• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.304-304
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• 2010

The study on the catalytic oxidation of carbon monoxide (CO) to carbon dioxide ($CO_2$) using the noble metals has long been the interest subject and the recent progress in nanoscience provides the opportunity to develop new model systems of catalysts in this field. Of the noble metal catalysts, we selected ruthenium (Ru) as metal catalyst due to its unusual catalytic behavior. The size of colloid Ru NPs was controlled by the concentration of Ru precursor and the final reduction temperatures. For catalytic activity of CO oxidation, it was found that the trend is dependent on the size of Ru NPs. In order to explain this trend, the surface oxide layer surrounding the metal core has been suggested as the catalytically active species through several studies. In this poster, we show the influence of surface oxide on Ru NPs on the catalytic activity of CO oxidation using chemical treatments including oxidation, reduction and UV-Ozone surface treatment. The changes occurring to UV-Ozone surface treatment will be characterized with XPS and SEM. The catalytic activity before and after the chemical modification were measured. We discuss the trend of catalytic activity in light of the formation of core-shell type oxide on nanoparticles surfaces.

• Proceedings of the Korean Vacuum Society Conference
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• 1994.06a
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• pp.109-109
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• 1994

• Proceedings of the KSRS Conference
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• 2005.10a
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• pp.458-461
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• 2005

Surface Solar Insolation is important for vegetation productivity, hydrology, crop growth, etc. However, ground base measurement stations installed pyranometer are often sparsely distributed, especially over oceans. In this study, Surface Solar Insolation is estimated using the visible and infrared spin scan radiometer(VISSR) data on board Geostationary Meteorological Satellite (GMS)-S covering from March 2001 to December 2001 in clear and cloudy conditions. To retrieve atmospheric factor, such as, optical depth, the amount of ozone, H20, and aerosol, SMAC (Simplified Method for Atmospheric Correction) code, is adopted. The hourly Surface Solar Insolation is estimated with a spatial resolution of $5km\;\times\;5km$ grid. The daily Surface Solar Insolation is derived from the available hourly Surface solar irradiance, independently for every pixel. The pyranometer by the Korea Meteorological Agency (KMA) is used to validate the estimated Surface Solar Insolation with a spatial resolution of $3\;\times\;3Pixels.$

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2344-2347
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• 2007

To generate negative ion, a small dielectric barrier discharge (DBD) plasma reactor was used in this study and operated by high AC voltage. With increasing of voltage, we can get more negative ions. However unfortunately, if the input voltage is too high, it will also cause formation of ozone which is very harmful to human being health. So the work of finding out the best condition of Voltage and frequency was carried out firstly. After several times of measurement, operating at 20 kHz frequency is the best condition generating high ion concentration without ozone. For the purpose of finding out the best reactor structure, two types of surface dielectric barrier discharge (DBD) reactors were examined to produce negative oxygen ions at the conditions of 20 kHz frequency. The results indicated that the surface DBD reactor with several small tips showed better characteristics for generation of negative oxygen ions at the same condition.

• Journal of Environmental Science International
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• v.11 no.7
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• pp.663-667
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• 2002

The aerodynamic resistance($R_a$) to vertical transfer in the surface boundary layer can be formulated in terms of the friction velocity, height of observation, vertical heat flux and surface roughness. Unlike previous studies which focused on the role of $R_c$, present study perform additional tests using a variety of $R_a$ formulae. Several $R_a$ formulations available in the literature, suitable for unstable conditions, were tested for their influence on the dry deposition velocity. The canopy resistance($R_c$) determines the shape of the diurnal pattern, while a small amplitude diurnal cycle in $V_d$ was attributed to the aerodynamic resistance. The aerodynamic resistance is the major contributor to the formation of spikes in nighttime and $R_a$ is relatively important at night because the canopy resistance is smaller. All formulations show similar diurnal cycle and yield good agreement with the observations. Although present $V_d$ formulations are suitable for numerical air qualify models, the research must continue for further improvements in resistance parametrizations.

• Journal of Environmental Science International
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• v.14 no.2
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• pp.231-240
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• 2005

The number of cases exceeding environmental standards of atmospheric ozone in the major cities in Korea has steadily increased during the past decades. In order to understand and analyze the atmospheric reactions in the atmosphere, especially the secondary photochemical reactions, smog chambers studies have been performed very actively by many research groups worldwide. However, these studies have focused on the mechanism of photochemical reactions in high concentration conditions, not at the ambient levels. Therefore, in-depth studies in these conditions are essentially needed to realize exact mechanism in the atmosphere near the earth surface, especially at Korean atmospheric conditions. In this experiment, the mechanism of photochemical smog was examined through a comparative experiment of smog chambers under sun light and black light conditions. The results of our study indicated that concentrations of ozone, aldehyde, and PAN increased as the radiation of light source increases. Photochemical reaction patterns can be considered quite similar for both black light and sun light experiments. Based on our experiments using toluene as a reactant which is present at significant high levels in ambient air relative to other VOCs, it was found that toluene could contribute notably to oxidize NO to $NO_2$, this reaction can eventually generate some other photochemical oxidants such as ozone, aldehyde, and PAN. The results of simulation and experiments generally showed a good agreement quite well except for the case of $O_3$. The restriction of oxidization of NO to $NO_2$ seems to cause this difference, which is mainly from the reaction of peroxy radical itself and other reactants in the real gas.

• Asian Journal of Atmospheric Environment
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• v.5 no.1
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• pp.29-40
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• 2011

In this study, the effects of an urban thermal environment on air quality were investigated using hourly surface weather observation data and air quality data over six summers from 2000 to 2005 in two cities on the Korean Peninsula. One, the city of Daegu, is representative of basin topography and the other, the city of Busan, represents a coastal area. It is known that the characteristics of an urban thermal environment are represented as an "urban heat island". Here, we focus on the nighttime urban thermal environment, which is called a "tropical night", during the summer. On tropical nights in Busan, the temperature and cloud cover levels were higher than on non-tropical nights. Wind speed did not appear to make a difference even on a tropical night. However, the frequency of southwestern winds from the sea was higher during tropical nights. The prevailing southwest winds in all areas meant an inflow of air from the sea. So at most of the air quality stations, the ozone concentration during tropical nights was lower than during non-tropical nights. In Daegu, the tropical nights had higher temperatures and cloud covers. Despite these higher temperatures, the ozone concentration during the tropical nights was lower than that on non-tropical nights at most of the air quality stations. This feature was caused by low irradiance, which in turn caused an increased cloud cover. Wind speed was stronger during the tropical nights and dispersed the air pollutants. These meteorological characteristics of the tropical nights reduced ozone concentrations in the Daegu Basin.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.22 no.12
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• pp.142-149
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• 2008

This paper proposes an effective decomposition method of trichloroethylene using pellet packed-bed non-thermal plasma reactor and catalyst. For that, two types of reactors filled with manganese dioxide and alumina pellets are designed. When $MnO_2$ packed reactor is used, TCE decomposition rate is high due to the generation of oxygen atom radicals at the surface of catalyst during ozone decomposition. In addition, When $Al_2O_3$ packed reactor is used, TCE is oxidized into DCAC and it did not decomposed into small molecules such as COx and $Cl_2$. However, the plasma processed gas using $Al_2O_3$ packed reactor is passed through the $MnO_2$ catalyst reactor, which is placed at the downstream of plasma reactor, the decomposition rate increased as well due to oxygen atom radicals through ozone decomposition. Therefore, the adequate use of $MnO_2$ catalyst in the plasma process is very promising way to increase the decomposition efficiency.

• Journal of Sensor Science and Technology
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• v.13 no.1
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• pp.66-71
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• 2004

Pt-doped zinc oxide (ZnO:Pt) films were deposited by ultrasonic spray pyrolysis. Resistivity variation with Pt concentration was measured. The Pt distribution in ZnO:Pt films was studied through Auger Electron Spectroscopy (AES). The ZnO:Pt films were annealed in the ambient of air, water vapor and ozone, respectively. The variation in crystallographic properties and surface morphologies with respect to the annealing condition was observed by X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). The resistivity variation of the films with the annealing condition was measured. Finally, Atomic Force Microscopy (AFM) measurements were carried out to study the effects of the annealing on the roughness of ZnO:Pt films.

• Journal of Korean Society for Atmospheric Environment
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• v.28 no.3
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• pp.249-260
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• 2012

Monitoring of climate change and atmospheric environment by satellite measurements has been increased in recent years. In this study, nitrogen dioxide ($NO_2$) measurements from Ozone Monitoring Instrument (OMI) were compared with surface measurements over the Korean peninsula. $NO_2$ from OMI measurements showed high values and also showed seasonal variations such as high concentration in winter and low in summer over metropolitan areas while $NO_2$ concentration at national background station was low and did not clearly show seasonal variations. Surface measurements showed similar temporal and spatial variations to those of satellite measurement. The comparison between satellite measurements and surface measurements showed that the correlation between them was higher in urban area (r=0.64 at Seoul and r=0.63 at Daegu) than in national background stations (r=0.37 at Jeju) because the concentration in urban area was relatively high so that the variation of $NO_2$ concentration could be detected better than at national background stations by satellite. Satellite can effectively measure the emission and transport of pollutants with no limitations in spatial coverage.