• Title/Summary/Keyword: Surface migration

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Electrochemical Ion Migration Sensitivity of Printed Circuit Board Plated with Sn-3.0Ag-0.5Cu and Sn-37Pb (Sn-3.0Ag-0.5Cu, Sn-37Pb 표면처리 기판의 전기화학적 이온 마이그레이션 민감도)

  • Hong, Won-Sik;Park, No-Chang;O, Cheol-Min;Kim, Gwang-Bae
    • Proceedings of the KWS Conference
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    • 2006.10a
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    • pp.136-138
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    • 2006
  • Recently a lots of problems have observed in high densified and high integrated electronic components. One of them is ion migration phenomena, which induce the electrical short of electrical circuit. Ion migration phenomena has been observed in the field of exposing the specific environment and using for a long time. Also as the RoHS restriction was started in July 1st, 2006, Pb-free solder was utilized in electronics assemblies. In this case, it is very important to compatible between components and printed circuit board(PCB), thus surface treatment materials of PCB was changed to Sn, Sn-3.0Ag-0.5Cu, Cu. Therefore these new application become to need to reevaluate the sensitivity about electrochemical ion migration. This study was evaluated the occurrence time of electrochemical ion migration using by water drop test. We utilized PCB(printed circuit board) having a comb pattern as follows 0.1, 0.318, 0.5, 1.0 mm pattern distance. Sn-3.0Ag-0.5Cu and Sn-37Pb were electroplated on the comb pattern. 6.5V and 15.0V were applied in the comb pattern and then we measured the electrical short time causing by occurring the ion migration. In these results, we evaluate the sensitivity and derived the prediction models of ion migration occurrence time depending on the pattern materials, applied voltage and pattern spacing of PCB conductor.

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Acrylic Polymer Composition Suitable for Ion Delivery and Selective Detection of Proton, and Hydroxyl and Cu(II) Ions (이온 이동에 적합한 아크릴고분자 박막의 조성과 수소이온, 수산화이온, 구리이온의 선택적 검출)

  • Lee, Dahye;Woo, Heejung;Do, Jung Yun
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.801-808
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    • 2014
  • Ion diffusion and chemical binding to acrylic polymer were investigated in a solid film. The composition of acrylic monomers containing amino group and carboxylic acid was adjusted for rapid ion migration in the film. p-Methylred (PMR) and phenolphthalein derivatives were optically sensitive to the concentration of proton and hydroxyl anion, respectively and verified the ion migration through the film layers. A rapid proton migration was observed in the film of a high amino content. On the other hand, $OH^-$ migration occurred rapidly in a high content of carboxylic acid group. The proton migration occurred through the internal layer as well as surface layer of a film and was reversible during 50 repetition examination. Copper(II) ion migration was examined with a Rhodamine-containing polymer film. The light absorption and emission spectra of a Rhodamine-Cu complex showed the key contribution of carboxylic acid group to the Cu(II) migration in a film.

Tracking of Yellowtail Seriola quinqueradiata Migration Using Pop-up Satellite Archival Tag (PSAT) and Oceanic Environments Data (위성전자표지와 해양환경자료를 이용한 방어(Seriola quinqueradiata) 이동경로 추적 연구)

  • Kim, Changsin;Yang, Jigwan;Kang, Sujin;Lee, Seung-Jong;Kang, Sukyung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.54 no.5
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    • pp.787-797
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    • 2021
  • Yellowtail Seriola quinqueradiata tagged with a Pop-up Satellite Archival Tag (PSAT) was released off the coast of near the Moseulpo, Jeju Island and the ecological data during about 40 days was obtained. However, it is difficult to determine the spatial location of underwater ecological data. To improve the accuracy of estimating the Yellowtail migration route using temperature, suitable background field of the oceanic environment data was evaluated and used for input data. After developing of the tracking algorithm for migration route estimation, three experiment cases were estimated with ecological data among the surface layer, the mixed layer, and the whole water column. All tracking experiments move from western to eastern Jeju Island. Additionally, tracking experiment using 3D ocean numerical model reveal that it is possible to estimate the migration route using the fish ecological data of the entire water column. Therefore, using a large number of ecological data and a high-accuracy ocean numerical model to estimate the migration route seems to be a way to increase the accuracy of the tracking experiment. Moreover, the tracking algorithm of this study can be applied to small pelagic fishery using small archival electronic tags to track the migration route.

Diurnal Changes of Vertical Distribution of Microcystis aeruginoa during the Water Bloom in Kongsan Reservoir (공산호에서 수화발생동안 Microcystis aeruginosa 수직분포의 변동)

  • Moon, Chu-Whan;Kim, Han-Soon
    • Korean Journal of Ecology and Environment
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    • v.33 no.2 s.90
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    • pp.119-127
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    • 2000
  • Diurnal vertical distribution of phytoplankton and physico-chemical characteristics were studied in Kongsan reservoir during summer 1996, when a dense algal bloom, consisting mostly of Microcystis, developed. The maximum biomass was observed near the surface layer, where Microcystis aeruginosa dominated and declined gradually with depth. The dense population of blue-green alga M. aeruginosa acumulated near the surface layer during the early morning and evening, but abruptly decreased after sunrise. The most of biomass was distributed above 5 m of the water column and diurnal changes of biomass clearly appeared at the surface but was not showed upward and downward migration. The results of this study suggest that diurnal variation of biomass at the surface layer was affected by horizontal migration with wind.

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The Effects of Molding Conditions on the Surface Gloss of ABS Molding (ABS(Acrylonitrile-Butadiene-Styrene) 성형품의 성형조건이 표면 광택에 미치는 영향)

  • Jeong, Yeong-Deug;Hwang, Si-Hyon;Lee, Mi-Hye
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.4 s.97
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    • pp.110-115
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    • 1999
  • The surface gloss of an injection molded part is one of the most significant point for evaluating the quality of products appearance. The effects of process condition on the gloss of ABS(Acrylonitrile-Butadiene-Styrene) molded part were investigated in this work. The measurements of gloss and morphology on the surface of molded part were carried out with different melt temperature, mold temperature, mold surface roughness, injection pressure and holding pressure. Gloss had a maximum value with melt temperature in the range of 210 to 220 ${^\circ}C$ and with mold temperature 40 to 50${^\circ}C$ and with injection pressure 80~90 MPa, respectively. Melt temperature was shown to have the largest effect on gloss in our work. Gloss was not improved in the region of melt temperature 240${^\circ}C$ above and of mold temperature 60${^\circ}C$ above. It was concluded that the variation of gloss was mainly caused by rubber particles migration under shear stress not by their aggregation or necklace.

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Biocompatibility study of lithium disilicate and zirconium oxide ceramics for esthetic dental abutments

  • Brunot-Gohin, Celine;Duval, Jean-Luc;Verbeke, Sandra;Belanger, Kayla;Pezron, Isabelle;Kugel, Gerard;Laurent-Maquin, Dominique;Gangloff, Sophie;Egles, Christophe
    • Journal of Periodontal and Implant Science
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    • v.46 no.6
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    • pp.362-371
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    • 2016
  • Purpose: The increasing demand for esthetically pleasing results has contributed to the use of ceramics for dental implant abutments. The aim of this study was to compare the biological response of epithelial tissue cultivated on lithium disilicate ($LS_2$) and zirconium oxide ($ZrO_2$) ceramics. Understanding the relevant physicochemical and mechanical properties of these ceramics will help identify the optimal material for facilitating gingival wound closure. Methods: Both biomaterials were prepared with 2 different surface treatments: raw and polished. Their physicochemical characteristics were analyzed by contact angle measurements, scanning white-light interferometry, and scanning electron microscopy. An organotypic culture was then performed using a chicken epithelium model to simulate peri-implant soft tissue. We measured the contact angle, hydrophobicity, and roughness of the materials as well as the tissue behavior at their surfaces (cell migration and cell adhesion). Results: The best cell migration was observed on $ZrO_2$ ceramic. Cell adhesion was also drastically lower on the polished $ZrO_2$ ceramic than on both the raw and polished $LS_2$. Evaluating various surface topographies of $LS_2$ showed that increasing surface roughness improved cell adhesion, leading to an increase of up to 13%. Conclusions: Our results demonstrate that a biomaterial, here $LS_2$, can be modified using simple surface changes in order to finely modulate soft tissue adhesion. Strong adhesion at the abutment associated with weak migration assists in gingival wound healing. On the same material, polishing can reduce cell adhesion without drastically modifying cell migration. A comparison of $LS_2$ and $ZrO_2$ ceramic showed that $LS_2$ was more conducive to creating varying tissue reactions. Our results can help dental surgeons to choose, especially for esthetic implant abutments, the most appropriate biomaterial as well as the most appropriate surface treatment to use in accordance with specific clinical dental applications.

Studies on Copper Pillar Bump with Trapezoidal Cross Section on the Top Surface for Reliability Improvement (사다리꼴 상부 단면을 갖는 구리기둥 범프의 신뢰성 향상에 대한 연구)

  • Cho, Il-Hwan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.7
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    • pp.496-499
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    • 2012
  • Modified structure of copper pillar bump which has trapezoidal cross section on the top region is suggested with simulation results and concept of fabrication process. Due to the large surface area of joint region between bump and solder in suggested structure, electro-migration effect can be reduced. Reduction of electro-migration is related with current density and joule heating in bump and investigated with finite element methods with variation of dimensional parameters. Mechanical characteristics are also investigated with comparing modified copper pillar bump and conventional copper pillar bump.

Surface Migration in Al and Cu Films (알루미늄 및 구리 박막에서의 표면전자이주)

  • 박종원;김윤태;이진호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.11a
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    • pp.106-108
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    • 1994
  • Electromigration(EM) tests were carried out on Al and Cu films in HV systems to study surface migration. The Al films were made on oxidized silicon wafers by thermal evaporation, in-situ annealed at 300$^{\circ}C$, patterned, and EM tested at 260$^{\circ}C$ and 4.5MA/$\textrm{cm}^2$. SEM observation with back scattered electron mode on the EM tested Al films disclosed that thinning took place under the native Al oxide. In the case of Cu films, tested using in-situ TEM, thinning was also observed at the early stage of void formation even though the thinned areas were much less than those of the Al films.

Lectin-binding properties of chicken primordial germ cells during embryonic development

  • Kim, Duk-Kyung;Seo, Sam-Youl;Lee, Eun-Young;Lee, Seul-Ki;Han, Jae-Yong
    • Proceedings of the Korea Society of Poultry Science Conference
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    • 2001.11a
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    • pp.69-70
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    • 2001
  • Lectins have great potential as to determine the alternation of the distribution of cell surface carbohydrates during cellular development and differentiation. Here, we investigated the presence and distribution of cell surface carbohydrates on chicken primordial germ cells (PGCs) during the migration and gonadal stages using a variety of lectins. A total of six FITC-labelled lectins from several specificity classes were used: ConA (glucose/mannose), WGA (N-acetylglucosamine), STA (N-acetylglucosamine), DBA (N-acetylgalactosamine/galactose), UEA-I (fucose) and PHA-E (oilgosaccharide). As a results, PGC-specific binding was observed in STA. PGCs of migration stage (2.5- and 5.5-day embyos) were STA-positive whereas PGCs of 10-day embryonic gonad were not. The results suggest that N-acetylglucosamine residuse are present specifically in migrating chicken PGCs and changes during development.

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Effect of Mode of Binding Linkage on Monolayer Assembly of Zeolite

  • Lee, Jin-Seok
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.248-254
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    • 2012
  • During the monolayer assembly of zeolite microcrystals using sonication with stacking (SS) method, the factors that govern the degree of close packing (DCP) between the microcrystals, the rate of attachment (rA) of microcrystals onto the substrate, the degree of coverage (DOC), and the binding strength (BS) between each crystal and the substrate were investigated for each mode of binding linkage (MBL). The tested MBLs were covalent linkage (CL), ionic linkage (IL), and polyelectrolyte-mediated ionic linkage (p-IL). Unlike the monolayers of zeolite crystals assembled on glass with a covalent linkage, the strong BS, very high DOC, and very high DCP do not decrease during monolayer assembly on glass through ionic linkages. This results indicate that the surface migration of crystals undergo linkage-nondestructively when crystals were attached to the substrates through ionic linkages.