• 제목/요약/키워드: Surface hydration

검색결과 254건 처리시간 0.029초

버블시트 피복양생법에 의한 소성 및 건조수축 균열저감 (Plastic and Drying Shrinkage Cracking Reduction by the Bubble Sheet Curing)

  • 이정교;한천구
    • 한국건축시공학회지
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    • 제16권3호
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    • pp.211-217
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    • 2016
  • 본 연구에서는 2015년 가을철 실제 시공중인 고층 아파트를 대상으로 1중 백색 버블시트로 타설된 콘크리트의 표면을 덮어주는 버블시트 피복양생 공법과 표면을 노출한 채로 양생없이 유지하는 표면노출 방법간을 비교하여 소성 및 건조수축균열의 저감정도를 분석하였다. 실험 결과, 버블시트를 시공하였을 경우, 수화열 및 적산온도는 표면노출보다 약간 높았고, 바닥 균열의 갯수, 길이, 최대 균열폭, 균열 면적 모두 현저하게 적은 값이 측정되었다. 따라서 가을철 버블시트를 타설된 콘크리트 표면에 적용 할 경우에는 소성 및 건조수축균열을 획기적으로 방지할 수 있는 효과적인 표면피복 양생공법인 것으로 판단되었다.

고강도 고함량 고로슬래그 혼합 시멘트 모르터의 수화 및 포졸란 반응에 미치는 석회석 미분말과 실리카퓸의 영향 (Effects of Limestone Powder and Silica Fume on the Hydration and Pozzolanic Reaction of High-Strength High-Volume GGBFS Blended Cement Mortars)

  • 정지용;장승엽;최영철;정상화;김성일
    • 콘크리트학회논문집
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    • 제27권2호
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    • pp.127-136
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    • 2015
  • 본 연구는 고강도 고함량 고로슬래그 콘크리트의 특성에 미치는 석회석 미분말과 실리카퓸의 영향을 검토하기 위해 50%에서 최대 80%까지 고로슬래그를 다량 혼합하고, 석회석 미분말을 최대 20%, 실리카퓸을 최대 10%까지 혼합한 물-결합재비 20%의 고강도 시멘트 모르터의 유동성, 강도발현, 수화 및 포졸란 반응 특성, 공극율 및 공극 크기 분포 등을 분석하였다. 실험결과에 따르면 고함량 고로슬래그 배합은 포틀랜드 시멘트 배합에 비해 고로슬래그의 낮은 표면 마찰로 유동성이 크게 향상되고, 시멘트 수화에 필요한 자유수가 많아져 수화반응이 촉진되면서 초기강도가 증가하나, 너무 낮은 물-결합재비와 단위시멘트량으로 인해 수산화칼슘의 생성량이 부족하여 포졸란 반응이 충분히 활성화되지 못함에 따라 장기강도 발현이 억제된다. 석회석 미분말은 유동성에는 큰 영향을 주지 않고, 역시 시멘트의 초기 수화를 촉진하는 것으로 나타났으나, 수화를 가속하는 효과는 고로슬래그보다 높지 않고, 고로슬래그와 달리 수경성이 없기 때문에 오히려 석회석 미분말의 치환율이 높아질수록 압축강도가 낮아지는 것으로 나타났다. 또한 고분말의 고로슬래그를 사용하거나, 또는 실리카퓸으로 고로슬래그를 치환하는 경우 시멘트 수화에 필요한 자유수를 더 많이 흡착함으로써 유동성과 강도를 저하시키는 것으로 나타났다. 또한 고로슬래그를 사용한 배합의 공극율이 보통 포틀랜드 시멘트 배합보다 낮게 나타났으나, 석회석 미분말은 공극율에 뚜렷한 영향을 나타내지 않았고 실리카퓸은 낮은 시멘트 수화도로 인해 공극율을 오히려 증가시키는 것으로 나타났다. 반면 공극 크기 분포에 있어서는 고로슬래그와 실리카퓸를 혼합한 경우 미세공극이 증가하는 것으로 나타났다.

Gas Reaction Characteristics of Waste Oyster Shell Sorbent

  • Jung, Jong-Hyeon;Shon, Byung-Hyun;Kim, Hyun-Gyu;Yoo, Kyung-Seun;Choung, Young-Hean;Choi, Suck-Gyu;Kim, Young-Sik
    • 한국환경보건학회:학술대회논문집
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    • 한국환경보건학회 2005년도 국제학술대회
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    • pp.365-370
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    • 2005
  • The objective of this study is to develop the sorbent of oyster shell, which can remove gaseous acid pollutants emitted from the incinerator and power plants. The physicochemical properties of prepared absorbents have been measured using ICP and BET Also, this study is to investigate the Hydration/calcination reaction in the fixed bed reactor. Thus, the results could be summarized as follows. Oyster shell can be used in powder type without former processing. It should be also noted that sulfation reactivity of oyster sample increases to about 5 times by calcination/hydration reaction due to the increase of specific surface area and pore volume. From these experiments, we have found that both $SO_2$ and $NO_x$ in simulated flue gas can be effectively removed by use of oyster absorbent.

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쪽 니람의 DNCB 유발 생쥐의 아토피 피부염에 미치는 효과 (The Effect of the Polygonum tinctoria Niram on Atopic Dermatitis in DNCB-Induced Hairless Mice)

  • 추한나;박은혜;정종길;백윤웅;김정상
    • 대한한의학방제학회지
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    • 제22권1호
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    • pp.141-150
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    • 2014
  • Objectives : The purpose of this study was to investigate the effects of Polygonum tinctoria Niram(PTN) on atopic dermatitis(AD) in hairless mice induced by 2,4-dinitrochlorobenzene(DNCB). Method : They were divided into four group, Nor, Con, 1X and 5X, for evaluating the change of appearance of skin surface, skin hydration, thickness of epidermis and mast cell numbers during 30 days. Results : PTN suppressed symptoms of AD in appearance of skin and increased skin hydration for 1X and 5X. In histopathological examination, 1X and 5X significantly reduced the thickness of epidermis and number of mast cell in dermis. These results suggested that the PTN improved the AD-like symptoms of hairless Mice.

계측에 의한 지하철 박스구조물 벽체부의 균열 밑 구조거동 예측 (Pre-estimate on Structural Behavior and Cracks of Subway Wall Structures Using Gage Measurement)

  • 김영진;김상철
    • 한국철도학회논문집
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    • 제9권6호
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    • pp.657-663
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    • 2006
  • By measuring concrete temperature and strains of concrete and reinforcing bars throughout gages embedded and also by observing the crack occurrence, this study aims at the characteristics of structural behavior of subway wall structure in associate with concrete ages. The length of 23.5m, thickness of 2.0m of real subway custody line was selected as a representative structure and 7 thermocouples and 6 strain gages were installed to measure the behavior of wall structure. The results were compared and verified with analytical results using MIDAS in order to show their usefulness. It was found that only attachment of strain gages on the surface of reinforcing bars can figure out the timing of crack occurrence and hydration heat program is useful to estimate comparatively exact magnitudes of temperature. Since estimated time of crack occurrence throughout thermal stress analysis depends on the period of transferred thermal stress from concrete to reinforcing bars, however, cracks from naked eyes were identified later than analytical results. Cracks were observed first at the center of wall line and then to the end of line symmetrically.

수밀 콘크리트용 규불화염계 무기 조성물을 첨가한 콘크리트 수밀성 및 균열저감 특성 (Watertightness and Crack Reduction Property of Concrete added Fluosilicate Salt Based Inorganic Compound for Watertight Concrete)

  • 김도수;길배수;최세진;박민용;이성연;여병철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2004년도 학술대회지
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    • pp.33-38
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    • 2004
  • This study was performed to know watertightness and reduction effect and crack occurred by hydration heat, restraint of multiplication of hydration heat, through mechanical test, strength test and crack control test using fluosilicate salt based inorganic compound made from by-product during phosphoric acid manufacturing process. Mix proportions for experiment were modulated at 0.45 of water to cement ratio and $0.5-2.0\%$ of adding ratio of fluosilicate salt based inorganic compound. Evaluation for watertightness of concrete was carried out permeability, absorption test and porosity analysis. Effect of crack reduction was evaluated by length, drying shrinkage as well as stress change of hardened concrete at unrestraint/restraint state and also elucidated crack pattern on the concrete surface. It is ascertained that characteristics of crack resistance and watertightness for concrete was improved by an adequate addition of fluosilicate salt based inorganic compound.

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이중버블시트를 이용한 단열양생공법의 한중콘크리트 현장적용 (Field Application of Insulation Curing Method with Double Bubble Sheets Subject to Cold Weather)

  • 홍석민;백대현;김종;전충근;한민철;한천구
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2008년도 춘계 학술논문 발표대회
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    • pp.57-60
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    • 2008
  • This study investigated the results of insulation heat curing method using double layer bubble sheet in slab concrete and mass concrete in cold weather environment. First of all, when double bubble sheets are applied, it was shown that slab concrete was protected from early freezing by remaining between 6 and 15℃ even in case outside temperature drops -9℃ below zero until the 2nd day from piling, and in the case of mass concrete, with the maximum temperature difference between the center and surface less than 4℃, crack occurrence index was close to 2 and no hydration heat crack occurred by internal constraint. The insulation heat preservation curing method using the double bubble sheet applied in this field prevented early freezing owing to stable curing temperature management, deterring concrete strength development delay at low temperature, and obtained the needed strength. Also, it was proven that the method is highly effective and economic for cold weather concrete quality maintenance through curing cost reduction like construction period shortening and labor cost reduction, etc by reducing the process of temporary equipment installation and disassembling.

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겉보리 및 쌀보리의 수화속도 (Absorption of Water by Husked and Naked Barley)

  • 이종숙;김성곤
    • 한국식품과학회지
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    • 제15권3호
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    • pp.220-224
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    • 1983
  • 겉보리(올보리와 강보리) 및 쌀보리(세도하다가와 백동)를 각각 40 및 30%도정한 다음, 20, 30 및 $40^{\circ}C$에서 6시간 침지하면서 수화속도를 검토하였다. 수화속도는 수화시간의 평방근에 비례하였고, 확산계수 ($D,\;cm^{2}/min$)는 D = $D_{0}\;{\exp}\;(-E_{a}/RT)$로 표시되었다. 확산계수 값은 강보리가 돌보리보다 다소 높았으며, 세도하다가와 백동은 비슷하였다. 쌀보리의 확산계수는 겉보리보다 다소 높았다.

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공유결합으로 다공성 막에 고정화된 효소에 의한 이산화탄소 포집 (Carbon Dioxide Sequestration of Enzyme Covalently Immobilized on Porous Membrane)

  • 박진원
    • KSBB Journal
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    • 제28권4호
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    • pp.225-229
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    • 2013
  • Bovine Carbonic anhydrase (BCA) was immobilized on a submicro-porous membrane through covalent immobilization. The immobilization was conducted on the porous membrane surface with the treatment of polyethyleneimine, glutaraldehyde, and the anhydrase, in sequence. The immobilization was confirmed using X-ray photon spectrometer. The pH values of carbon-dioxide saturated solution with buffer were monitored with respect to time to calculate the catalytic activities of hydration of carbon-dioxide for free and immobilized CA. The catalytic rate constant values for free CA, immobilized CA on polystyrene nanoparticles, and immobilized CA on a porous cellulose acetate membrane were 0.79, 0.67, and 0.56 $s^{-1}$, respectively. Reusability was studied up to 10 cycles of $CO_2$ sequestration. The activity for the CA immobilized on the membrane was kept to 95% after 10 cycles, and comparable to the CA on the nanoparticles. The stabilities for heat and storage were also investigated for the three cases. The results suggested that the CA immobilized the membrane had the least loss rate of the activity compared to the others. From this study, the porous membrane was feasible as a carrier for the CA immobilization in hydration and sequestration of carbon-dioxide.

숏크리트용 고분말도 슬래그 시멘트의 특성 (A Study on Properties of High Blaine Slag Cement for Shotcrete)

  • 김재영;염수경;유동우;최현국
    • 한국세라믹학회지
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    • 제47권5호
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    • pp.357-364
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    • 2010
  • This study was performed to get basic information about properties of high blaine slag cement(HSC) to use shotcrete(or sprayed concrete and mortar). Particle size distribution, setting time and compressive strength test, analysis like as SEM, DSC thermal analysis, XRD was carried out to investigate principle properties of HSC. Setting time of HSC was delayed slightly, but influence of accelerators was more bigger than ordinary portland cement(OPC). Compressive strength of HSC at 28 days was more higher than OPC regardless of using accelerators. Results of analysis showed early period hydration products of HSC is more small and located widely, because of the interface of between cement particle and water is increased as specific surface of cement increase. From the SEM observation and analysis of DSC and XRD results, aluminates accelerators bring on some hydration products like as calcium aluminium hydrates, alkali free accelerators increases ettringite and monosulfates. Aluminates accelerators has a advantage of setting time and early strength, alkali free accelerators increases strength after 7 days.