• Title/Summary/Keyword: Surface modification

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Interfacial Shear Strength and Thermal Properties of Electron Beam-Treated Henequen Fibers Reinforced Unsaturated Polyester Composites

  • Pang Yansong;Cho Donghwan;Han Seong Ok;Park Won Ho
    • Macromolecular Research
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    • v.13 no.5
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    • pp.453-459
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    • 2005
  • Natural fiber henequen/unsaturated polyester (UPE) composites were fabricated by means of a compression molding technique using chopped henequen fibers treated at various electron beam (EB) dosages. The interfacial shear strength (IFSS), dynamic mechanical properties, and thermal expansion behavior were investigated through a single fiber microbonding test, fractographic observation, dynamic mechanical analysis, and thermomechanical analysis, respectively. The results indicated that the interfacial and dynamic mechanical properties significantly depended on the level of the EB treatment irradiated onto the henequen fiber surfaces. The effect of EB treatment on the IFSS, storage modulus and fracture surface of the henequen/UPE composites agreed with each other. The results of this study also suggested that the modification of henequen fiber surfaces at 10 kGy EB is the most effective for improving the interfacial properties of the henequen/UPE composites.

Biological Synthesis of Alkyne-terminated Telechelic Recombinant Protein

  • Ayyadurai, Niraikulam;Kim, So-Yeon;Lee, Sun-Gu;Nagasundarapandian, Soundrarajan;Hasneen, Aleya;Paik, Hyun-Jong;An, Seong-Soo;Oh, Eu-Gene
    • Macromolecular Research
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    • v.17 no.6
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    • pp.424-429
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    • 2009
  • In this study, we demonstrate that the biological unnatural amino acid incorporation method can be utilized in vivo to synthesize an alkyne-terminated telechelic protein, Synthesis of terminally-functionalized polymers such as telechelic polymers is recognized to be important, since they can be employed usefully in many areas of biology and material science, such as drug delivery, colloidal dispersion, surface modification, and formation of polymer network. The introduction of alkyne groups into polymeric material is particularly interesting since the alkyne group can be a linker to combine other materials using click chemistry. To synthesize the telechelic recombinant protein, we attempted to incorporate the L-homopropargylglycine into the recombinant GroES fragment by expressing the recombinant gene encoding Met at the codons for both N- and C-terminals of the protein in the Met auxotrophic E. coli via Hpg supplementation. The Hpg incorporation rate was investigated and the incorporation was confirmed by MALDI-TOF analysis of the telcchelic recombinant protein.

Compensation Design to Reduce Springback in Sheet Metal Forming of 1.2GPa Ultra High Strength Steel (1.2GPa급 강판 판재 성형에서 스프링백 감소를 위한 금형 보상 설계)

  • Kwon, S.H.;Lee, H.S.;Lee, Y.S.;Kim, S.W.;Jung, C.Y.;Hong, S.
    • Transactions of Materials Processing
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    • v.25 no.5
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    • pp.301-305
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    • 2016
  • The manual modification of stamping die has widely been used in order to reduce springback after sheet metal forming. When UHSS (Ultra High Strength Steel) is used in sheet metal forming, the die design considering springback compensation is more difficult because higher strength sheet has more springback. In this study, the optimization method was used in order to design die geometry considering springback compensation after forming of 1.2GPa UHSS. Die geometries were defined as design variables and the springback distance from the die surface was conducted as object function in optimization process. The optimized die geometry considering springback compensation was performed using finite element and optimization analysis. The simulation results such as thickness distribution and springback amount were compared with measured data using 3D optical measurement system (GOM ARGUS, ATOS). And the prediction of springback amount showed a good agreement within test results.

The Reaction Efficiency and Surface Characteristics for Metallic Ions in Air Flotation Process (부상공정에서 금속이온의 기포 표면 전위 특성 및 반응효율)

  • Han, Moo-Young;Dockko, Seok;Kim, Young-Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.2
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    • pp.222-227
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    • 2004
  • Flotation processes involve the use of very small bubbles (micro-bubbles) to separate particles from water. The process has become a good alternative to sedimentation, especially where the particles are small or of low density. Although the flotation process commences with a collision between particles and bubbles, most research has been focused only on the characteristics of the particles. In this paper, recent theoretical and experimental research on the characteristics of bubbles is summarized. The effect on the collision efficiency of the size and charge of bubbles is calculated through trajectory analysis. The size and charge of bubbles are measured under different conditions and the ramifications of the results are discussed. The results may lead to a better understanding and optimization of the existing process. In particular, we discuss an idea that a new advanced flotation process might be possible by the modification of the characteristics of the bubble alone or of both bubble and particle.

Integrated Process for Development of an Optimal Axial Flow Fan (Design, RP, Measurement, Injection Molding, Assembly) (최적 축류팬 개발을 위한 통합공정 (설계, 시제품제작, 측정, 금형가공, 사출, 조립))

  • 박성관;최동규
    • Korean Journal of Computational Design and Engineering
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    • v.3 no.3
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    • pp.201-209
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    • 1998
  • To develop timely an optimal fan, a design system and a new manufacturing process used step by step have to be integrated. A small sized optimal fan for refrigerators, that was the goal on this project, was developed by the following principal processes. All processes are technologically linked in many directions: The existing fan was measured through reverse engineering. The measured data was used for the basic source of 3D design. The performance tests were carried and used as the data for the evaluation of the existing fan. Flow analysis by FANS-3D/sup [1]/ was performed at the given information (pressure drop and flow rate) to find out the configuration of optimal fan design. The flow patterns were investigated to measure the performance of fan through numerical experiment. The grid point data obtained by the above analysis turned into 3D high efficiency fan model by using CATIA. The product was manufactured by RP process (SLS, SLA) and tested the characteristic curves of the developed fan to compare with the existing fan. The modification of fan design were all examined to see any change in performance and checked to find any deficiency in assembling the fan into a duct. After the plastics flow analysis of the injection molding cycle to ensure acceptable quality fan, an optimal mold was processed by using tool-path for the newly designed fan.

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A Numerical Study on the Formation Mechanism of a Mesoscale Low during East-Asia Winter Monsoon

  • Koo, Hyun-Suk;Kim, Hae-Dong;Kang, Sung-Dae;Shin, Dong-Wook
    • Journal of the Korean earth science society
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    • v.28 no.5
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    • pp.613-619
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    • 2007
  • Mesoscale low is often observed over the downstream region of the East Sea (or, northwest coast off the Japan Islands) during East-Asia winter monsoon. The low system causes a heavy snowfall at the region. A series of numerical experiments were conducted with the aid of a regional model (MM5 ver. 3.5) to examine the formation mechanism of the mesoscale low. The following results were obtained: 1) A well-developed mesoscale low was simulated by the regional model under real topography, NCEP reanalysis, and OISST; 2) The mesoscale low was simulated under a zonally averaged SST without topography. This implies that the meridional gradient of SST is the main factor in the formation of a mesoscale low; 3) A thermal contrast ($>10^{\circ}C$) of land-sea and topography-induced disturbance served as the second important factor for the formation; 4) Paektu Mountain caused the surface wind to decelerate downstream, which created a more favorable environment for thermodynamic modification than that was found in a flat topography; and 5) The types of cumulus parameterizations did not affect the development of the mesoscale low.

Poly-3,4-dihydroxybenzaldehyde Modified with 3,4-dihydroxybenzoic acid for Improvement of Electrochemical Activities

  • Cha Seong-Keuck
    • Journal of the Korean Electrochemical Society
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    • v.7 no.4
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    • pp.167-172
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    • 2004
  • 3,4-dihydroxybenzaldehyde(3,4-DHB) was oxidatively el electropolymerized on glassy carbon (GC) electrodes to prepare CC/p-3,4-DHB type electrodes, which were subsequently modified with 3,4-dihydroxybenzoic acid(3,4-DHBA) using 0.05M HCI as a catalyst. The esterification reactions were performed between -OH sites on the polymeric film surface of the p-3,4-DHB and the -COOH sites within the 3,4-DHBA molecules in solution. These reactions had a rate constant value of $1.1\times10^{-1}\;s^{-1}$ for the esterification step as obtained from the first-order rate constant in the solution. The electrochemical responses of the GC/p-3,4-DHB-3,4-DHBA electrodes exert an influence upon the buffer solution, its pH and applied potential ranges. The redox process of the electrode was more easily controlled by charge transfer kinetics than that of the CC/p-3,4-DHB. The modified electrodes had redox active sites that were 10 times more active than those present before modification. The electrical admittance of the modified electrodes was also three times higher than that of the unmodified electrodes. After being annealed in ethanol for 20 hrs the electrodes brought about a 3.3 times greater change of water molecules in the redox reaction. The modified electrodes are stable in the potential range of 0.4 to 0.55V.

Raman spectroscopy study on the reactions of UV-generated oxygen atoms with single-layer graphene on SiO2/Si substrates

  • Ahn, Gwang-Hyun;Kim, Hye-Ri;Hong, Byung-Hee;Ryu, Sun-Min
    • Carbon letters
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    • v.13 no.1
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    • pp.34-38
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    • 2012
  • Successful application of graphene requires development of various tools for its chemical modification. In this paper, we present a Raman spectroscopic investigation of the effects of UV light on single layer graphene with and without the presence of $O_2$ molecules. The UV emission from a low pressure Hg lamp photolyzes $O_2$ molecules into O atoms, which are known to form epoxy on the basal plane of graphene. The resulting surface epoxy groups were identified by the disorder-related Raman D band. It was also found that adhesive residues present in the graphene samples prepared by micro-mechanical exfoliation using adhesive tape severely interfere with the O atom reaction with graphene. The UV-induced reaction was also successfully applied to chemical vapor deposition-grown graphene. Since the current method can be readily carried out in ambient air only with UV light, it will be useful in modifying the surfaces of graphene and related materials.

Functional Properties of Modified Low Density Lipoprotein and Degradation of Modified LDL by Human Monocyte-Macrophages

  • Kim, Tae-Woong;Park, Jae-Hoon;Park, Young-June;Son, Heung-Soon;Yang, Ki-Sook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.24 no.3
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    • pp.362-370
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    • 1995
  • Human plasma low density lipoprotein(LDL) is the main carrier for cholesterol, and recent studies suggest the normal LDL can be readily oxidized by free radical and not interact with LDL receptor. Lipoprotein pariticles are consisted of lipid andprotein, and fatty acids of lipoproteins are prone to oxidation. LDL particles readily undergo oxidative modification by copper. From the results, oxidized LDL altered its biological properties. A marked increase in the electrophoretic mobility of LDl on agarose gel indicated that negative surface charge of the LDL particles was increased. Also, the results from the HPLC showed that oxidized LDL was degraded into several polypeptides nonenzymatically. Degradation tests which measured the amount of 5-IAF labelled oxidized LDL were carried out by monocyte and hepatocyte cell culture. Hepatocyte cell culture of modified LDL did not show consistent pattern. However, binding rate of modified LDL with HMDM(human monocyte derived macrophage) was enhanced with oxidation, but was retarded by addition of antioxidants(hyaluronic acid, vitamin A, vitamin E). Also comparisons of oxidized-LDL, acetyl-LDL and MDA-LDL showed significant differences in the chemical properteis and binding affinity to HMDM. Thus, modificaition of normal LDL altered its biological properties.

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Performance Evaluation of a Solar Tracking PV System with Photo Sensors (포토센서를 이용한 태양위치 추적기의 성능분석에 관한 연구)

  • Jeong, Byeong-Ho;Cho, Geum-Bae;Lee, Kang-Yeon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.27 no.5
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    • pp.67-73
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    • 2013
  • The conversion of solar radiation into electrical energy by Photo-Voltaic (PV) effect is a very promising technology, being clean, silent and reliable, with very small maintenance costs and small ecological impact. The output power produced by the PV panels depends strongly on the incident light radiation. The continuous modification of the sun-earth relative position determines a continuously changing of incident radiation on a fixed PV panel. The point of maximum received energy is reached when the direction of solar radiation is perpendicular on the panel surface. Thus an increase of the output energy of a given PV panel can be obtained by mounting the panel on a solar tracking device that follows the sun trajectory. Tracking systems that have two axes and follow the sun closely at all times during the day are currently the most popular. This paper presents research conducted into the performance of Solar tracking system with photosensors. The results show that an optimized dual-axis tracking system with photosensor performance and analysis. From the obtained results, it is seen that the sun tracking system improves the energy and energy efficiency of the PV panel.ti-junction CPV module promises to accelerate growth in photovoltaic power generation.