• Title/Summary/Keyword: Surface phase change

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Dissolution and Reprecipitation Behavior of TiC-TiN-Ni Cermets During Liquid-Phase Sintering

  • Yoon, Choul-Soo;Shinhoo Kang;Kim, Doh-Yeon
    • The Korean Journal of Ceramics
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    • v.3 no.2
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    • pp.124-128
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    • 1997
  • An attempt was made to understand the dissolution and reprecipitation behavior of the constituent phases such as TiC, TiN, and Ti(CN) in TiC-TiN-Ni system. During the liquid-phase sintering the TiC phase was found to dissolve preferentially in Ni binder. The solid-solution phase, Ti(CN), formed around the TiN phase, resulting in a core/rim structure. This result was reproduced when large TiC particles were used with fine TiN particles. The path for the microstructural change in TiC-TiN-Ni system was largely controlled by the difference in the interfacial energy of each phase with the liquid binder phase. The results were discussed with thermodynamic principles.

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New parametric approach to decomposition of disk averaged spectra of potential extra terrestrial planet I. Surface type ratio of the Earth

  • Ryu, Dong-Ok;Seong, Se-Hyun;Yu, Jin-Hee;Oh, Eun-Song;Ahn, Ki-Beom;Hong, Jin-Suk;Lee, Jae-Min;Kim, Suk-Whan
    • Bulletin of the Korean Space Science Society
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    • 2010.04a
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    • pp.34.2-34.2
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    • 2010
  • We built 7 potential extra-terrestrial planets including the full 3D Earth model with various surface types and 6 planet models, each with uniform surface characteristics. The surface types include ice, tundra, forest, grass, ground and ocean. We then imported these 7 planets into integrated ray tracing(IRT) model to compute their disk averaged spectra and to understand the spectral behavior depending on the geometrical view, illumination phase and seasonal change. The IRT computation show that the 6 planets with uniform surfaces exhibit clear spectral differences from that of the Earth. We then built a phase and seasonal DAS database for the 6 uniform surface planets and used them for parametric spectral decomposition technique to derive the Earth DAS. This computation resulted in the first potential solution to the surface type ratio of the Earth compared to the measured earth surface type ratio. The computational details and the implications are discussed.

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A Study on the Gaseous Nitrocarburising of Cast Irons (주철의 가스질화침탄처리)

  • Kim, Y.H.;Yoon, H.J.
    • Journal of the Korean Society for Heat Treatment
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    • v.16 no.2
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    • pp.71-77
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    • 2003
  • We investigate the phase formation in the compound layer of cast irons during the gaseous nitrocarburising of four different cast irons, that contain different types of graphites in the shape and size. We examine the change in the surface roughness with the nitrocarburising time. The observation of cross-sectional microstructure and X-ray diffraction analysis indicate that the compound layer consists of single ${\varepsilon}-Fe_{2-3}(N,C)$ phase and that its thickness increases in a parabolic manner with the treatment time. The surface roughness parameters, Rz and Ra increase with increasing treatment time. In other words, the roughness parameters increase as the thickness of compound layer increases. The parameters also depend on the shape and size of graphite in the individual cast irons.

Composition and Microstructure of Electroplated Zinc-Chromium Alloy according to Electrolysis Conditions (전해조건에 따른 아연-크롬합금 도금층의 조성 및 조직특성)

  • 안덕수;김대영;예길촌
    • Journal of the Korean institute of surface engineering
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    • v.35 no.4
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    • pp.232-240
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    • 2002
  • The composition and the microstructure of the Zn-Cr alloys electroplated in chloride bath with EDTA were studied according to electrolysis conditions. The cathode current efficiency decreased with increasing both Cr/(Cr+Zn) ratio and current density. The Cr content of the alloy deposits increased with Cr/(Cr+Zn) ratio and current density The phase structure of Zn-Cr alloy deposits changed from η-Zn through η-Zn+${\gamma}$'-ZnCr to ${\gamma}$'-ZnCr with increasing Cr content of alloys. The surface morphology of Zn-Cr alloy deposits changed from fine needle shaped crystallites through the mixed structure of needle-shaped and granular one to the colony structure with fine granular crystallites according to the change of phase structure

Eulerian Two-Phase Flow Analysis for Solid-Liquid Mixing in a Industrial Mixer (산업용 교반기의 고체-액체 혼합에 대한 Eulerian Two-Phase 유동해석)

  • Song, Ae-Kyung;Hur, Nahm-Keon;Won, Chan-Shik;Ahn, Ick-Jin
    • 유체기계공업학회:학술대회논문집
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    • 2006.08a
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    • pp.471-474
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    • 2006
  • The Mixer is apparatus that help precipitation or an inhomogeneous distribution of various phases to be mixed and that user makes necessary material mixing one or the other. Mainly the mixer which is used from chemical and food industry is very important system in engineering that mixes the material. The inside flow of the mixer under the actual states which put a basis in flow of the fluid is formed rotation of the impeller. The inside flow of impeller will be caused by various reasons change with shape of impeller, number of rotation, mixing material and flow pattern of free surface etc. Also mixer study depended in single-phase flow and experimental research. So the numerical analysis of flow mixing solid-fluid particle is simulated. It is become known, that the case where agitator inside working fluid includes the solid particle the sinkage reverse which the solid particle has decreases an agitation efficiency. From the research which it sees the hazard solid which examines the effect where the change of the sinkage territory which it follows agitation number of revolution and diameter of the particle goes mad to an agitator inside flow distribution - numerical analysis the inside flow distribution of liquid state with Eulerian Two-Phase Method.

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Baseline Refinement for Topographic Phase Estimation using External DEM

  • Lee, Chang-Won;Moon, Wooil-M.
    • Proceedings of the KSRS Conference
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    • 2002.10a
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    • pp.460-464
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    • 2002
  • Multitemporal interferometric SAR has became an useful geodetic tool for monitoring Earth's surface deformation, generation of precise DEM, and land cover classification even though there still exist certain constraints such as temporal and spatial decorrelation effects, atmospheric artifacts and inaccurate orbit information. The Korea where nearly all areas are heavily vegetated, JERS-1 SAR has advantages in monitoring surface deformations and environmental changes in that it uses 4-times longer wavelength than ERS-l/2 or RADARSAT SAR system. For generating differential SAR interferogram and differential coherence image fer deformation mapping and temporal change detection, respectively, topographic phase removal process is required utilizing a reference inteferogram or external DEM simulation. Because the SAR antenna baseline parameter for JERS-1 is less accurate than those of ERS-l/2, one can not estimate topographic phases from an external DEM and the residual phase appears in differential interferogram. In this paper, we examined topographic phase retrieval method utilizing an external DEM. The baseline refinement is carried out by minimizing the differences between the measured unwrapped phase and the reference points of the DEM.

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Phase Transformation and Mechanical Properties on Sintering Temperature of $\alpha$-SiC Manufactured by Pressureless Sintering (상압소결법에 의해 제조한 $\alpha$-SiC의 소결온도에 따른 상전이와 기계적 특성)

  • 주진영;신용덕;박미림;이종덕
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.431-434
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    • 2001
  • The mechanical and phase transformation of the cold isostatically pressed $\alpha$-SiC ceramic were investigated as a function of the sintering temperature. The result of phase analysis by XRD revealed 6H, 4H, 3C and phase transformation between 6H and 4H showed a sudden change over 200$0^{\circ}C$. However, the alongrightarrow$\beta$ reverse transformation did not occur to any sintering temperature. The relative density and the mechanical properties of $\alpha$-SiC ceramic was increased with increased sintering temperature. The flexural strength rapidly inclosed below 210$0^{\circ}C$ and showed the highest value of 410 MPa at 220$0^{\circ}C$. This reason is because crack was propagated through surface flaw. The fracture toughness showed the highest value of 3.3 MPa.m$_{1}$2/ at 220$0^{\circ}C$.

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Galloping Algorithm of Quadruped Robots on Irregular Surface (비평탄면에서의 4 족 로봇의 갤로핑 알고리즘)

  • Shin, Chang-Rok;Park, Jong-Hyeon;Yoo, Hong-Hee
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.888-893
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    • 2008
  • In This paper proposes the control algorithm for quadruped robots on irregularly sloped uneven surface. Body balance is important in stable running locomotion. Since the body balance is determined by the forces applied at the feet during touchdown phase, the ground reaction force is controlled for stable running. To control the forces at each foot, the desired force is generated. The generated desired force is compared with actual contact force, then, the difference between them modifies the foot trajectory. The desired force is generated by combination of the rate change of the angular and linear momentum at flight. Then the rate change of momentum determines each force distribution. The distribution of the force is carried out by fuzzy logic. The computer simulation is carried out with the commercial software RecurDyn$^{(R)}$. Dynamic model simulation program show that the stable running on the irregularly sloped uneven surface are accomplished by the proposed method.

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Surface Characteristics of Ground and Post-Sintered Zirconia (지르코니아의 소결 후 특성)

  • Kim, Min-Jeong;Kim, Im-Sun;Choi, Byung-Hwan;Kim, Won-Gi
    • Journal of Technologic Dentistry
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    • v.38 no.3
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    • pp.157-163
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    • 2016
  • Purpose: It is to compare and evaluate the change of the wear rate and phase variation of the Zirconia before and after the sintering after the grinding by a high speed equipment manufactured for the Zirconia. Methods: The specimen of the sintered Zirconia was manufactured as size of $15mm{\times}15mm{\times}2mm$. The grinding has been applied to each of all pieces of each test groups for a minute fit for each condition at same speed of 50,000 rpm by a diamond bur at high speed handpiece with injection of the air and water. For the observation of the surface before and after the sintering of the each test piece, the cross section of it was observed as 100 magnification by a scanning electron microscope after it was coated by PT, and the diffraction analysis was performed by XDR to compare the crystal phase of the Zirconia. The average surface roughness value of all specimens were evaluated. The wear test was performed at room temperature by applying a load of 1kg for 120,000 cycles for the chewing period 6 months. Wear was analyzed for the enamel cusps by measurement of the vertical substance loss with a laser scanner. Conclusion: The phase variation from the tetragonal phase to the monoclinic phase was confirmed in the test group of the pre-sintered Zirconia after the grinding, and the value of the surface roughness and the wear rate was increased in experimental group.

Effect of Carbon Content on the Nitrogen Permeation Heat Treatment in Aluminum Bearing 13%Cr Stainless Steels (Al 함유 13%Cr 스테인리스강의 표면 질소침투 열처리에 미치는 첨가원소 탄소의 영향 (13%Cr 스테인리스강의 고질소 표면침투 열처리))

  • Yoo, D.K.;Park, J.U.;Joo, D.W.;Kim, K.D.;Sung, J.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.3
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    • pp.151-157
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    • 2000
  • This study aims to investigate the effect of carbon content on the surface nitrogen permeation of 13%Cr-1.8%Al alloyed stainless steels. The surface nitrogen permeation was performed at $1050^{\circ}C{\sim}1200^{\circ}C$ in the $1kg/cm^2$ nitrogen gas atmosphere. The nitrogen permeated surface layer of the specimen containing 0.03%C consists of AlN, martensite and retained austenite phases. while the surface layer of the specimen containing 0.14%C appears the $AlFe_3C_x$ phase including former three phases. The specimen containing 0.14%C shows lower total case depth than that containing 0.03%C at the nitrogen permeation temperatures of $1050^{\circ}C$ and $1100^{\circ}C$, while the total case depth of the specimen containing 0.14%C is remarkably increased at the temperature of $1150^{\circ}C$ and $1200^{\circ}C$ due to the increase in the retained austenite content. Martensitic phase, AlN and $AlFe_3C_x$ precipitate of the nitrogen permeated surface layer cause to increase the surface hardness of 550~600Hv.

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