• Title/Summary/Keyword: Surface free energy

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Numerical Prediction of Ship Hydrodynamic Performances using Explicit Algebraic Reynolds Stress Turbulence Model (선박의 저항성능 추정을 위한 EARSM 난류 모형의 활용)

  • Kim, Yoo-Chul;Kim, Kwang-Soo;Kim, Jin
    • Journal of the Society of Naval Architects of Korea
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    • v.51 no.1
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    • pp.67-77
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    • 2014
  • In this study, Explicit Algebraic Reynolds Stress Model (EARSM) which is based on the existing ${\kappa}-{\omega}$ model has been applied to the flow field analysis around ship hulls. Existing transport equations for the turbulent kinetic energy and the dissipation rate are used in almost the same form and anisotropy terms of Reynolds stresses are newly considered. The well-known KVLCC2 and KCS hull forms are selected as validation cases, which were also used in 2010 Workshop on CFD in Ship Hydrodynamics. In case of KVLCC2 double model, comparison of mean velocity distribution, turbulent kinetic energy, and Reynolds stresses near the propeller plane has been carried out and wave elevation and wave profiles have been additionally studied for KCS and KVLCC2 with free surface models. Some improved results for mean velocity distribution at the propeller plane have been obtained while there is little change in free surface wave profiles.

The Fabrication of PVA Polymer Coated on the Surface of B4C Nanocomposite by High Energy Ball Mill (고에너지볼밀을 이용한 PVA 고분자가 표면 코팅된 B4C 나노복합재 제조)

  • Uhm, Young-Rang;Kim, Jae-Woo;Jung, Jin-Woo;Rhee, Chang-Kyu
    • Journal of Powder Materials
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    • v.16 no.2
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    • pp.110-114
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    • 2009
  • Mechanical coating process was applied to form 89 %-hydrolyzed poly vinyl alcohol (PVA) onto boron carbide ($B_4C$) nanopowder using one step high energy ball mill method. The polymer layer coated on the surface of B4C was changed to glass-like phase. The average particle size of core/shell structured $B_4C$/PVA was about 50 nm. The core/shell structured $B_4C$/PVA was formed by dry milling. However, the hydrolyzed PVA of $98{\sim}99%$ with high glass transition temperature ($T_g$) was rarely coated on the powder. The $T_g$ of polymer materials was one of keys for guest polymer coating on to the host powder by solvent free milling.

Effects of Silane-treated Silica on the Cure Temperature and Mechanical Properties of Elastomeric Epoxy (실란 커플링제로 처리된 실리카가 탄성에폭시의 경화온도 및 기계적 물성에 미치는 영향)

  • Choi, Sun-Mi;Lee, Eun-Kyoung;Choi, Seo-Young
    • Elastomers and Composites
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    • v.43 no.3
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    • pp.147-156
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    • 2008
  • In this work, epoxy/carboxyl-terminated butadiene acrylonitirile (EP/CTBN) composites were prepared by employing a reinforcing filler, silica treated with silane coupling agent in different ratio by dry and wet method. Their curing characteristics, surface free energy, interface morphologies and mechanical properties such as tensile strength and impact resistance were carefully investigated. Differential scanning calorimetry(DSC) results showed that curing temperature was lowered with the increase of silane coupling agent because of the increase of relative curing agent cotent by filling the pores of silica. Wet method was proved to be more effective for lowering curing temperature of EP/CTBN composite. In general, surface free energy and impact resistance were increased with the increase of silane coupling agent in this work. Tensile strength, however, was observed to be decreased at 4 wt% of silane coupling agent. It was found that the dry method was proved to be preferable for pretreatment of silica with coupling agent.

Study on Early Adhesive Characteristic of Chip Seals Using a Surface Energy Approach (표면 에너지 원리를 이용한 칩실 포장의 초기 점착력 특성 연구)

  • Im, Jeong Hyuk
    • International Journal of Highway Engineering
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    • v.17 no.6
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    • pp.47-54
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    • 2015
  • PURPOSES : The objective of this study is to evaluate the early adhesive characteristic of asphalt emulsions, including polymer-modified emulsions, for chip seals using the surface energy concept, the bitumen bond strength (BBS) test, and the Vialit test. METHODS : Two general methods, the BBS test and Vialit test, were applied to investigate the bond strength and the aggregate loss, respectively. A new theory, the surface free energy (SFE) theory, was used to evaluate the adhesive characteristic between the emulsion and the aggregate. Based on the theory, the contact angles were measured, and then the surface energy components were calculated. Using those components, the work of adhesion (Wa) was calculated for each emulsion. To ensure reliable results, all the tests were performed under the same conditions, i.e., at $25^{\circ}C$ for 240 minutes of curing time. For the materials, three emulsions (CRS-2, CRS-2L, and CRS-2P) and one aggregate type (granite) were employed. RESULTS AND CONCLUSIONS : Under the same conditions, the modified emulsions showed better adhesive characteristics and curing behaviors than the unmodified emulsions. In addition, there was no significant difference between the various modified emulsions. One of the important findings is that the analysis by Wa presents more sensitive results than other methods. The results of the Wa showed that the CRS-2P emulsion has the best adhesive characteristics. Consequently, the use of modified emulsions for chip seals could prevent aggregate loss and allow open traffic earlier.

Nanopatterned Surface Effect on the Epitaxial growth of InGaN/GaN Multi-quantum Well Light Emitting Diode Structure

  • Kim, Keun-Joo
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.2
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    • pp.40-43
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    • 2009
  • The authors fabricated a nanopatterned surface on a GaN thin film deposited on a sapphire substrate and used that as an epitaxial wafer on which to grow an InGaN/GaN multi-quantum well structure with metal-organic chemical vapor deposition. The deposited GaN epitaxial surface has a two-dimensional photonic crystal structure with a hexagonal lattice of 230 nm. The grown structure on the nano-surface shows a Raman shift of the transverse optical phonon mode to $569.5\;cm^{-1}$, which implies a compressive stress of 0.5 GPa. However, the regrown thin film without the nano-surface shows a free standing mode of $567.6\;cm^{-1}$, implying no stress. The nanohole surface better preserves the strain energy for pseudo-morphic crystal growth than does a flat plane.

Design and heat transfer optimization of a 1 kW free-piston stirling engine for space reactor power system

  • Dai, Zhiwen;Wang, Chenglong;Zhang, Dalin;Tian, Wenxi;Qiu, Suizheng;Su, G.H.
    • Nuclear Engineering and Technology
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    • v.53 no.7
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    • pp.2184-2194
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    • 2021
  • The Free-Piston Stirling engine (FPSE) is of interest for many research in aerospace due to its advantages of long operating life, higher efficiency, and zero maintenance. In this study, a 1-kW FPSE was proposed by analyzing the requirements of Space Reactor Power Systems (SRPS), of which performance was evaluated by developing a code through the Simple Analysis Method. The results of SAM showed that the critical parameters of FPSE could satisfy the designed requirements. The heater of the FPSE was designed with the copper rectangular fins to enhance heat transfer, and the parametric study of the heater was performed with Computational Fluid Dynamics (CFD) software STAR-CCM+. The Performance Evaluation Criteria (PEC) was used to evaluate the heat transfer enhancement of the fins in the heater. The numerical results of the CFD program showed that pressure drop and Nusselt number ratio had a linear growth with the height of fins, and PEC number decreased as the height of fins increased, and the optimum height of the fin was set as 4 mm according to the minimum heat exchange surface area. This paper can provide theoretical supports for the design and numerical analysis of an FPSE for SRPSs.

Core-Shell Polymerization with Hydrophilic Polymer Cores

  • Park, Jong-Myung
    • Macromolecular Research
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    • v.9 no.1
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    • pp.51-65
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    • 2001
  • Two-stage emulsion polymerizations of hydrophobic monomers on hydrophilic seed polymer particles were carried out to make core-shell composite particles. It was found that the loci of polymerization in the second stage were the surface layer of the hydrophilic seed latex particles, and that it has resulted in the formation of either eccentric core-shell particles with the core exposed to the aqueous phase or aggregated nonspherical composite particles with the shell attached on the seed surface as many small separated particles. The driving force of these phenomena is related to the gain in free energy of the system in going from the hydrophobic polymer-water interface to hydrophilic polymer-water interface. Thermodynamic analysis of the present polymerization system, which was based on spreading coefficients, supported the likely occurrence of such nonspherical particles due to the combined effects of interfacial free energies and phase separation between the two polymer phases. A hypothetical pathway was proposed to prepare hydrophilic core-hydrophobic shell composite latex particles, which is based on the concept of opposing driving and resistance forces for the phase migration. It was found that the viscosity of the monomer-swollen polymer phase played important role in the formation of particle morphology.

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Flow, Heat and Mass Transfer Analysis for Vertical Grooved Tube Evaporator (흠진 수직 증발관에서 유동 및 열/물질 전달 해석)

  • Park Il-Seouk;Choi Do Hyung
    • 한국전산유체공학회:학술대회논문집
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    • 1998.11a
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    • pp.108-113
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    • 1998
  • A numerical investigation for the flow, heat and mass transfer characteristics of the grooved evaporating tube with the films flowing down on both the inside and outside tube walls has been carried out. The condensation occurs along the outside wall while the evaporation takes place at the free surface of the inside film. The 3-D transport equations for momentum and energy are solved by using the FVM(Finite Volume Method). The free surface shape is tracked by the moving grid technique satisfying the SCL(Space Conservation Rule). Due to the secondary motion of the fluid, the film thins at the crest, while thickens at the valley. The velocity and temperature fields as well as the amounts of the condensed and evaporated mass have been successfully predicted for various operating conditions and groove shapes.

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NUMERICAL ANALYSIS OF FLOW AND COOLING CHARACTERISTICS OF SLIT JETS IMPINGEMENT (슬릿젯의 유동 및 냉각 성능에 대한 수치적 연구)

  • Son, S.;Son, G.;Lee, P.;See, S.
    • 한국전산유체공학회:학술대회논문집
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    • 2010.05a
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    • pp.448-450
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    • 2010
  • Free surface liquid jet impingement, which is applicable to cooling of hot plates in a steel-making process, is investigated numerically by solving the conservation equations of mass, momentum and energy in the liquid and gas phases. The free-surface of liquid-gas interface is tracked by an improved level-set method incorporating a sharp-interface technique for accurate imposition of stress and heat flux conditions on the liquid-gas interface. The level-set approach is combined with a non-equilibrium $k-{\omega}$ turbulence model. The computations are made for slit nozzle jets to investigate their flow and cooling characteristics. Also, the effects of jetting angle, velocity and moving velocity of plate on the interfacial motion and the associated flow and temperature fields are quantified.

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III-V 삼상 화합물 반도체의 분자선 결정성장법에서의 열역학적 고찰

  • O, Won-Ung;O, Jae-Eng;Baek, Su-Hyun
    • ETRI Journal
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    • v.13 no.4
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    • pp.42-51
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    • 1991
  • MBE 성장시 기판 표면에서의 성장과정을 운동론적 지배과정과 열역학적 지배과정으로 나누어 성장모델을 제시하였으며, 화학적 평형상태에서의 열역학이 III-V compound의 성장속도와 composition 에 미치는 영향을 기존의 보고된 결과 데이터와 비교 분석하였다. 특히 miscibility gap 내에 존재하는 III-V ternary compound의 경우 박막의 성질 및 소자의 특성에 영향을 미치는 alloy clustering은 저온 성장시 surface kinetics에 의해, 고온성장시에는 열역학적 spinodal decomposition에 의해 결정됨을 알수 있었다. 열역학적 모델에서는 기판과 layer사이의 lattice mismatch와 재료의 elastic coefficient의 함수인 additive strain Gibbs free energy, 그리고 ternary solid solution의 regular behavior를 가정하여 ternary alloy의 mixing에 기인한 excess Gibbs free energy를 고려하였다.

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