• Title/Summary/Keyword: Surface ozone

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Surface Discharge Characteristics of a DC Corona Charged Ferroelectric Pellet Barrier (직류 코로나 하전된 강유전체구 층의 연면방전특성)

  • Geum, Sang-Taek;Lee, Geun-Taek;Mun, Jae-Deok
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.5
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    • pp.385-390
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    • 1999
  • Surface corona discharge characteristics of a dc corona charged ferroelectric pellet barrier have been investigated experimentally. Electric charges stored on the surfaces of the ferroelectric pellets by a dc corona discharge provide partial electric fields on the surfaces of the ferroelectric pellets, which could generate surface corona discharges on the ferroelectric pellets. This system utilizes both the surface discharges on the ferroelectric pellet barrier and the corona discharge between corona tip and mesh electrode. Positive and negative dc voltages were applied to the tip to generate partial discharges, and corona currents were estimated to investigate the buildup charge on ferroelectric pellets as a function of the applied time and the charge relaxation time constants of ferroelectric pellets. As a result, in the case of the negative corona discharge with the ferroelectric pellet barrier, the mean corona current and ozone generation increase greatly, and the surface discharges on the ferroelectric pellets can be fenerated efficiently. It is also found that, charge relaxation time, dielectric constants offerroelectric pellets, polarity of applied voltage and applied time affected to the surface discharges among the ferroelectric pellets.

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Characteristics of the Stratospheric Ozone and the Surface Damaging UV-B Radiation in Pohang (포항 지역의 성층권 오존 및 지표 유해 자외선 특성)

  • 정성래;오재호;최영진
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.307-308
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    • 1999
  • 오존전량은 대류권계면 고도[Hoinka at al., 19961, 기온과 지위 고도[Spankuch and Schulz, 1995], 잠재 와도[Vaughan and Price, 1991] 또는 상대 와도와 같은 기상 변수와 높은 상관관계를 나타낸다. 그리고 성층권 오존량의 감소는 지표 유해자외선을 증가시킨다는 연구 결과가 발표되고 있다(예: 조회구 등 1998; Zerefos et al. 1997).(중략)

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Surface Reflectance Retrieval from Satellite Observation (OMI) over East Asia Using Minimum Reflectance Method (위성관측 오존계에서 최소 반사도법을 이용하여 동아시아 지역의 지면반사도 산출)

  • Shin, Hee-Woo;Yoo, Jung-Moon;Lee, Kwon-Ho
    • Journal of the Korean earth science society
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    • v.40 no.3
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    • pp.212-226
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    • 2019
  • This study derived spectral Lambertian Equivalent Reflectance (LER) over East Asia from the observations of Ozone Monitoring Instrument (OMI) onboard polar-orbit satellite Aura. The climatological (October 2004-September 2007) LER values were compared with the surface reflectance products of OMI or MODerate resolution Imaging Spectroradiometer (MODIS) in terms of the atmosphere-environment variables as follows: wavelength (UV, visible), surface properties (land, ocean), and cloud filtering. Four kinds of LER outputs in the UV and visible region (328-500 nm) were retrieved based on the averages of lowest (1, 5, and 10%) surface reflectance values as well as the minimum reflectance. The average of the lowest 10% among them was in best agreement with the OMI product: correlation coefficient (0.88), RMSE (1.0%) and mean bias (-0.3%). The 10% average and OMI LER values over ocean were 2% larger in UV than in visible, while the values over land were 1% smaller. The LER variability on the wavelength and surface property was highest (~3%) in the condition of both land and visible, particularly in the ice-cap and desert regions. The minimum reflectance values over the oceanic and inland sample areas overestimated the MODIS product by 1.4%. This high-resolution MODIS observations were effective in removing cloud contamination. The relative errors of the 10% average to MODIS were smaller (-0.6%) over ocean but larger (1.5%) over land than those of the OMI product to MODIS. The reduced relative error in the OMI product over land may result from additional cloud filtering using the Landsat data. This study will be useful when retrieveing the surface reflectance from geostationary-orbit environmental satellite (e.g., Geostationary Environment Monitoring Spectrometer; GEMS).

Characteristics of Surface Ozone in a Valley Area Located Downwind from Coastal Cities under Sea-breeze Condition: Seasonal Variation and Related Winds (연안 대도시 해풍 풍하측 계곡지역의 지표오존 분포 특성: 계절변화와 바람과의 관계)

  • Kang, Jae-Eun;Oh, In-Bo;Song, Sang-Keun;Kim, Yoo-Keun
    • Journal of Environmental Science International
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    • v.21 no.2
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    • pp.153-163
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    • 2012
  • The seasonal variations of ozone ($O_3$) concentrations were investigated with regard to the relationship between $O_3$ and wind distributions at two different sites (Jung Ang (JA): a semi-closed topography and Seo Chang (SC): a closed topography) within a valley city (Yangsan) and their comparison between these sites (JA and SC) and two non-valley sites (Dae Jeo (DJ) and Sang Nam (SN)) located downwind from coastal cities (Busan and Ulsan). This analysis was performed using the data sets of hourly $O_3$ concentrations, meteorological factors (especially, wind speed and direction), and those on high $O_3$ days exceeding the 8-h standard (60 ppb) during 2008-2009. In summer and fall (especially in June and October), the monthly mean values of the daily maximum $O_3$ concentrations and the number of high $O_3$ days at JA (and SC) were relatively higher than those at DJ (and SN). The increase in daytime $O_3$ concentrations at JA in June was likely to be primarily impacted by the transport of $O_3$ and its precursors from the coastal emission sources in Busan along the dominant southwesterly winds (about 5 m/s) under the penetration of sea breeze condition, compared to other months and sites. Such a phenomenon at SC in October was likely to be mainly caused by the accumulation of $O_3$ and its precursors due to the relatively weak winds under the localized stagnant weather condition rather than the contribution of regional transport from the emission sources in Busan and Ulsan.

Molecular Size Distributions of NOM in Conventional and Advanced Water Treatment Processes (기존수처리 공정 및 고도정수처리 공정에서 NOM의 분자크기 분포 변화)

  • Choi, Il-Hwan;Jung, Yu-Jin
    • Journal of Korean Society on Water Environment
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    • v.24 no.6
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    • pp.682-689
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    • 2008
  • The purpose of this study was to find out the variation between molecular size distribution (MSD) of natural organic matter (NOM) in raw waters after different water treatment processes like conventional process (coagulation, flocculation, filtration) followed by advanced oxidation process (ozonation, GAC adsorption). The MSD of NOM of Suji pilot plant were determined by Liquid Chromatography-Organic Carbon Detection (LC-OCD) which is a kine of high-performance size-exclusion chromatography (HPSEC) with nondispersive infrared (NDIR) detector and $UV_{254}$ detector. Five distinct fractions were generally separated from water samples with the Toyopearl HW-50S column, using 28 mmol phosphate buffer at pH 6.58 as an eluent. Large and intermediate humic fractions were the most dominant fractions in surface water. High molecular weight (HMW) matter was clearly easier to remove in coagulation and clarification than low molecular weight (LMW) matter. Water treatment processes removed the two largest fractions almost completely shifting the MSD towards smaller molecular size in DW. No more distinct variation of MSD was observed by ozone process after sand filtration but the SUVA value were obviously reduced during increase of the ozone doses. UVD results and HS-Diagram demonstrate that ozone induce not the variation of molecular size of humic substance but change the bond structure from aromatic rings or double bonds to single bond. Granular activated carbon (GAC) filtration removed 8~9% of organic compounds and showed better adsorption property for small MSD than large one.

Delignification Effect on Properties of Lignocellulose Nanofibers from Korean White Pine and Their Nanopapers (잣나무 유래 리그노셀룰로오스 나노섬유 및 나노종이 특성에 미치는 탈리그닌의 영향)

  • Jang, Jae-Hyuk;Lee, Seung-Hwan;Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.1
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    • pp.9-16
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    • 2015
  • This study was carried out to investigate the effect of delignification on properties of lignocellulose nanofibers (LCNFs) prepared by wet disk-milling (WDM) after steam and ozone oxidation pre-treatments and their nanopaper sheets. Delignification treatment was effective to obtain fine morphology with uniform fiber diameter less than 35 nm without aggregation, and increased the specific surface area (SSA) and filtration time of LCNFs. In particular, SSA and filtration time of the LCNFs prepared by WDM after ozone pretreatment increased 1.5 and 5.4 times after further delignification. Delignification also increased whiteness and decreased the redness of nanopaper sheets. The highest color difference (41.9) before and after the delignification was obtained in LCNFs prepared by WDM after the steam pretreatment. Tensile properties of nanopaper sheets were also increased by further delignification. The highest tensile strength was found to be 142 MPa.

Sensitivity Analysis of the WRF Model according to the Impact of Nudging for Improvement of Ozone Prediction (오존농도 예측 정확도 향상을 위한 자료동화기법에 따른 WRF모델의 기상민감도 연구)

  • Kim, Taehee;Jeong, Ju-Hee;Kim, Yoo-Keun
    • Journal of Environmental Science International
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    • v.25 no.5
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    • pp.683-694
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    • 2016
  • Sensitivity analysis of the WRF model according to the impact of nudging (e.g., nudging techniques and application domains) was conducted during high nocturnal ozone episode to improve the prediction of the regional ozone concentration in the southeastern coastal area of the Korean peninsula. The analysis was performed by six simulation experiments: (1) without nudging (e.g., CNTL case), (2) with observation nudging (ONE case) to all domains (domain 1~4), (3) with grid nudging (GNE case) to all domains, (4)~(6) with grid nudging to domain 1, domain 1~2 and domain 1~3, respectively (GNE-1, GNE-2, GNE-3 case). The results for nudging techniques showed that the GNE case was in very good agreement with those observed during all analysis periods (e.g., daytime, nighttime, and total), as compared to the ONE case. In particular, the large effect of grid nudging on the near-surface meteorological factors (temperature, relative humidity, and wind fields) was predicted at the coastline and nearby sea during daytime. The results for application domains showed that the effects of nudging were distinguished between the meteorological factors and between the time periods. When applied grid nudging until subdomain, the improvement effects of temperature and relative humidity had differential tendencies. Temperature was increased for all time, but relative humidity was increased in daytime and was decreased in nighttime. Thus, GNE case showed better result than other cases.

A Study of Ozone Generation Characteristic using Ceramic Catalyst Tube of Ti-Si-Al (Ti-Si-Al형 세라믹 촉매 방전관의 오존 발생 특성 연구)

  • 조국희;김영배;이동훈
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.16 no.6
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    • pp.130-136
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    • 2002
  • A novel ozonizer has been developed using a high frequency surface discharge and a high purity Ti-Si-Al ceramic catalyst as its dielectric component. A cylindrical thin compound ceramic catalyst in reactor is adhered to inside of the film-like outside electrode. And, when experiment condition are oxygen gas temperature of 20 [$^{\circ}C$], inner reactor pressure of 1.6 atm 600[Hz] and flow late of 2[l/min]. the ozonizer can easily produce ozone concentration(50~60[g/㎥]for oxygen) and power efficiency(180[g/kWh]for oxygen) without using a special enrichment means. At 2[l/min], 20[$^{\circ}C$], 1.6[atm], 600[Hz]and 40[W], the result of simulation to gas temperature of reactor using general code Phoenics, the maximum temperature of reactor was 132[$^{\circ}C$]in reactor. Ant the result electric field simulation of Ti-Si-Al type reactor using general code Flux 2D, maximum electric field was 0.131E.08[V/m].

Ultraviolet-ozone irradiation of HPMC thin films: Structural and thermal properties

  • Abdel-Zaher, Nabawia A.;Moselhey, Manal T.H.;Guirguis, Osiris W.
    • Advances in materials Research
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    • v.6 no.1
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    • pp.1-12
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    • 2017
  • The aim of the work was to evaluate the effect of ultraviolet-ozone ($UV-O_3$) irradiation with different times on the structure and thermal properties of hydroxypropyl methylcellulose (HPMC) in the form of a thin film to be used as bioequivalent materials according to their important broad practical and medical applications. HPMC thin films were exposed to $UV-O_3$ radiation in air at a wavelength of 184.9 nm.The beneficial effects of this treatment on the crystallinity and amorphousity regions were followed by X-ray diffraction technique and FTIR spectroscopy. Differential scanning calorimetry, thermogravimetric and differntial thermal analyses were used in order to study the thermal properties of HPMC samples following the process of photodegradation. The obtained results indicated that the rate of degradation process was increased with increasing the exposure time. Variations in shape and area of the thermal peaks were observed which may be attributed to the different degrees of crystallinity after exposing the treated HPMC samples. This meant a change in the amorphousity of the treated samples, the oxidation of its chemical linkages on its surface and its bulk, and the formation of free radical species as well as bond formation.

Parameterization Model for Damaging Ultraviolet-B Irradiance

  • Kim, Yoo-Keun;Lee, Hwa-Woon;Moon, Yun-Seob
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.3 no.1
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    • pp.41-56
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    • 1999
  • Since UV-B radiation measuring networks have not been established, numerical models which calculate the flux from other readily available meteorological measurements may play an important role. That is, such a problem can be solved by using parameterization models such as two stream approximation, the delta-Eddington method, doubling method, and discrete ordinate method. However, most UV-B radiative transfer models have not been validated with measurements, because such models are not intended as practical computational schemes for providing surface estimates of UV-B radiation. The main concern so far has been to demonstrate model sensitivity for cloudless skies. In particular, few have been concerned with real cloud information. Clouds and aerosols have generally been incorporated as constituents of particular atmospheric layers with specified optical depths and scattering properties. The parameterization model presented here is a combination of a detailed radiative transfer algorithm for a coludless sky radiative process and a more approximate scheme to handle cloud effects. The model input data requires a daily measurement of the total ozone amount plus a daily record of the amount and type of cloud in the atmosphere. Measurements for an examination of the models at the Department of Atmospheric Sciences, Pusan National University have been takenfrom February, 1995. These models can be used to calculate present and future fluxes where measurements have not been taken, and construct climatologies for the period before ozone depletion began.

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