• Title/Summary/Keyword: Surface ozone

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The effect of iron ions on the reducing of natural organic matter and THMFP in ozonation (오존 처리 시 철 2가 이온이 자연유기물질과 트리할로메탄 저감에 미치는 영향)

  • Kwak, Yeonwoo;Lee, Seulki;Jang, Gyuhwan;Hong, Seongho
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.6
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    • pp.447-456
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    • 2019
  • This study focused on natural organic matter and trihalomethane removal by ozonation with various ferrous concentration in surface water. Ozonation is more affected by injection concentration than reaction time. dissolved organic carbon removal rates in ozonation increased with the increase in ferrous concentration. The highest removal was obtained at 6 mg/L of ferrous concentration. When 1 mg/L of ferrous was added with 2 mg/L of ozone concentration, it was found to be a rapid decrease in specific ultraviolet absorbance at the beginning of the reaction because ferrous acts as a catalyst for producing hydroxyl radical in ozonation. As ozone concentration increased, trihalomethane formation potential decreased. When 2 mg/L of ozone was injected, trihalomethane formation potential was shown to decrease and then increase again with the increase in ferrous concentration.

Corona Discharge and Ozone Generation Characteristics of a Wire-to-Wire Plasma Reactor with a Ferroelectric Pellet Layer (강유전체층을 갖는 선대선 방편 플라즈마장치의 코로나 방전 및 오존발생 특성)

  • 문재덕;신정민;한상옥
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.7
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    • pp.377-381
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    • 2004
  • A discharge plasma reactor using a ferroelectric pellet packed bed is now used as a removal means of pollutant gases, such as NOx, SOx and VOCs. When an ac voltage is applied to this plasma reactor, then the pellets are polarized, and great electric fields are formed at each top and bottom contact points of the ferroelectric pellets. Thus the points of each pellet become covered with intense corona discharges, where an electrophysicochemical reaction is taking place strongly However these strong discharges also elevate the temperature of the pellets greatly and concurrently decrease the output ozone generation, as a result, the overall removal efficiency of gas becomes decreased greatly A new configuration of discharge plasma reactor using a ferroelectric pellet layer and a wire-to-wire electrode has been proposed and investigated experimentally. It is found that an intensive microdischarge is taking place on the surface of ac corona-charged ferroelectric pellet layer of the proposed reactor, which concurrently enhances the efficiency of plasma generation greatly And, this type of configuration of plasma reactor utilizing a wire-to-wire electrode and a ferroelectric pellet layer could be used as one of effective plasma reactors to remove pollutant gas.

Comparison of Chlorine, Chlorine Dioxide and Ozone as Disinfectants in Drinking Water (정수소독공정에 이용되는 염소, 이산화염소, 오존 소독제의 비교, 고찰에 관한 연구)

  • Lee, Yoon-Jin;Lee, Sun-Jong;Lee, Dong-Chan;Kim, Hyun;Lee, Hwan;Lee, Cheol-Hyo;Nam, Sang-Ho
    • Journal of Environmental Health Sciences
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    • v.28 no.3
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    • pp.1-8
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    • 2002
  • The experiments for the characterization of inactivation were performed in a series of batch processes with the total coliform as a general indicator organism based on chlorine, chlorine dioxide and ozone as disinfectants. The water sam-ples were taken from the outlet of settling basin in a conventional surface water treatment system that is provided with the raw water drawn from the mid-stream of the Han River. The inactivation of total coliform was experimentally ana-lyzed for the dose of disinfectant contact time, pH, Temperature and DOC. The nearly 2.4,3.0,3.9 log inactivation of total coliform killed by injecting 1 mか1 at 5 minutes for chlorine, chlorine dioxide and ozone. For the inactivation of 99.9%(3 log), Disinfectants required were 1.70, 1.00 and 0.60 mか1 for chlorine, chlorine dioxide and ozone, respec-tively. The higher the pH is, the poorer the disinfections effects are in the range of pH 6-9 by using chlorine and ozone. But the irfluence of pH value on killing effects of chlorine dioxide is weak. The parameters estimated by the models of Chick-Watson, Hom, and Selleck from our experimental data obtained for chlorine are: log(N/ $N_{0}$ )=-0.16 CT with n= 1, log(N/ $N_{0}$ )=-0.71 $C^{0.87}$T with n$\neq$1, for Chicks-Watson model, log (N/ $N_{0}$ )= -1.87 $C^{0.47}$ $T^{0.36}$ for Hom model. For chlorine dioxide are: log(N/ $N_{0}$ )= -1.53 CT with n = 1, log(N/ $N_{0}$ )= -2.29 $C^{0.94}$T with n$\neq$1,, for Chicks-Watson model, log(N/ $N_{0}$ )= -3.64 $C^{0.43}$ $T^{0.24}$ for Hom model and for ozone are: log(N/ $N_{0}$ )= -2.59 CT with n = 1, log(N/ $N_{0}$ )= -2.28 $C^{0.36}$T with n$\neq$1, for Chicks-Watson model, log(N/ $N_{0}$ )= -4.53 $C^{0.26}$ $T^{0.19}$ for Hom model.19/ for Hom model.

Numerical Study on the Ozone Formation Sensitivity of Precursors Using Adjoint Model around the South-eastern Area of the Korean Peninsula (수반모형을 이용한 한반도 남동지역의 오존 전구물질의 오존 생성 민감도에 관한 수치연구)

  • Park, Soon-Young;Lee, Soon-Hwan;Lee, Hwa Woon;Kim, Dong-Hyeok
    • Journal of the Korean earth science society
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    • v.34 no.7
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    • pp.669-680
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    • 2013
  • Ozone sensitivity analysis with respect to $NO_x$ is conducted around the south-eastern area of the Korean Peninsula. WRF-CMAQ modeling system is used to simulate a local circulation and high ozone episode day. To analyze the sensitivity, the adjoint model for CMAQ is adopted in this study. The purpose of current study is to investigate the location that affects a day time ozone concentration of these receptors on the high ozone episode day. Adjoint sensitivity analysis for Daegu shows two areas of influence. One is the range from the neighboring location to Pohang and it affects mainly on the same day as receptor time. The other is the remote south-eastern area from Daegu. This remote influence area suggests that $NO_x$ emitted on the previous day can change the ozone concentration at receptor time. The influence area for Busan, on the other hand, is originated only from the emission on the previous day because the sea-breeze occurred on the episode day makes low influence of surrounding emission. The cross sectional analysis reveals that $NO_x$ advection is important not only near the surface of land but also around the height of boundary layer.

Filler-Elastomer Interactions. 10. Ozone Treatment on Interfacial Adhesion of Carbon Blacks/NBR Compounds (충전재-탄성체 상호작용. 10. 카본블랙/NBR 복합재료의 계면 접착에 미치는 오존처리의 영향)

  • Cho, Ki-Sook;Zaborski, M.;Slusarski, L.;Park, Soo-Jin
    • Elastomers and Composites
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    • v.38 no.2
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    • pp.139-146
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    • 2003
  • In this work, the influence of ozone treatment on surface properties of carbon black is investigated in terms of X-ray photoelectron spectroscopy (XPS) and contact angles. And their mechanical interfacial properties of the carbon black/acrylonitrile butadiene rubber (NBR) compounds are studied by the crosslink density and composite tearing energy ($G_{IIIC}$). As a result, it is found that the increasing of the ozone concentration leads to an increase of the introduction rate of oxygen-containing functional groups onto carbon black surfaces and to an increase of the surface free energy, resulting in improving both crosslink density and tearing energy ($G_{IIIC}$) of the compounds. The results can be explained by the fact that the oxygen-containing functional groups of carbon black surfaces make an increase of the degree of adhesion at interfaces between carbon blacks and rubber matrix.