• Title/Summary/Keyword: Surface functional group

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ITO와 AZO 동시 증착법으로 제조된 투명전도막의 특성 연구 (Investigation of Transparent Conductive Oxide Films Deposited by Co-sputtering of ITO and AZO)

  • 김동호;김혜리;이성훈;변응선;이건환
    • 한국표면공학회지
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    • 제42권3호
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    • pp.128-132
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    • 2009
  • Transparent conducting thin films of indium tin oxide(ITO) co-sputtered with aluminum-doped zinc oxide(AZO) were deposited on glass substrate by dual magnetron sputtering. It was found that the electrical properties and structural characteristics of the films are significantly changed according to the sputtering power of the AZO target. The IAZTO film prepared with D.C power of ITO at 100 W and R.F power of AZO at 50 W shows an electrical resistivity of $4.6{\times}10^{-4}{\Omega}{\cdot}cm$ and a sheet resistance of $30{\Omega}/{\square}$ (for 150 nm thick). Besides of the improvement of the electrical properties, compared to the ITO films deposited at the same process conditions, the IAZTO films have very smooth surface, which is due to the amorphous nature of the films. However, the electrical conductivity of the IAZTO films was found to be deteriorated along with the crystallization in case of the high temperature deposition (above $310^{\circ}C$). In this work, high quality amorphous transparent conductive oxide layers could be obtained by mixing AZO with ITO, indicating possible use of IAZTO films as the transparent electrodes in OLED and flexible display devices.

A Method for Absolute Determination of the Surface Areal Density of Functional Groups in Organic Thin Films

  • Min, Hyegeun;Son, Jin Gyeong;Kim, Jeong Won;Yu, Hyunung;Lee, Tae Geol;Moon, Dae Won
    • Bulletin of the Korean Chemical Society
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    • 제35권3호
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    • pp.793-797
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    • 2014
  • To develop a methodology for absolute determination of the surface areal density of functional groups on organic and bio thin films, medium energy ion scattering (MEIS) spectroscopy was utilized to provide references for calibration of X-ray photoelectron spectroscopy (XPS) or Fourier transformation-infrared (FT-IR) intensities. By using the MEIS, XPS, and FT-IR techniques, we were able to analyze the organic thin film of a Ru dye compound ($C_{58}H_{86}O_8N_8S_2Ru$), which consists of one Ru atom and various stoichiometric functional groups. From the MEIS analysis, the absolute surface areal density of Ru atoms (or Ru dye molecules) was determined. The surface areal densities of stoichiometric functional groups in the Ru dye compound were used as references for the calibration of XPS and FT-IR intensities for each functional group. The complementary use of MEIS, XPS, and FT-IR to determine the absolute surface areal density of functional groups on organic and bio thin films will be useful for more reliable development of applications based on organic thin films in areas such as flexible displays, solar cells, organic sensors, biomaterials, and biochips.

Adsorption Selectivities between Hydroxypyridine and Pyridone Adsorbed on the Ge(100) Surface

  • Lee, Myungjin;Lee, Hangil
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.137-137
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    • 2013
  • The most stable adsorption structures and their corresponding energies of 4-pyridone, 4-hydroxypyridine, 2-pyridone and 2-hydroxypyridine have been investigated by Density Functional Theory (DFT) calculation method and high-resolution photoemission spectroscopy (HRPES). We confirmed that between the two reaction centers of 4- and 2-pyridone, only O atom of carbonyl functional group can act as a Lewis base and thus, O dative bonding structure is the most stable. On the other hand, we clarified that both the two reaction centers (the cyclic N atom and the O atom of hydroxyl functional group) of 4- and 2-hydroxypyridine (tautomers of 4- and 2-pyridone) can successfully function as a Lewis base. Through the interpretation of the N 1s and O 1s core level spectra obtained using HRPES, we could confirm the electronic structures and bonding configurations of these molecules with a coverage dependence on the Ge(100) surface.

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불안정 지지면과 안정 지지면에서의 만성 뇌졸중 환자의 균형 능력 비교 (Comparison of Balance Ability between Stable and Unstable Surfaces for Chronic Stroke Patients)

  • 이지연;노효련
    • 한국산학기술학회논문지
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    • 제12권8호
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    • pp.3587-3593
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    • 2011
  • 본 연구는 만성 뇌졸중 환자를 대상으로 하여 불안정한 지지면과 안정 지지면에서의 균형 훈련이 균형능력향상에 어떠한 영향을 주는지 알아보고자 한다. 이 연구의 대상자는 만성 뇌졸중 환자 30명(남: 16, 여: 14)으로 안정지지면 군과 불안정 지지면 군으로 무작위로 배분하여 주 5회 6주 동안 실시하였다. 균형증진 운동은 선행 연구를 참조하여 수정 보완한 것으로 6가지의 운동으로 구성하였다. 대상자들의 균형능력의 측정은 기능적 기립 균형 검사, 기능적 전방 팔 뻗기 검사, 실행능력 지향형 운동성 평가를 이용하였다. 기능적 기립 균형검사와 실행능력 지향형 운동성 평가에서는 안정지지면 운동군과 불안정 지지면 운동군 두 군에서 향상되었다. 기능적 전방 팔 뻗기 검사에서는 불안정 지지면 군에서만 향상되었다. 따라서, 안정 지지면에서의 운동도 만성 뇌졸중 환자의 균형능력 향상을 시키지만 불안정 지지면 운동군에서의 균형운동이 균형 능력 향상에 더 효과적인 것으로 나타났다.

기능적 발목 불안정성 축구 선수에 대한 움직임을 동반한 가동술과 테이핑 적용이 균형과 점프 수행력에 미치는 영향 (Effect of MWM and Taping on Balance and Jump Performance in Soccer Player with Functional Ankle Instability)

  • 정용식;정연우;정영준
    • 대한정형도수물리치료학회지
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    • 제22권1호
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    • pp.43-49
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    • 2016
  • Background: The purpose of this study was to investigate the effects on balance and Jump performance in soccer player with functional ankle instability of Movement with mobilization (MWM) and taping. Methods: In 30 male college soccer player with functional ankle instability subjects of this study randomization, fibular reposition taping (FRT) group (n=10), kinesio taping (KT) group (n=10), control group (n=10) that included in the MWM and taping was classified group.Before and after intervention, measured in surface area ellipse and countermovement jump with arm swing. Results: Showed a significant balance and jump performance from the FRT group and KT group compared to the control group. Showed a significant improvement in balance from the FRT group compared to the KT group. Conclusions: MMW and taping showed the increased balance and Jump performance in soccer player with functional ankle instability.

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어깨관절 아탈구가 있는 만성 뇌졸중환자에게 기능적 전기자극 치료가 기능회복에 미치는 효과 (Effect of Functional Recovery for the Functional FES upon Chronic Stroke Patients with Shoulder Subluxation)

  • 황룡;김찬문
    • 대한물리치료과학회지
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    • 제16권4호
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    • pp.75-81
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    • 2009
  • Background: The purpose of this study was to confirm whether surface FES was effective in the function of chronic stroke patients' affected shoulder and whether FES influenced their functional abilities in ADL, as well. Method: the subjects were inpatients at a general hospital in Gyeonggi-Do, Korea and had been diagnosed as a sub-luxation in their affected shoulder. They were 26 and were separated to an experimental group and a control group, in equal number. Both groups had gotten an exercise treatment for 6 weeks. The control group didn't get any FES as opposed to the experimental group. Result: in the experimental group there was no statistical significant difference in the vertical space and the joint space, even though the space was reduced. In the control group, there was no statistical significant difference, either. Moreover, each space of their shoulders was increased. In the range of motion of each group, there was no statistical significant difference. In functional independent ability, there was a significant difference in an experimental group. In contrast, there was no difference in a control group. Conclusion: this result suggests that FES should be effective in the sub-luxation of the patients' affected shoulder and the range of motion of their shoulders. On the other hand, compared to the previous items, FES was quite effective in the functional improvement.

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산화그레핀을 이용한 바나듐레독스흐름전지용 카본펠트전극의 표면개질을 통한 전기화학적 활성개선 (Electrochemical Enhancement of Carbon Felt Electrode for Vanadium Redox Flow Battery with Grephene Oxide)

  • 이건주;김선회
    • 한국수소및신에너지학회논문집
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    • 제28권2호
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    • pp.206-211
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    • 2017
  • Carbon felt electrode for the vanadium redox-flow battery (VRFB) has been studied to see the effect of grephene oxide (GO) treatment on the surface of the carbon felt electrode. In this paper, surface of carbon felt electrodes were treated with various concentrations of grephene oxide. Electrochemical analysis, cyclic voltammetry (CV), was performed to investigate redox characteristics as electrode for VRFB. Also the effect of GO on the introduction of functional group on the surface of carbon felt electrodes were investigated using X-ray photoelectron spectroscopy (XPS), which discovered increase in the overall functional group content on the surface of carbon felts.

Cytosolic domain regulates the calcium sensitivity and surface expression of BEST1 channels in the HEK293 cells

  • Kwon Woo Kim;Junmo Hwang;Dong-Hyun Kim;Hyungju Park;Hyun-Ho Lim
    • BMB Reports
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    • 제56권3호
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    • pp.172-177
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    • 2023
  • BEST family is a class of Ca2+-activated Cl- channels evolutionary well conserved from bacteria to human. The human BEST paralogs (BEST1-BEST4) share significant amino acid sequence homology in the N-terminal region, which forms the transmembrane helicases and contains the direct calcium-binding site, Ca2+-clasp. But the cytosolic C-terminal region is less conserved in the paralogs. Interestingly, this domain-specific sequence conservation is also found in the BEST1 orthologs. However, the functional role of the C-terminal region in the BEST channels is still poorly understood. Thus, we aimed to understand the functional role of the C-terminal region in the human and mouse BEST1 channels by using electrophysiological recordings. We found that the calcium-dependent activation of BEST1 channels can be modulated by the C-terminal region. The C-terminal deletion hBEST1 reduced the Ca2+-dependent current activation and the hBEST1-mBEST1 chimera showed a significantly reduced calcium sensitivity to hBEST1 in the HEK293 cells. And the C-terminal domain could regulate cellular expression and plasma membrane targeting of BEST1 channels. Our results can provide a basis for understanding the C-terminal roles in the structure-function of BEST family proteins.

Effect of Heel Raise Exercise with NMES on Peroneus Longus Muscle Strength and Postural Control Ability in Subjects with Functional Ankle Instability: Randomized Controlled Trial

  • Seo, Joon Ho;Lee, Jeon-Hyeong;Lee, Mi Young
    • The Journal of Korean Physical Therapy
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    • 제33권1호
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    • pp.28-33
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    • 2021
  • Purpose: This study examined the effects of heel raise exercises combined with neuromuscular electrical stimulation (NMES) on the muscle strength and postural control ability of subjects with functional ankle instability (FAI). Methods: Twenty-two subjects with FAI participated in this study. They were assigned randomly to two groups: 11 each in the NMES and the sham-NMES groups. Heel raise exercise was applied, and NMES electrodes were attached to the peroneus longus muscles. The NMES group applied NMES during the heel raise exercise. NMES was applied for 20 minutes during the heel raise exercise. The heel raise exercise was performed four times a week for five weeks. The muscle strength and balance error scoring system (BESS) were measured before and after the intervention. Results: A comparison of before and after the intervention within the groups revealed improved muscle strength in the NMES and Sham-NMES groups, but the BESS was improved under all conditions only in the NMES group. The Sham-NMES group showed no improvement in the unstable support surface. Furthermore, when comparing the amount of change before and after the intervention between the groups, there were significant differences in the total score and unstable support in the BESS and muscle strength. Conclusion: NMES had a positive effect on the functional activities of the functional ankle instability subjects, such as balancing on an unstable support surface during postural control and increasing muscle strength.

A Study on the Characteristics and Surface Modification of the Zeocarbon for Water Treatment

  • Kim, Seo-A;Hong, Ji-Sook;Suh, Jeong-Kwon;Lee, Jung-Min
    • Carbon letters
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    • 제6권3호
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    • pp.166-172
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    • 2005
  • The objective of this study was to investigate the possibility of application for water treatment using the zeocarbon. The zeocarbon was mixture of zeolite and activated carbon. In general, the application of commercial zeocarbon to water treatment is difficult because of weak strength in water and the high pH value of effluents after water treatment. Therefore, we have modified the surface of zeocarbon. For the surface modification, we used the acid treatment to make surface functional group. As a result of modification, was created functional group on zeocarbon surface and was formed mesopore in zeocarbon. The surface modified zeocarbon was applied to removal of nitrogen. In removal experiments of nitrogen, removal efficiency was very high. And, strength of zeocarbon after water treatment and pH of effluents were stabilized. This indicates that the surface modified zeocarbon was easy to recover and reuse. Consequently, our results were shown the possibility of application for water treatment using the surface modified zeocarbon.

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