• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.458-458
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• 2012

Fuel Cell is used stacking metal or polymer substrate. This hydro property of substrate surface is very important. Usually, surface property is hydrophilic. The surface oxidation of SUS is investigated through plasma treatments with an atmospheric-pressure dielectric barrier discharge (DBD) for increasing hydrophilic property. The plasma process makes an experiment under various operating conditions of the DBD, which operating conditions are treatment time, plasma gas mixture ratio, the plasma source supply frequency. Two kinds of SUS substrate, SUS-304 and SUS 316L, were used. Discharge frequency has a crucial impact on equipment performance and gas treatment. After the plasma treatment of a SUS plate, highly improved wettability was noted. But, when high oxygen supply, the substrate damaged seriously.

• Nuclear Engineering and Technology
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• v.52 no.9
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• pp.2054-2063
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• 2020

The high-temperature oxidation behavior of ZrSi₂ used as a coating material for nuclear fuel cladding was investigated for developing accident-tolerant fuel cladding of light water reactors. Bulk ZrSi₂ samples were prepared by spark plasma sintering. In situ X-ray diffraction was conducted in air at 900, 1000, and 1100 ℃ for 20 h. The microstructures of the samples before and after oxidation were examined by scanning electron microscopy and transmission electron microscopy. The results showed that the oxide layer of zirconium silicide exhibited a layer-by-layer structure of crystalline ZrO₂ and amorphous SiO₂, and the high-temperature oxidation resistance was superior to that of Zircaloy-4 owing to the SiO₂ layer formed. ZrSi₂ was coated on the Zircaloy-4 tube surface using laser 3D printing, and the coated tube was oxidized for 2000 s at 1200 ℃ under a vapor/argon mixture atmosphere. The outer surface of the coated tube was hardly oxidized (10-30 ㎛), while the inner surface of the uncoated tube was significantly oxidized to approximately 300 ㎛.

• Proceedings of the KSME Conference
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• 2000.11b
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• pp.732-737
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• 2000

The purpose of this study is to compare the SMD(Sauter mean diameter) with different vibrant plates. Each vibrant plates have different surface roughness. Also liquid film thickness are measured for explanation how to concern atomization. Ultrasonic waves is used for vibration. Immersion liquid method is used for the measure of SMD and also liquid film thickness is measured using of point needle method. Distilled water and gasoline fuel are used to liquids. Supplied liquid flow rates are $18{\sim}296cc/min$. Centerline average roughness of vibrant plates are 0.5, 2.0, 4.7, $9.5\;{\mu}m$ and diameter of vibrant plate is 60mm. In result, good atomization of liquid is obtained in widen flow rates. The mean droplet size is increased in orders of 4.7, 2.0. 9.5, $0.5\;{\mu}m$ surface roughness. Distilled water has a big mean droplet size than gasoline fuel in low flow rate. Above the 78cc/min flow rates, distilled water has a small mean droplet size than gasoline fuel. Liquid films changes are measured with ultrasonic power. Also, cavitation effect on sprays is observed.

• Journal of the Korean Electrochemical Society
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• v.8 no.2
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• pp.106-114
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• 2005

This article covers the theoretical ac-impedance models for the analysis of oxygen reduction on the porous cathode electrode f3r solid oxide fuel cell (SOFC). Firstly, ac-impedance models were explained on the basis of the mechanism of oxygen reduction, which were classified into the rate-determining steps; (i) adsorption of oxygen atom on the electrode surface, (ii) diffusion of adsorbed oxygen atom along the electrode surface towards the three-phase (electrode/electrolyte/gas) boundaries, (iii) surface diffusion of adsorbed oxygen atom m ixed with the adsorption reaction of oxygen atom on the electrode surface and (iv) diffusion of oxygen vacancy through the electrode coupled with the charge transfer reaction at the electrode/gas interface. In each section for ac-impedance model, the representative impedance plots and the interpretation of important parameters attributed to the oxygen reduction reaction were explained. Finally, we discussed in detail the applications of the proposed theoretical ac-impedance models to the real electrode of SOFC system.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.115.2-115.2
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• 2010

Autothermal reforming(ATR) processes of hydrocarbon liquids such as diesel fuels are spotlighted as methods to produce hydrogen for Fuel cell. However, the use of heavy hydrocarbons as feedstocks for hydrogen production causes some problems which increase the catalyst deactivation by the carbon deposition. Coking can be inhibited by increasing the water dissociation on the catalyst surface. This results in catastrophic failure of whole system. Performance degradation of diesel autothermal reforming leads to increase of undesirable hydrocarbons at reformed gases and subsequently decrease the performance. In this study, perovskite-based catalysts were investigated as alternatives to substitute the noble metal catalyst for the ATR of diesel. The investigated perovskite structure was based on LaCrO3. and metals were added at the A-site to enhance oxygen ion mobility, transition metals were doped on the B-site to enhance the reformation. Substituted Lanthanum chromium perovskite were made by aqueous combustion synthesis, which can produce high surface area. And for the homogeneous fuel supply, we made ultrasonic injection system for reforming. We compared durability of evaporation system and ultrasonic system for fuel injection.

• Journal of ILASS-Korea
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• v.17 no.3
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• pp.121-127
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• 2012

The study is to investigate the mixing stability, fuel properties, and macroscopic spray characteristics of diesel-gasoline blended fuels in a common-rail injection system of a diesel engine. The test fuels were mixed diesel with gasoline fuel, which were based volume fraction of gasoline from 0 to 100% in 20% intervals. In order to analyze the blended effect of gasoline to diesel fuel, the properties of test fuels such as density, viscosity, and surface tension were measured. In addition, the spray behavior characteristics were studied by investigating the spray tip penetration and spray angle using a spray images through a spray visualization system. It was revealed that the density, kinematic viscosity and surface tension of diesel-gasoline blending fuels were decreased with the increase of gasoline fuel. The injection quantity of test fuels were almost similar level at short energizing duration condition. On the other hand, the increase of energizing duration shows the decrease of injection quantity compared to short energizing duration. The test blending fuels have similar growth in Spray tip penetration and Spray cone angle.

• Journal of Energy Engineering
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• v.4 no.2
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• pp.297-302
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• 1995

Ignition of a reactive solid in a shape of square corner by a hot surface is studied theoretically. Ignition time and the location of ignition point are determined as a function of dimensionless parameters, with the use of the homogeneous model of ignition. The effect of geometry on the ignition of solid fuel results in the local characteristics: the reaction is initiated in a hot point in depth of the substance. It is shown that ignition time is proportional to the dimensionless initial temperature, whereas for the ignition of the semiinfinite body this dependence was quadratic.

• Journal of Korean Society of Forest Science
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• v.101 no.2
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• pp.286-290
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• 2012

Globally, the forest fires are a significant contributor of carbon dioxide and other greenhouse gases in the atmosphere. In this study, fuel load consumed by forest fire and emission of green house gases were analysed in the surface layer. For this, remaining fuel was collected and weighed with the species (Japanese red pine, deciduous) and the forest fire types (surface fire, crown fire) in the 51 forest fires. 8,361 kg/ha fuel load was consumed in deciduous forest damaged by surface fire, and 8,055 kg/ha, 12,333 kg/ha in Japanese red pine burned by surface fire and crown fire. The combustion ratios were 78, 59, and 90%, respectively. 15,856 kg/ha the green house gases such as $CO_2$, $CH_4$, $CH_4$ in deciduous forest burned by surface fire was emitted and 14,834 kg/ha, 22,709 kg/ha in Japanese red pine burned by surface fire and crown fire.

• Journal of the Institute of Electronics Engineers of Korea SP
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• v.47 no.1
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• pp.91-96
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• 2010

In this paper, a deformation measurement technology of the nuclear fuel rod is proposed. The deformation measurement system include high definition CCD or CMOS image sensor, lens, semiconductor laser line beam marker, and optical & mechanical accessories. The basic idea of the deformation measurement is to illuminate the outer surface of the fuel rod with collimated laser line beam at an angle of 45 degrees or higher. The relative motion of the fuel rod in the horizontal direction causes the illuminated laser line beam to move vertically along the surface of the fuel rod. The resulting change of laser line beam position in the surface of the fuel rod is imaged as the parabolic beam in the high definition CCD or CMOS image sensor. From the parabolic beam pattern, the ellipse model is extracted. And the slope of the long and the short axis of the ellipse model is found. The crossing point between the saddle point of the parabolic beam and the long & short axis of the ellipse model is taken as the feature of the deformed fuel rod. The vertical offset between feature points before and after fuel rod deformation is calculated. From the experimental results, $50\;{\mu}m$ inspection resolution is acquired using the proposed method, which is three times enhanced than the conventional criterion ($150\;{\mu}m$) of the guide for the inspection of the nuclear fuel rod.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.13 no.4
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• pp.301-313
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• 2015

The rock cavern storage for spent fuel has been assessed to apply in Korea with reviewing the state of the art of the technologies for surface storage and rock cavern storage of spent fuel. The technical feasibility and economic aspects of the rock cavern storage of spent fuel were also analyzed. A considerable area of flat land isolated from the exterior are needed to meet the requirement for the site of the surface storage facilities. It may, however, not be easy to secure such areas in the mountainous region of Korea. Instead, the spent fuel storage facilities constructed in the rock cavern moderate their demands for the suitable site. As a result, the rock cavern storage is a promising alternative for the storage of spent fuel in the aspect of natural and social environments. The rock cavern storage of spent fuel has several advantages compared with the surface storage, and there is no significant difference on the viewpoint of economy between the two alternatives. In addition, no great technical difficulties are present to apply the rock cavern storage technologies to the storage of domestic spent fuel.