• 한국수소및신에너지학회논문집
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• 제29권6호
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• pp.559-569
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• 2018

Catalytic supports made of carbon have many advantages, such as high coking resistance, tailorable pore and surface structures, and ease of recycling of waste catalysts. Moreover, they do not require pre-reduction. In this study, ash-free coal (AFC) was obtained by the thermal extraction of carbonaceous components from raw coal and its performance as a carbon catalytic support was compared with that of well-known activated carbon (AC). Nickel was dispersed on the carbon supports and the resulting catalysts were applied to the steam reforming of toluene (SRT), a model compound of biomass tar. Interestingly, nickel catalysts dispersed on AFC, which has a very small surface area (${\sim}0.13m^2/g$), showed higher activity than those dispersed on AC, which has a large surface area ($1,173A/cm^2$). X-ray diffraction (XRD) analysis showed that the particle size of nickel deposited on AFC was smaller than that deposited on AC, with the average values on AFC ${\approx}11nm$ and on AC ${\approx}23nm$. This proved that heteroatomic functional groups in AFC, such as carboxyls, can provide ion-exchange or adsorption sites for the nano-scale dispersion of nickel. In addition, the pore structure, surface morphology, chemical composition, and chemical state of the prepared catalysts were analyzed using Brunauer-Emmett-Taylor (BET) analysis, transmission electron microscopy (TEM), scanning electron microscopy (SEM), x-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, and temperature-programmed reduction (TPR).

• 대한기계학회논문집A
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• 제29권5호
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• pp.663-670
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• 2005

DIN CK35 (JIS S35CK) steels have been used as a material in fuel pump blocks for marine engines. Failures in the inner surface of a drilling hole, due to the initiation of fatigue cracks have been frequently reported. However, the mechanism initiating these cracks and growths has not been clearly diagnosed yet. This study was conducted using a scraped fuel pump block, containing an initiated fatigue crack in the inner surface of a drilling hole. Initially, the cracks and fractured surfaces inside the block were investigated using an optical microscope and a SEM (Scanning Electron Microscope). In addition, microstructure observation, fatigue life test and fatigue crack growth test were performed using a specimen, which was taken from the same block. Results from these tests are summarized as follows; (1) The early crack in the block was supposed to occur inside the inner surface of the drilling hole. (2) The fatigue endurance of this material was about 330 Mpa. (3) The early crack was generated in the cavitations created by the breakdown of a big inclusion, or separation between the big inclusion and the base metal, in which the fundamental ingredients of the inclusion were C, 5, and Mn. (4) In order to prevent these types of failures, the suppression of inclusions inflow by improving the casting process, formation of fine inclusions by applying a heat treatment process, and coating of the surface of the drilling hole were required.

• Corrosion Science and Technology
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• 제19권2호
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• pp.57-65
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• 2020

As competition among global automakers intensifies, demand for materials that are better in price and performance is increasing. While steel and plastic materials compete for automotive fuel tanks, plastic materials have advantages such as light weight for automobiles. However, they have high prices. Accordingly, in this paper, four types of Zn-X plated steel sheets, electroplating (X = none, Sn) and galvannealed (X = Fe, Fe-Mg), were manufactured and their applicability as a fuel tank material was evaluated. Nano-composite coating solution with good conductivity was treated on the surface of plated steels using a roll coater and then cured through induction furnace to improve corrosion resistance. Quality characteristics such as corrosion resistance, fuel resistance to diverse gasoline and diesel fuels, and seam weldability were evaluated for the above plated steels. Their properties were compared and analyzed with conventional Zn-Ni electroplating steels. Among the above plated steels, Zn-Fe-Mg galvannealed steels coated with nano-composite coating exhibited better properties than other steels. Detailed experimental results suggest that evenly distributed Mg elements on the coating layer play a key role in the enhanced quality performance.

• 한국연소학회:학술대회논문집
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• 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
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• pp.173-178
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• 2003

An experimental study is conducted to investigate the effects of fuel temperature on the spray characteristics of a dual-orifice type swirl injector which is used in gas turbines. The major parameters affecting spray characteristics are fuel temperature and injection pressure entering into the injector. Fuel temperature is shown to have strong influence on the spray characteristics especially at a lower temperature. In this study, fuel temperature is varied from $30^{\circ}C$ to $120^{\circ}C$ and injection pressure is altered from 3 to $7 kg_{f}$ /$cm^{2}$. Two kinds of fuel, which have different surface tension and viscosity, are chosen as an atomizing fluid. As a result, injection instability occurs in the low temperature range due to icing phenomenon and the change of fuel properties. As the injection pressure increases, the kinematic viscosity range for stable atomization becomes wider. The factor controlling the SMD of spray is substantially different depending on the fuel temperature range.

• 전기학회논문지P
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• 제58권4호
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• pp.568-573
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• 2009

Because of environmental crisis, researchers are seeking and developing a new, clean, safe and renewable energy. Solar cell energy and fuel cell energy have inestimable development potential. The paper introduces hybrid photovoltaic-fuel cell generation systems supplying a remote power load and hybrid system of solar cell and fuel cell considering the advantages of stable and sustainable energy from the economic point of view. Fuel cell power system has been proven a viable technology to back up severe PV power fluctuations under inclement weather conditions. Fuel cell power generation, containing small land us, is able to alleviate the heavy burden for large surface requirement of PV power plants. In addition, the PV-fuel cell hybrid power system shows a very little potential for lifetime $CO_2$ emissions. In this paper shows the I-V characteristics of the solar module which are dependent on the power of the halogen lamp and the I-V characteristics of fuel cells which are connected in parallel. Also, it shows efficiency of the hybrid system.

• 한국분무공학회지
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• 제2권2호
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• pp.43-50
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• 1997

The purpose of this investigation is to carry out, the influence factor on the fuel spray characteristics for improve the engine combustion performance and exhaust omission in direct injection type diesel engine. The fuel properties, fuel spray structure and the shape or the piston surface of diesel engine play an important role of engine combustion process and exhaust emission. In order to obtain the effect of using auxiliary chamber and emulsified fuel on the fuel spray characteristics the experiment un conduct with single cylinder direct injection type diesel engine to examine the engine performance and gas emission. The results of this investigation showed that the increase auxiliary chamber volume and emulsified fuel give an effect on the fuel spray characteristics by reduced the concentration of nitric oxide emission in the combustion chamber. Also it can improve the combustion characteristics such as cylinder pressure, rate of pressure rise and rate of heat release.

• Nuclear Engineering and Technology
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• 제52권12호
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• pp.2880-2886
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• 2020

A small leak occurring on the surface of a fuel rod due to damage exposes UO₂ to a steam atmosphere. During this time, fission gas trapped inside the fuel rod leaks out, and the gas leakage can be increased due to UO₂ oxidation. Numerous studies have focused on the steam oxidation and its thermodynamic calculation in UO₂. However, the thermodynamic calculation of the UO₂ oxidation in a pressurized water reactor (PWR) environment has not been studied extensively. Moreover, the kinetics of the oxidation of UO₂ pellet also has not been investigated. Therefore, in this study, the thermodynamics of UO₂ oxidation under steam injection due to a damaged fuel rod in a PWR environment is studied. In addition, the diminishing radius of the UO₂ pellet with time in the PWR environment was calculated through an experiment simulating the initial time of steam injection at the puncture.

• 한국산림과학회지
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• 제94권6호
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• pp.481-487
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• 2005

이 연구에서는 지표화 중심의 산불확산예측 알고리즘을 기반으로 GIS 환경에서 운용이 가능한 지표화 확산예측모델을 개발하였다. 이 모델은 지형, 연료, 기상 등 산불환경인자를 분석하고 입력하는 부분과 시간에 따라 확산속도, 화선에서의 산불강도, 연소면적을 예측하는 지표화 확산예측 부분, 마지막으로 예측결과를 사용자에게 제시하는 출력 부분으로 구성되었다. 산불확산속도를 계산하기 위해서 산불행동에 영향을 미치는 산불환경인자중에서 지형인자는 경사, 기상인자는 풍속, 풍향, 실효습도를 고려하였다. 또한 연료인자는 수치임상도를 이용하여 연료깊이, 연료량, 소화습도를 계산할 수 있는 연료모듈을 개발하여 입력되도록 하였다. 연료습도는 실효습도, 최고온도, 강수량, 일일 적산량의 함수관계로 추정하였다. 모델을 2002년 청양에서 발생한 산불에 적용한 결과 확산속도에 대해 61%의 일치도를 보였다.

• Nuclear Engineering and Technology
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• 제54권6호
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• pp.1972-1981
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• 2022

A typical ferritic/martensitic (F/M) steel sheet was subjected to pulsed laser surface remelting (LSR) and corrosion test in lead-bismuth eutectic (LBE) at 550 ℃. There present two modification zones with distinct microstructures in the LSRed specimen: (1) remelted zone (RZ) consisting of both bulk δ-ferrite grains and martensitic plates and (2) heat-affected zone (HAZ) below the RZ, mainly composed of martensitic plates and high-density precipitates. Martensitic transformation occurs in both the RZ and the HAZ with the Kurdjumov-Sachs and Nishiyama-Wassermann orientation relationships followed concurrently, resulting in scattered orientations and specific misorientation characteristics. Hardnesses of the RZ and the HAZ are 364 ± 7 HV and 451 ± 15 HV, respectively, considerably higher than that of the matrix (267 ± 3 HV). In oxygen-saturated and oxygen-depleted LBE, thicknesses of oxide layers developed on both the as-received and the LSRed specimens increase with prolonging corrosion time (oxide layers always thinner under the oxygen-depleted condition). The corrosion resistance of the LSRed F/M steel in oxygen-saturated LBE is improved, which can be attributed to the grain-refinement accelerated formation of dense Fe-Cr spinel. In oxygen-depleted LBE, the growth of oxide layers is very low with both types of specimens showing similar corrosion resistance.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 1999년도 추계학술발표회 초록집
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• pp.27-28
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• 1999