• Title/Summary/Keyword: Surface kinetic

Search Result 653, Processing Time 0.028 seconds

The Removal Kinetics of Mn and Co from the Contaminated Solutions by Various Calcium Carbonate Surfaces (다양한 방해석 표면에 대한 Mn과 Co 흡착 기작)

  • H., Yoon;Ko, K.S.;Kim, S.J.
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2004.09a
    • /
    • pp.219-222
    • /
    • 2004
  • Removal characteristics of Mn and Co was studied from the contaminated solutions via surface reaction with various calcium carbonate (calcite). Synthetic calcium carbonates which has different surface morphology as well as surface areas were prepared by a spontaneous precipitation method and used. Mn and Co removal behavior by the different solid surface demonstrate characteristic sorption behaviors depend on the type of calcite used, such as surface area or surface morphology. Calcium carbonate crystals (mostly calcite) which exhibit complicated surface morphology (c-type) shows strong sorption affinity for Mn and Co removal via sorption than on the a-type or b-type calcite crystals of less complicated surfaces. The applicability of two kinetic models, the pseudo-first-order kinetic equation and the Elovich kinetic model was examined on these sorption behavior. Elovich kinetic model was found more suitable to explain the very early stage adsorption kinetics, while the pseudo-first-order kinetic equation was successfully fitted for the adsorption kinetics after 50 hours.

  • PDF

Kinetic Model on the Vacuum Deposition (眞空 蒸着에 관한 速度論的 모델)

  • Kim, Dae-Soo
    • Journal of the Korean institute of surface engineering
    • /
    • v.19 no.2
    • /
    • pp.51-58
    • /
    • 1986
  • A theoretical model was proposed to predict the rate of particles impinging on the negatively biased substrate and the total kinetic energy per unit time. The model takes into an account of kinetic theory based on Maxwell statistics and elementary plasma theory, incorporated with Hertz-Knudsen's evaporation theory. It is found that as the bias potential increases the ion flux and kinetic energy increases to a value above which the effect of potential is insignificant.

  • PDF

A Study on the Vertical upward Bubble Flow using Image Processing Technique (영상기법을 이용한 수직상향 기포유동에 관한 연구)

  • 서동표;오율권
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.27 no.5
    • /
    • pp.617-623
    • /
    • 2003
  • In the present study, the characteristics of upward bubble flow were experimentally investigated in a liquid bath. The velocity of upward bubble flow was calculated for two different experimental conditions:1) bubble flow without kinetic energy 2) bubble flow with kinetic energy. Bubble flow without kinetic energy starts to undergo the effect of buoyancy l0cm away from the nozzle. Whereas. kinetic energy is dominant before 30 cm away from the nozzle in bubble flow but after this point kinetic energy and inertial force are applied on bubble flow at the same time In addition, as the flow rate increases the maximum velocity point moves to the nozzle. The velocity Profiles near free surface is extremely irregular due to surface flow. Gas volume fraction is high near the nozzle due to gas concentration. but decreases with the increasement of axial position. Gas volume fraction does not vary after the axial position, z=60 in spite of the increasement of flow.

Effects of Impact Velocity on Crystallization and Activation Energy of Cu-based Bulk Metallic Glasses in Kinetic Spray Coating (저온 분사 코팅 공정에서 충돌속도에 따른 CuNiTiZr 벌크 비정질 소재의 활성화 에너지와 결정화 거동 분석)

  • Yoon, Sang-Hoon;Bae, Gyu-Yeol;Kim, Jung-Hwan;Lee, Chang-Hee
    • Journal of the Korean institute of surface engineering
    • /
    • v.41 no.6
    • /
    • pp.301-307
    • /
    • 2008
  • In this paper, nanocrystallization of CuNiTiZr bulk metallic glass (BMG) subjecting to a kinetic spraying, dependent on impact velocity, was investigated by numerical and experimental approaches. The crystallization fraction and nucleation activation energy of initial feedstock and as-deposited coating were estimated by DSC and Kissinger method, respectively. The results of numerical modeling and experiment showed that the crystalline fraction and nucleation activation energy in BMG coatings were depended on kinetic energy of incident particle. Upon impact, the conversion of particle kinetic energy leads to not only decreasing free energy barrier but also increasing the driving force for an amorphous to crystalline phase transformation. The nanocrystallization of BMGs is associated with the strain energy delivered by a plastic deformation with a high strain rate.

Utilization of Cotton Stalks-Biomass Waste in the Production of Carbon Adsorbents by KOH Activation for Removal of Dye-Contaminated Water

  • Fathy, Nady A.;Girgis, Badie S.;Khalil, Lila B.;Farah, Joseph Y.
    • Carbon letters
    • /
    • v.11 no.3
    • /
    • pp.224-234
    • /
    • 2010
  • Four activated carbons were produced by two-stage process as followings; semi-carbonization of indigenous biomass waste, i.e. cotton stalks, followed by chemical activation with KOH under various activation temperatures and chemical ratios of KOH to semi-carbonized cotton stalks (CCS). The surface area, total pore volume and average pore diameter were evaluated by $N_2$-adsorption at 77 K. The surface morphology and oxygen functional groups were determined by SEM and FTIR, respectively. Batch equilibrium and kinetic studies were carried out by using a basic dye, methylene blue as a probe molecule to evaluate the adsorption capacity and mechanism over the produced carbons. The obtained activated carbon (CCS-1K800) exhibited highly microporous structure with high surface area of 950 $m^2/g$, total pore volume of 0.423 $cm^3/g$ and average pore diameter of 17.8 ${\AA}$. The isotherm data fitted well to the Langmuir isotherm with monolayer adsorption capacity of 222 mg/g for CCS-1K800. The kinetic data obtained at different concentrations were analyzed using a pseudo-first-order, pseudo-second-order and intraparticle diffusion equations. The pseudo-second-order model fitted better for kinetic removal of MB dye. The results indicate that such laboratory carbons could be employed as low cost alternative to commercial carbons in wastewater treatment.

Homoopitaxial Growth on Ni(110) Surface

  • Kahng, S.J.
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2000.02a
    • /
    • pp.138-138
    • /
    • 2000
  • Kinetic behaviors of homoepitaxial growth on Ni(110) surface was studied at the growth-temperature ranges 290~380 K with scanning tunneling microscopy. At low temperature (~290 K), deposited Ni grows layer-by-layer mode in the first several layers with one-dimensional islands but eventually (at > monolayers) forms three-dimensional islands througy the kinetic shortening of the average length of one-dimensional islands. At the intermediat temperature (~340 K), the three-dimensional islands were observed to be I) regular mesa-like structure with high aspect ratio (~1:10) at ~15 monolayer, ii) hut-like structure with low aspect ratio (~1:1.5) at ~35 monolayer, and iii) rounded mound structure at ~55 monolayers, due to the competition of kinetic and energetic terms. At the high temperature (~ 380 K), the flat surface with layer-by-layer mode was observed up to 50 monolayers. Microscopic orgins for the observations will be discussed on the basis of kinetic Monte Carlo simulations.

  • PDF

A Study on the Bubble Flow in the Gas-Liquid Plume (기-액 기둥에서 기포유동에 관한 연구)

  • Seo, Dong-Pyo;Hong, Myung-Seok;Oh, Yool-Kwon
    • Proceedings of the KSME Conference
    • /
    • 2003.04a
    • /
    • pp.2105-2108
    • /
    • 2003
  • The characteristics of upward bubble flow were experimentally investigated in a liquid bath. In the present study, a thermal-infrared camera and high speed CCO camera were used to measure their temperature and local rising velocity, respectively. Heat transfer from bubble surface to water is largely completed within z=10mm from the nozzle, and then the temperature of bubble surface reaches that of water rapidly. The rising velocity of bubble was calculated for two different experimental conditions: 1) bubble flow without kinetic energy 2) with kinetic energy. Bubble flow without kinetic energy starts to undergo the effect of inertia force 10cm away from the nozzle. Whereas, kinetic energy is dominant before 30 cm away from the nozzle in bubble flow, but after this point, kinetic energy and inertial force are applied on bubble flow at the same time.

  • PDF

A Comparison of the Serratus Anterior Muscle Activity according to the Shoulder Flexion Angles in a Closed Kinetic Chain Exercise and an Open Kinetic Chain Exercise (열린사슬운동 및 닫힌사슬운동에서 위팔굽힘 각도에 따른 앞톱니근의 근활성도 비교)

  • Moon, Sung-Jong;Kim, Tack-Hoon;Roh, Jung-Suk
    • Journal of the Korean Society of Physical Medicine
    • /
    • v.8 no.3
    • /
    • pp.369-378
    • /
    • 2013
  • PURPOSE: The purpose of present study was to ascertain how the activity of the serratus anterior muscle, the upper trapezius muscle and the pectoral major muscle was affected while the upper arm was being flexed at 70, 90 and 110 degrees respectively in a closed kinetic chain exercise (wall push up plus) and an open kinetic chain exercise (static hug). METHODS: Sixteen healthy young men subjects participated in the study. Surface electromyography (EMG) data were collected from the dominant-side muscles during a closed kinetic chain exercise and an open kinetic chain exercise. The activity of each muscle was measured quantitatively, and by the use of the two-way repeated ANOVA, the data were compared with each other according to exercises and shoulder flexion angles. RESULTS: Results indicated that the closed kinetic chain exercise did not interact with the open kinetic chain exercise (p>.05). In both the closed kinetic chain exercise and the open kinetic chain exercise, the activity of the serratus anterior muscle became different significantly according to angles (p<.05). Its activity increased in order of 70, 90 and 110 degrees (p<.05). In both exercises and all angles, muscle activity was significantly higher in the serratus anterior muscle than in the upper trapezius muscle and the pectoral major muscle (p<.05). CONCLUSION: The above results show that there is a need to selectively control the exercise stress of the serratus anterior muscle in the case of the patients with the shoulder impingement syndrome characterized by the winged scapula, insufficient scapular protraction and upward rotation.

Investigating the Cause of Hindrance to the Interfacial Bonding of INCONEL 718 Layer Deposited by Kinetic Spray Process (저온 분사 공정을 이용해 적층된 INCONEL 718의 계면접합 저해요인 분석)

  • Kim, Jaeick;Lee, Seungtae;Lee, Changhee
    • Journal of the Korean institute of surface engineering
    • /
    • v.48 no.6
    • /
    • pp.275-282
    • /
    • 2015
  • The cost for maintenance (replacement cost) of Ni-superalloy components in plant industry is very expensive because of high unit price of INCONEL 718. A development of repairing technology using kinetic spray process can be very helpful for reducing the maintenance cost. However, it is very difficult to produce well-deposited INCONEL 718 layer showing high interfacial bond strength via kinetic spraying. Thus, INCONEL 718 was deposited on SCM 440 substrate and the interfacial properties were investigated, in order to elucidate the cause of hindrance to the bonding between INCONEL 718 layer and SCM 440 substrate. As a result, it was revealed that the dominant obstacle to the interfacial bonding was excessive compressive residual stress accumulated in the coating layer, resulting from low plastic-deformation susceptibility of INCONEL 718. Nevertheless, the bonding state was enhanced by the post heat-treatment through relieving the residual stress and generating a diffusion/metallurgical bonding between the INCONEL 718 deposit and SCM 440 substrate.

Interaction between Raindrops Splash and Sheet Flow in Interrill Erosion of Steep Hillslopes (급경사면의 세류간 침식에서 빗물튀김과 면상흐름의 상호작용)

  • Nam, Myeong Jun;Park, Sang Deog;Lee, Seung Kyu;Shin, Seung Sook
    • Journal of Korea Water Resources Association
    • /
    • v.48 no.7
    • /
    • pp.595-604
    • /
    • 2015
  • Interrill erosion by the rainfall is divided into a detachment of soil particles by raindrop splash when raindrops having kinetic energy strike on the surface soil and a sediment transport by sheet flow of surface runoff. Rainfall kinetic energy is widely used as an indicator expressing the potential ability to separate the soil particles from soil mass. In this study, the soil erosion experiments of rainfall simulation were operated to evaluate the effects of rainfall kinetic energy on interrill erosion as using the strip cover to control raindrop impact. The kinetic energy from rainfall simulator was 0.58 times to that of natural rainfall. Surface runoff and subsurface runoff increased and decreased respectively with increase of rainfall intensity. Surface runoff discharge from plots of non-cover was 1.82 times more than that from plots with cover. The rainfall kinetic energy influenced on the starting time of surface and subsurface runoff. Soil erosion quantity greatly varied according to existence of the surface cover that can intercept rainfall energy. Sediment yields by the interaction between raindrop splash and sheet flow increased 3.6~5.9 times and the increase rates of those decreased with rainfall intensity. As a results from analysis of relationship between stream power and sediment yields, rainfall kinetic energy increased the transport capacity according to increase of surface runoff as well as the detachment of soil particles by raindrop splash.