용한 SOL-GEL 공정을 이용하여 제조된 복합체에 실리카 겔을 얇게 코팅하였다. CPCM의 열 성능은 시차주사열량계(DSC)과 열 중량분석(TGA)을 통해 분석했다. DSC 결과 테트라데칸 PCM은 용융 및 동결 온도가 각각 6.4℃ 및 1.3℃이고 해당 엔탈피는 각각 226J/g 및 223.8J/g인 것으로 나타났다. CPCM은 7.1℃ 및 2.4℃에서 용융 및 동결 과정에서 각각 32.98J/g 및 27.7J/g의 엔탈피를 나타내었다. TGA 시험 결과 AC는 500℃까지 열적으로 안정하며, 이는 120℃ 정도인 순수 테트라데칸의 분해 온도보다 훨씬 높은 것으로 나타났다. 또한, AC-PCM과 CPCM의 경우 각각 80℃와 100℃에서 열분해가 시작되었다. CPCM의 화학적 정성 분석을 위해 푸리에 변환 적외선(FT-IR) 분광법을 이용하였으며, 그 결과 개발된 복합체가 화학적으로 안정함을 확인하였다. 마지막으로, SOL-GEL 공정 후 AC 표면에 실리카 겔의 얇은 층이 존재함을 확인하기 위해 주사전자현미경(SEM)을 이용하여 AC와 CPCM의 표면 형태를 분석하였다.

위상대조도 MRI에서 숙임각에 따른 상행대동맥의 혈류 측정 (Blood Flow Measurement with Phase Contrast MRI According to Flip Angle in the Ascending Aorta)

  • 김문선;권대철
    • 한국자기학회지
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    • 제26권4호
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    • pp.142-148
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    • 2016
  • 자기공명영상에서 위상대조(phase contrast; PC) 기법으로 혈류 속도와 혈류량을 정량적으로 측정하기 위해 VENC(150 cm/s)에서 숙임각의 변화에 따른 혈류 속도와 혈류량을 측정하였다. 1.5T MRI로 지원자 17명(여: 8, 남: 9, 평균연령 $57.9{\pm}15.4$)을 대상으로 non-breath holding 기법을 적용하여 상행대동맥에서 VENC(150 cm/s)로 숙임각을 $20^{\circ}$, $30^{\circ}$, $40^{\circ}$ 변화하여 측정하였다. 혈류는 average velocity, peak velocity, net forward volume, net forward volume/body surface area를 획득하였다. 상행대동맥에서 AV(average velocity)의 평균값은 숙임각 $20^{\circ}$(9.87 cm/s), $30^{\circ}$(9.6 cm/s), $40^{\circ}$(10.05 cm/s)로 측정되었다. 숙임각을 $20^{\circ}$, $30^{\circ}$, $40^{\circ}$에서 peak velocity, average velocity, net forward volume, net forward volume/body surface area는 통계적인 유의한 차이가 없었다(p > .05). 혈류속도와 혈류량 측정은 매개변수를 조정하여 적용하면 심장혈관 질환의 진단 및 치료에 중요한 정보가 되는 혈류량을 정확히 계산하고, 혈류량 측정에 관한 연구에 도움을 줄 수 있다.

Co/Fe 황화물의 혼합안료에 의한 도자기 표면의 상형성과 색변화 (Effects of Co/Fe Sulfate Pigments on the Colour and Phase of Porcelain)

  • 김남훈;신대용;김경남
    • 한국재료학회지
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    • 제32권8호
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    • pp.354-360
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    • 2022
  • In this study, an Co/Fe coated porcelain using a cobalt and ferrous sulfate was sintered at 1,250 ℃. The specimens were investigated by HR-XRD, FE-SEM (EDS), Dilatometer, and UV-vis spectrophotometer. The surface of the porcelain was uniformly fused with the pigment, and white ware and celadon body specimens were densely fused to a certain thickness from the surface. Other new compounds were produced by the chemical reaction of cobalt/ferrous sulfate with the porcelain body during the sintering process. These compounds were identified as cobalt ferrite spinel phases for white ware and white mixed ware, and an andradite phase for the celadon body, and the amorphous phase, respectively. As for the color of the specimens coated with cobalt and ferrous mixed pigments, it was found that the L* value was greatly affected by the white ware, and the a* and b* values were significantly changed in the celadon body. The L* values of the specimens fired with pure white ware, celadon body, and white mix ware were 72.1, 60.92, 82.34, respectively. The C7F3 pigment coated porcelain fired at 1,250 ℃ had L* values of 39.91, 50.17, and 40.53 for the white ware, celadon body, and white mixed ware, respectively; with a* values of -1.07, -2.04, and -0.19, and at b* values of 0.46 and 6.01, it was found to be 4.03. As a new cobalt ferrite spinel phase was formed, it seemed to have had a great influence on the color change of the ceramic surface.

표면장력과 후압을 고려한 고에너지밀도 레이저 용접공정 해석 (A study of high-power density laser welding process considering surface tension and recoil pressure)

  • 하응지;김우승
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 추계학술대회
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    • pp.1190-1195
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    • 2004
  • In this study, numerical investigation has been performed on the evolution of key-hole geometry during high-energy density laser welding process. Unsteady phase-change heat transfer and fluid flow with the surface tension and recoil pressure are simulated. To model the overheated surface temperature and recoil pressure considering subsonic/sonic vapor flow, the one-dimensional vaporization models proposed by Ganesh and Knight are coupled over liquid-vapor interface. It is shown that the present model predicts well both the vaporization physics and the fluid flow in the thin liquid layer over the other model.

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자유표면변형을 고려한 저에너지밀도 및 고에너지밀도 레이저 용접공정 통합 해석 (A Unified Analysis of Low-Power and High-Power Density Laser Welding Processes with Evolution of Free Surface)

  • 하응지;김우승
    • 대한기계학회논문집B
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    • 제29권10호
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    • pp.1111-1118
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    • 2005
  • In this study, a unified numerical investigation has been performed on the evolution of weld pool and key-hole geometry during low-power and high-power density laser welding. Unsteady phase-change heat transfer and fluid flow with the surface tension are examined. The one-dimensional vaporization model is introduced to model the overheated surface temperature and recoil pressure during high-power density laser welding. It is shown that Marangoni convection in the weld pool is dominant at low-power density laser welding, and the keyhole with thin liquid layer and the hump are visible at high-power density laser welding. It is also shown that the transition from conduction welding to penetration welding fur iron plate exists when the laser power density is about $10^6W/Cm^2$.

레이저 및 전자빔을 이용한 표면 열처리 (Heat Treatment Using a Laser Beam or an Electron Beam)

  • 김홍준;최우천;권영각
    • 대한기계학회논문집
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    • 제19권2호
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    • pp.427-432
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    • 1995
  • Surface heat treatment using a laser beam or an electron beam is studied through numerical analyses and experiments. For the surface heat treatment process, a theoretical model is developed to predict the effects of laser beam power, travel speed and properties of a workpiece on the depth and width of the heat affected zone(HAZ). The shape of HAZ and the hardness of heat-treated surface are experimentally obtained using an electron beam. Three materials(SS41, S45C and S55C) are selected as workpiece materials. The hardness of HAZ is increased up to 3 times for materials of a low carbon content. The results of the numerical analysis are compared with those of experiments. The comparison shows that the numerical model predicts larger depths and widths.

Photocatalytic Properties of $TiO_2$ Coatings Prepared by Cold Spray Process

  • Han, Jong-Hyuck;Lee, Soo-Wohn
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2005년도 추계학술발표회 및 workshop
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    • pp.183-184
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    • 2005
  • Four different coatings deposited using cold spray process were studied with two different powder agglomerating techniques (spray d교 and evaporated powder) and using $TiO_2$ nano-sized powders with and without a 10wt% addition of ZnO. Characterization was performed by SEM, XRD and roughness test. Also the photocatalytic effect of the coatings was evaluated. Although the change of powder preparation techniques and the addition of ZnO into $TiO_2$ did not show appreciable variations in the surface morphology and Anatase phase transformation, it did show influence on the surface roughness of the coating, the highest roughness being found in the coatings made by spray powder prepared method. Regarding the photocatalytic effect it was observed that the using the spray dry coating and the addition of ZnO are promoter of purification at higher rates.

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13%Cr 스테인리스강의 표면 질소침투처리에 미치는 Al첨가의 영향 (Effect of Al Addition on the Surface Nitrogen Permeation Treatment of 13%Cr Stainless Steels)

  • 윤삼석;김기돈;이해우;강창룡;성장현
    • 열처리공학회지
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    • 제12권3호
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    • pp.221-230
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    • 1999
  • The surface nitrogen permeation of Al alloyed 0.14%C-13%Cr stainless steels was investigated after heat treating at $1050^{\circ}C{\sim}1150^{\circ}C$ in the nitrogen gas atmosphere. The strong affinity between Al and nitrogen permeates the nitrogen through the interior of the steels. Two precipitates of round type and needle type are observed at the surface layer. These precipitates mainly consist of AlN containing plenty of aluminum. The surface layer of 0.53%Al alloyed specimen shows ferrite phase, while the surface layers of 1.65%Al and 2.27%Al alloyed specimens appear ${\gamma}$ plus ${\alpha}$ phases. The depth of nitrogen permeation depends upon the Al content and microstructure of the matrix. The 1.65%Al alloyed specimen representing ${\alpha}+{\gamma}$ matrix phases at the nitrogen permeation temperature shows the maximum case depth in this experiment. Although the surface hardness increases by raising the Al content of the specimen owing to the increase of nitride precipitation density, the nitride precipitation deteriorates the corrosion resistance in the solution of HCl, $H_2SO_4$, and $FeCl_3$.

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근적외선 연속발진 레이저 조사에 의한 게르마늄 광학창 손상 연구 (Study of Damage in Germanium Optical Window Irradiated by a Near-infrared Continuous Wave Laser)

  • 이광현;신완순;강응철
    • 한국군사과학기술학회지
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    • 제17권1호
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    • pp.82-89
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    • 2014
  • The damage in germanium (Ge) optical window irradiated by a near-infrared continuous wave (CW) laser was studied. Laser-induced heating and melting process were surveyed, and the specific laser power and the irradiance time to melt were estimated by numerical simulation. The experiments were also carried out to investigate the macro and micro structure change on Ge window. Results showed that the surface deformation was formed by melting and resolidification process, the damaged surface had a polycrystalline phase, and the transmittance as an optical performance factor in mid-infrared region was decreased. We confirmed that an abnormal polycrystalline phase and surface deformation effect such as hillock formation and roughness increase reduced the transmittance of Ge window and were the damage mechanism of CW laser induced damage on Ge window.

지난 130년 간 한반도 근해의 표층 수온 변화 경향 (Trends in Sea Surface Temperature (SST) Change Near the Korean Peninsula for the Past 130 Years)

  • 김성중;우성호;김백민;허순도
    • Ocean and Polar Research
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    • 제33권3호
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    • pp.281-290
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    • 2011
  • This study examined the change in sea surface temperature (SST) around the Korean peninsula since industrialization at year 1880, and its possible causes using observation based data from the Hadley Center, the Goddard Institute of Space Studies, and National Climate Data Center. Since year 1880, There have been multi-decadal fluctuations with a gradual reduction from 1880 to around 1940, and from 1950-1980. There has then been a marked increase from 1940-1950, and from 1980 to the present. The ocean surface warming is larger during the boreal winter than summer, and greater in the south. The multi-decadal SST fluctuations around the Korean Peninsula are largely consistent with the negative phase of the Pacific Decadal Oscillation (PDO), which fluctuates with periods of about 20-50 years. Secondly, the El Ni$\tilde{n}$o-Southern Oscillation (ENSO), whose long period component moves along with the PDO, appears to influence the SST near the Korean Peninsula, especially in recent decades. Overall, the SST around the Korean Peninsula has warmed since year 1880 by about $1^{\circ}C$, which is about twice the global-mean ocean surface warming. This long-term warming is aligned with an increase in greenhouse gas concentration, as well as local factors such as the PDO.