• Title/Summary/Keyword: Surface free energy

Search Result 638, Processing Time 0.029 seconds

Free Surface Vortex in a Rotating Barrel with Rods of Different Heights

  • Zhang, Xiaoyue;Zhang, Min;Chen, Wanyu;Yang, Fan;Guo, Xueyan
    • International Journal of Fluid Machinery and Systems
    • /
    • v.9 no.4
    • /
    • pp.325-331
    • /
    • 2016
  • A bathtub vortex above the outlet of a rotating barrel is simulated. By analyzing the Ekman layer theory, it can be found that the main flow circulation is inversely proportional to the thickness of Ekman layer. The thicker the Ekman boundary layer, the weaker the rotational strength and the shorter of the length of gas core is. According to this law, models of barriers with rods of different heights are established. The reduction of air-core length in this air entrainment vortex and weakening the strength of rotation field were achieved.

Influence of explosives distribution on coal fragmentation in top-coal caving mining

  • Liu, Fei;Silva, Jhon;Yang, Shengli;Lv, Huayong;Zhang, Jinwang
    • Geomechanics and Engineering
    • /
    • v.18 no.2
    • /
    • pp.111-119
    • /
    • 2019
  • Due to certain geological characteristics (high thickness, rocky properties), some underground coal mines require the use of explosives. This paper explores the effects of fragmentation of different decks detonated simultaneously in a single borehole with the use of numerical analysis. ANSYS/LS-DYNA code was used for the implementation of the models. The models include an erosion criterion to simulate the cracks generated by the explosion. As expected, the near-borehole area was damaged by compression stresses, while far zones and the free surface of the boundary were subjected to tensile damage. With the increase of the number of decks in the borehole, different changes in the fracture pattern were observed, and the superposition effects of the stress wave became evident, affecting the fragmentation results. The superposition effect is more evident in close distances to the borehole, and its effect attenuates when the distance to the borehole increase.

Reflection of plane waves from the boundary of a thermo-magneto-electroelastic solid half space

  • Singh, Baljeet;Singh, Aarti
    • Coupled systems mechanics
    • /
    • v.10 no.2
    • /
    • pp.143-159
    • /
    • 2021
  • The theory of generalized thermo-magneto-electroelasticity is employed to obtain the plane wave solutions in an unbounded, homogeneous and transversely isotropic medium. Reflection phenomena of plane waves is considered at a stress free and thermally insulated surface. For incidence of a plane wave, the expressions of reflection coefficients and energy ratios for reflected waves are derived. To explore the characteristics of reflection coefficients and energy ratios, a quantitative example is set up. The half-space of the thermo-magneto-electroelastic medium is assumed to be made out of lithium niobate. The dependence of reflection coefficients and energy ratios on the angle of incidence is illustrated graphically for different values of electric, magnetic and thermal parameters.

A Study on Thermal and Mechanical Interfacial Properties of Difunctional Epoxy/PMMA Blends (이관능성 에폭시/폴리메틸메타크릴레이트 블랜드의 열적 및 기계적 계면 특성)

  • 박수진;김기석;이재락;민병각;김영근
    • Composites Research
    • /
    • v.17 no.1
    • /
    • pp.10-17
    • /
    • 2004
  • In this work, the blend system prepared from epoky(DGEBA)/polymethylmethacrylate(PMMA) was investigated in thermal and mechanical interfacial property measurements. The thermal properties were carried out by DSC, DMA, and TGA measurements. Also, the surface free energy and fracture toughness were determined by contact angle and critical stress intensity factor($K_{IC}$), respectively. And the fracture surface was observed by SEM after $K_{IC}$ tests. As experimental results, the curing temperature and glass transition temperature were slightly increased in addition of PMMA. Surface free energy of the blends showed an improved value at low contents of PMMA which could be attributed to the both increasings of London dispersive and polar components. From measurement of $K_{IC}$ of the blends, the highest value was found at 5 phr. This was due to the increasing of compatibility or physical interaction in macromolecular chains between DGEBA and PMMA of the blends.

Effects of the Graphene Oxide on Glucose Oxidase Immobilization Capabilities and Sensitivities of Carbon Nanotube-based Glucose Biosensor Electrodes (그래핀 옥사이드가 탄소나노튜브기반 바이오센서 전극의 포도당 산화효소 담지능및 민감도에 미치는 영향)

  • Park, Mi-Seon;Kim, Do Young;Jung, Min-Jung;Lee, Young-Seak
    • Applied Chemistry for Engineering
    • /
    • v.26 no.1
    • /
    • pp.47-52
    • /
    • 2015
  • To improve both the GOD immobilization capability and sensitivity of MWCNTs-based biosensor electrode, the electrode was prepared by adding different quantities of GO. The addition of GO increased hydrophilicity and the surface free energy of electrodes for glucose sensing as well as the dispersion of MWCNTs. In addition, the GOD immobilization capability was enhanced and the sensitivity was improved up to $121{\mu}A\;mM^{-1}$ even though having a high $K_m$ value (0.105) when adding 0.05 g GO to 0.05 g MWCNTs. These experimental results were attributed to the fact that the improvement in dispersion stability for MWCNTs, hydrophilicity, and surface free energy of electrode surface due to the addition of GO affected GOD immobilization capability.

A Study on the Turbulent Flow Characteristics in the Wake of Transom Sterns using PIV Method (동일입자추적기법을 이용한 트랜섬선미 후류 난류유동특성에 관한 연구)

  • Lee, Gyoung-Woo;Gim, Ok-Sok
    • Journal of the Korean Society of Marine Environment & Safety
    • /
    • v.18 no.4
    • /
    • pp.352-359
    • /
    • 2012
  • An experiment was carried out to figure out the turbulence flow characteristics in the wake of the transom stern's 2-dimensional section by 2-frame grey level cross correlation PIV method at Re= $3.5{\times}10^3$, Re= $7.0{\times}10^3$. The angles of transom stern are $45^{\circ}$(Model "A"), $90^{\circ}$(Model "B") and $135^{\circ}$(Model "C") respectively. The depth of wetted surface is 40mm from free surface. Strong turbulence intensity appears at the interaction between the flow separation of the bottom of a model and the free surface. This study provides statistic flow information such as turbulence intensity, Reynolds stress and turbulence kinetic energy. Model C type (Raked transom) has low Reynolds stress and turbulence kinetic energy.

Effects of Electrochemical Oxidation of Carbon Fibers on Mechanical Interfacial Properties of Carbon Fibers-reinforced Polarized-Polypropylene Matrix Composites (전기화학적 산화처리가 탄소섬유/극성화된 폴리프로필렌 복합재의 기계적 계면 특성에 미치는 영향)

  • Kim, Hyun-Il;Choi, Woong-Ki;Oh, Sang-Yub;An, Kay-Hyeok;Kim, Byung-Joo
    • Applied Chemistry for Engineering
    • /
    • v.24 no.5
    • /
    • pp.476-482
    • /
    • 2013
  • In this work, the effects of electrochemical oxidation of carbon fiber surfaces on mechanical interfacial properties of carbon fibers-reinforced polarized-polypropylene matrix composites were studied with various current densities during the treatments. Surface properties of the fibers before and after treatments were observed by SEM, AFM, XPS, and contact angle measurements. Mechanical interfacial properties of the composites were measured in terms of critical stress intensity factor ($K_{IC}$). From the results it was found that $O_{1s}$ peaks of the fiber surfaces were strengthened after electrochemical oxidation which led to the enhancement of surface free energy of the fiber, resulting in good mechanical performance of the composites. It can be concluded that electrochemical oxidation of the carbon fiber surfaces can control the interfacial adhesion between the carbon fibers and polarized-polypropylene in this composites system.

Synthesis of Fluorine-Containing Water-Soluble Polyurethane with Environmental Affinity (환경친화적 수용성 불소계 폴리우레탄의 합성)

  • Lim, Hyejin;Park, In Jun;Lee, Soo-Bok;Lee, Yongtaek
    • Clean Technology
    • /
    • v.5 no.2
    • /
    • pp.37-44
    • /
    • 1999
  • The influence of the reactant composition on the surface free energy and on the dispersity in water was investigated by using the fluorine-containing water-soluble polyurethane synthesized with the fluorine-containing diol and hydrophilic diol. The diol donating ionic characteristics was more effective than polyol, and stable emulsion with the diameter of 610~310 nm was obtained in the range of 0.3~0.7 molar ratio of the diol to polyol. According to the increment of fluorine-containing compound up to 10 wt %, the surface free energy of polyurethane was dramatically decreased from 22.3 to 12.6 dyn/cm, and the diameter of water dispersed polyurethane increased from 380 to 860 nm due to the strong interaction between polymer molecules because fluorine segments are arranged on the surface of molecules. The macromonomer with perfluoroalkyl group was more effective in complement of the weak point of water-soluble polyurethane, which is a decrease of hydrophobicity, because of strong hydrophobicity.

  • PDF

Bacterial adhesion and colonization differences between zirconia and titanium implant abutments: an in vivo human study

  • De Oliveira, Greison Rabelo;Pozzer, Leandro;Cavalieri-Pereira, Lucas;De Moraes, Paulo Hemerson;Olate, Sergio;De Albergaria Barbosa, Jose Ricardo
    • Journal of Periodontal and Implant Science
    • /
    • v.42 no.6
    • /
    • pp.217-223
    • /
    • 2012
  • Purpose: Several parameters have been described for determining the success or failure of dental implants. The surface properties of transgingival implant components have had a great impact on the long-term success of dental implants. The purpose of this study was to compare the tendency of two periodontal pathogens to adhere to and colonize zirconia abutments and titanium alloys both in hard surfaces and soft tissues. Methods: Twelve patients participated in this study. Three months after implant placement, the abutments were connected. Five weeks following the abutment connections, the abutments were removed, probing depth measurements were recorded, and gingival biopsies were performed. The abutments and gingival biopsies taken from the buccal gingiva were analyzed using real-time polymerase chain reaction to compare the DNA copy numbers of Aggregatibacter actinomycetemcomitans, Porphyromonas gingivalis, and total bacteria. The surface free energy of the abutments was calculated using the sessile water drop method before replacement. Data analyses used the Mann Whitney U-test, and P-values below 0.05 find statistical significance. Results: The present study showed no statistically significant differences between the DNA copy numbers of A. actinomycetemcomitans, P. gingivalis, and total bacteria for both the titanium and zirconia abutments and the biopsies taken from their buccal gingiva. The differences between the free surface energy of the abutments had no influence on the microbiological findings. Conclusions: Zirconia surfaces have comparable properties to titanium alloy surfaces and may be suitable and safe materials for the long-term success of dental implants.

Interfacial Characteristics of Epoxy Composites Filled with γ-APS Treated Natural Zeolite (γ-APS로 표면처리된 천연 제올라이트/에폭시 복합재료의 계면특성)

  • Lee, Jae-Young;Lee, Sang-Keun;Kim, Sang-Wook
    • Journal of Adhesion and Interface
    • /
    • v.2 no.3
    • /
    • pp.1-8
    • /
    • 2001
  • Epoxy composites filled with natural zeolite was prepared to investigate the effects of silane coupling agent, ${\gamma}$-APS (${\gamma}$-aminopropyltriethoxysilane)on the surface free energy, tensile properties and interfacial morphology. The value of Lifshitz-van der Waals component, ${\gamma}{\frac{LW}{SV}}$ for polar was $19.22mJ/m^2$ and increased, while that of Lewis acid-base component, ${\gamma}{\frac{AB}{SV}}$ for polar was $15.27mJ/m^2$ and decreased with the increasing content of ${\gamma}$-APS treatment. It is due that the surface of the zeolite is more coated by hydrophobic of alkyl group than hydrophilic amine or hydroxyl group. The tensile strength and Young's modulus of epoxy system were improved by the treatment with ${\gamma}$-APS due to the strong interface bonding, which was confirmed by SEM.

  • PDF