• Title/Summary/Keyword: Surface ozone

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Characteristics of Surface and Synoptic Meteorology During High-Ozone Episodes in the Greater Seoul Area (서울.수도권 지역 고농도 오존 사례의 지상 및 종관 기상 특성)

  • 오현선;김영성
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.4
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    • pp.441-455
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    • 1999
  • Meteorological characteristics of three high-ozone episodes in the Greater Seoul Area, selected on the basis of morning-average wind direction and speed for the 1990~1997 period, were investigated. Three high-ozone episodes thus selected were seven days of July 3~9, 1992, nine days of July 21~29, 1994, and three days of August 22~24, 1994. Along with surface meteorological data from the Seoul Weather Station, surface and 850-hPa wind fields over the Northest Asia around the Korean Peninsula were used for the analysis. In the July 1992 episode, westerly winds were most frequent as a result of the influence of a high-pressure system in the west behind the trough. In contrast, in the July 1994 episode, easterly winds were most frequent due to the effect of a typhoon moving north from the south of Japan. Despite different prevailing wind directions in the two episodes, the peak ozone concentration of each episode always occurred when a sea-land breeze developed in association with weak synoptic forcing. The August 1994 episode, selected as being representative of calm conditions, was another typical example in which peak ozone concentration rose to 322 ppb under the well-developed sea-land breeze. All three high-ozone episodes were terminated by precipitation, and subsequent rises in ozone concentrations were also suppressed by a series of precipitation afterwards. In particular, two heavy rainfalls were the main reason why the August 1994 episode, with the highest and second-highest ozone concentrations during the 1990~1997 period, lasted for only a few days.

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Inactivation of Vibrio parahaemolyticus by Aqueous Ozone

  • Feng, Lifang;Zhang, Kuo;Gao, Mengsha;Shi, Chunwei;Ge, Caiyun;Qu, Daofeng;Zhu, Junli;Shi, Yugang;Han, Jianzhong
    • Journal of Microbiology and Biotechnology
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    • v.28 no.8
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    • pp.1233-1246
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    • 2018
  • Vibrio parahaemolyticus contamination causes serious foodborne illness and has become a global health problem. As a disinfectant, aqueous ozone can effectively kill a number of bacteria, viruses, parasites, and other microorganisms. In this study, three factors, namely, the aqueous ozone concentration, the exposure time, and the bacterial density, were analyzed by response surface methodology, and the aqueous ozone concentration was the most influential factor in the sterilization ratio. Under low aqueous ozone concentrations (less than 0.125 mg/l), the bacterial cell membranes remained intact, and the ozone was detoxified by intracellular antioxidant enzymes (e.g., superoxide dismutase and catalase). Under high aqueous ozone concentrations (more than 1 mg/l), cell membranes were damaged by the degree of peripheral electronegativity at the cell surface and the concentration of lactate dehydrogenase released into the extracellular space, and the ultrastructures of the cells were confirmed by transmission electron microscopy. Aqueous ozone penetrated the cells through leaking membranes, inactivated the enzymes, inhibited almost all the genes, and degraded the genetic materials of gDNA and total RNA, which eventually led to cell death.

Numerical Simulation for Dry Deposition Velocity of Ozone According to Land-use Types (지표면의 종류에 따른 오존의 건성침적속도에 관한 수치모의)

  • 이화운;노순아;문난경
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.5
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    • pp.583-594
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    • 2003
  • Ozone is an important atmospheric pollutant that is occurred in tropospheric chemical process and it also affects the human health and plants. For a correct application of abatement strategies for ozone, it is necessary to understand the factors that control atmospheric ozone removal by dry deposition processes. The present study investigates the numerical simulation of the dry deposition velocity (V$^{d}$ ) obtained from PNU/DEM (Pusan National University Deposition Model). PNU/DEM includes seasonal categories, meteorological factors, surface properties and land-use types and proposes for an accurate numerical computation. And, this study examines the ability of the PNU/DEM to compute V$_{d}$ of ozone over water surfaces and evaluates PNU/DEM by comparing its estimated V$_{d}$ to past observed V$_{d}$ over water. The parametrization was found to yield V$_{d}$ values generally in good agreement with the observations for the deciduous forest and the coniferous forest. Ozone is removed slowly at wet surface or water due to its low water solubility. Therefore V$_{d}$ values over water were lower than Vd values over the other surfaces. Comparison of PNU/DEM simulated V d values to observations of ozone V$_{d}$ that have been reported in the literature implies that PNU/DEM produces realistic results.

Improvement of a UV/Ozone Duplex Sterilizer (UV/Ozone 복합 살균기의 살균력 개선 연구)

  • Jee, Jung-Eun;Yang, Won-Kyun;Park, Eun-Chul;Kim, Kang-Suk;Joo, Jung-Hoon
    • Journal of the Korean institute of surface engineering
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    • v.41 no.2
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    • pp.76-82
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    • 2008
  • We investigated sterilization characteristics of UV lights by counting the number of bacteria units with varying sterilization time and distance from the light source. We focused on an idea that UV light of 184.9 nm could generate ozone and developed a new sterilizer. The UV-ozone duplex system sterilized bacteria faster than UV-only sterilizers. To reduce shadowing effects by target objects, we used UV transparent quartz plate as a support and put a reflecting plate. Distribution of UV irradiation intensity and ozone supply were analyzed by a 3D model and measured by a semiconductor UV sensor. But even with an Al reflector, multi-layered pens could not be treated properly from UV irradiation only. Ozone generating lamp could treat more uniformly multi-layered pens with a stirring fan by supplying ozone to shadowed surfaces.

Precipitation and Cloud Cover on High Ozone Days (고농도 오존일의 강우와 운량)

  • 김영성;김영진;윤순창
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.6
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    • pp.747-755
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    • 1999
  • Effects of precipitation and cloud cover on high ozone days are examined by investigating the precipitation and average cloud cover before the ozone peak time within a day. High ozone days above 100 ppb in the Greater Seoul Area(GSA) for the ozone season from May to September are chosen for the analyses in terms of the surface meteorological data during 1990~1997. The result shows that the effect of precipitation on the rise of ozone concentration is definitely negative so that ozone concentration could not rise above 100ppb immediately after precipitation. But, the effect of cloud cover is associated with the variations of other meteorological parameters. The number of high ozone days with "zero" cloud cover is rather less than that with cloud cover of 1 to 4 since temperature is usually lower in "zero" cloud cover days. Furthermore, ozone concentration can rise above 100ppb even with full cloud cover when the wind is weak and the temperature is high.temperature is high.

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The Distribution of Total Ozone Amounts and Intercomparison of their characteristics Derived from the TOVS Observations over the Korean Peninsula (TOVS로 부터 도출한 한반도 부근의 전오존량 분포 및 그 특성 비교)

  • 정효상;주상원
    • Korean Journal of Remote Sensing
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    • v.11 no.3
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    • pp.23-31
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    • 1995
  • The International TOVS(TIROS Operational Vertical Sounders) Process Package(ITPP-VI), which has been installed at Korea Meteorological Administration(KMA), is only for a global usage to need a surface data to generate atmospheric soundings and total ozone amount. If the initial input process in the ITTP-VI is not modified, it takes climatic surface data for producing sounding data and total ozone amount in general. KMA is trying to improve the quality of TOVS total ozone amount using real-time synoptoc observation in various ways instead of climatological data because this retrieved data in the new scheme for total ozone presently used at the KMA may critically provide to analyze the long-term trend of ozone structure over the Korean peninsula. Two cases in this study show that TOVS retrieved total ozone amounts used by synoptic surface observations can delineate more detailed ozone structures rather than those used by climate surface data. The distribution of TOVS retrieved ozone amount fields with the synoptic surface analyzed data(TOVS-GPV) show more in detail relatively than those with the climate data(TOVS-CLIMAT) as expected. In addition, the collocated inter-comparisons of TOVS-GPV with TOVS-CLIMAT, TOMS observations and Dobsometer observations are performed statistically. TOVS-GPV fields with TOMS observations show smaller bias relatively than TOVS-CLIMAT and also reduce the differences.

The Optimization of Ozone Solubility and Half Life Time in Ultra Pure Water and Alkaline Solution on Semiconductor Wet Cleaning Process (반도체 습식 세정 공정 중 상온의 초순수와 염기성 수용액 내에서 오존의 용해도 최적화)

  • Lee Sang-Ho;Lee Seung-Ho;Kim Kyu-Chae;Kwon Tae-Young;Park Jin-Goo;Bae So-Ik;Lee Gun-Ho;Kim In-Jung
    • Journal of the Semiconductor & Display Technology
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    • v.4 no.4 s.13
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    • pp.19-26
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    • 2005
  • The process optimization of ozone concentration and half life time was investigated in ultra pure water and alkaline solutions for the wet cleaning of silicon wafer surface at room temperature. In the ultra pure water,. the maximum concentration (35 ppm) of ozone was measured at oxygen flow rate of 3 liters/min and ozone generator power over 60%. The half life time of ozone increased at lower power of ozone generator. Additive gases such as $N_2$ and $CO_2$ were added to increase the concentration and half life time of ozone. Although the maximum ozone concentration was higher with the addition of $N_2$ gas, a longer half life time was observed with the addition of $CO_2$. When $NH_4OH$ of 0.05 or 0.10 vol% was added in DI water, the pH of the solution was around 10. The addition of ozone resulted in the half life time less than 1 min. In order to maintain high pH and ozone concentration, ozone was continuously supplied in 0.05 vol% ammonia solutions. 3 ppm of ozone was dissolved in ammonia solutions. The static contact angle of silicon wafer surface became hydrophilic. The particle removal was possible alkaline ozone solutions. The organic contamination can be removed by ozonated ultra pure water and then alkaline solution containing ozone can remove the particles on silicon surface at room temperature.

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Ozone Generation Characteristic Utilizing a Water Surface Discharge (수표면 방전을 이용한 오존발생특성)

  • Kim, In-Woong;Kim, Chan-Gyu;Park, Seung-Lok;Moon, Jae-Duck
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1763-1765
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    • 2002
  • A silent discharge type ozone generator using a water surface as an electrode has been proposed and investigated experimentally. A water surface has many Taylor cones when the ac voltage is applied on its surface, which increase the discharge surface greatly. In this paper, it was studied about the effect of the water conductivity. As increasing the water conductivity, the amount of generated ozone was increased and the silent discharge on the water surface took place steadily and calmly.

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A Comparative Study of Catalytic Ozone processes for Removal of Refractory Organics (난분해성 유기물질 제거를 위한 오존/촉매 공정의 비교에 관한 연구)

  • Lee, Gyu-Hwan;Lee, Yu-Mi;Rhee, Dong-Seok
    • Journal of Industrial Technology
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    • v.26 no.A
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    • pp.199-205
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    • 2006
  • Ozone alone and catalytic ozone processes were introduced for treatment of humic acid, which is representative refractory organic compound. The treatment efficiencies of humic acid in each process were analyzed in pH variation, DOC removal, and $UV_{254}$ decrease. Mn loaded GAC catalyst was prepared by loading potassium permanganate onto the granular activated carbon surface. BCM-GAC and BCM-Silica gel catalyst were prepared by BCM. $UV_{254}$ decrease in all processes was comparatively high with efficiency over 87%. DOC removal in ozone/GAC process was the highest with 78%, and removal rates for other processes followed the order ozone/BCM-GAC(62%) > ozone/BCM-silica gel(45%) > ozone/silica gel(43%) > ozone/Mn Loaded GAC(42%) > ozone alone(37%).

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Discharge and Ozone Generation Characteristics of a Wire-Plate Discharge System with a Slit Barrier (슬릿 유전체 장벽을 갖는 선대 평판형 방전장치의 방전 및 오존 발생특성)

  • Moon Jae-Duk;Jung Jae-Seung
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.9
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    • pp.421-426
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    • 2005
  • A wire-plate discharge system with a slit barrier has been proposed and investigated experimentally by focusing on the discharges on the slit barrier and ozone generation characteristics. This wire-plate discharge system with a slit barrier can generate an intensive corona discharges, and produce corona discharge twice, once from the corona wire electrode and second time from the surface and the slits of the slit dielectric barrier. As a result this propose wire-plate discharge system with the slit barrier can produce greatly increased ozone than without the slit barrier. This type of wire-plate discharge system with the slit barrier could be used for effective ozone generation as a means with retard to the removal of pollutant gas