• Title/Summary/Keyword: Surface equilibrium temperature

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Nature of Cold Injury and Resistance in Wheat and Barley (맥류의 한해와 내동성에 관하여)

  • 남윤일;연규복;구본철
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.34 no.s02
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    • pp.96-114
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    • 1989
  • There are several meterorolgical stresses in the winter cereal crops. Among these stresses, cold injury is one of the most important stresses for wheat and barley production in Korea. The reduction in grain yield of the wheat and barley due to cold injury has occurred almost every year in Korea. The objective of the study was to get the basic information in relation to the cold injury and to detect the method minimizing the damage of cold injury. When the air temperature was the ranges of -13$^{\circ}C$ to -15$^{\circ}C$, the soil temperature at the crown part of the plant was very stable, whereas in the ranges of -2$^{\circ}C$ to -3$^{\circ}C$ the soil surface temperature was more unstable and cold than air and subterranean temperatures. The different parts of the plant in wheat and barley possess the different levels of cold hardiness. In comparison to the cold hardiness of plant parts, the leaf and crown are the less sensitive to cold injury than root and vascular transitional zone. The type and extent of stress is determined by the redistribution pattern of water during freezing. These types from freezing processes were three types: a) Equilibrium freezing pattern b) Non -equilibrium freezing pattern, c) Non-equilibrium freezing pattern typical of tender tissues. Cold hardiness in wheat plants were more harder than barley plants at vegitative stage, but inverted at the reproductive stage. Injuries by low temperature during the seasons of barley cultivation in Korea were occured mainly in four stage; in the first and third stage, frost injury occurs, the second stage, freezing injury, and the fourth stage, chilling injury.

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A Study on Oxy-Fuel Combustion System with Multi-Jet Burner-Numerical Simulation with PDF Combustion Model (다공 동축 버너를 이용한 순산소 연소 시스템에 관한 연구-PDF 연소 모델을 이용한 수치해석)

  • Kim, Hyeon-Jun;Choi, Won-Young;Bae, Soo-Ho;Hong, Jung-Goo;Shin, Hyun-Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.7
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    • pp.504-512
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    • 2008
  • The characteristics of nonpremixed oxy-fuel flame in a multi-jet burner were experimentally and numerically investigated. The overall flow rate of fuel and oxygen was fixed, and the oxygen feeding ratio (OFR) was varied by 0.25, 0.5, and 0.75. The results of numerical simulation were compared with the measured results which are temperature profile and direct flame observation. The probability density function (PDF) model was applied accounting to the description between turbulence and chemistry, and standard ${\kappa}-{\varepsilon}$ model was used for turbulent flow field. Equilibrium assumption is very reasonable due to fast chemistry of the oxy-fuel combustion. Thus, the equilibrium calculation based on Gibbs free energy minimization was guaranteed to generate the solution of the oxy-fuel combustion. The result was obtained by numerical simulation. The predicted radial temperature profiles were in good agreement with the measured results. The flame length was shorten and was intensified with the decrease of OFR because the mixture of fuel and oxidizer are fast mixed and burnt. The maximum temperature became lower as the OFR increased, as a consequence of large flame surface area.

Preparation of Glycidylmethacrylate-Divinylbenzene Copolymers Containing Phosphoric Acid Groups and Their Adsorption Characteristics of Uranium(II) - Adsorption Equilibrium and Kinetics of Uranium on RGP Resins - (인산기를 함유한 Glycidylmethacrylate-Divinylbenzene 공중합체의 제조와 우라늄 흡착특성(제2보) - RGP수지에 대한 우라늄의 흡착평형과 흡착속도 -)

  • Huh, Kwang Sun;Park, Sang Wook
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.689-697
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    • 1998
  • In this work, we studied the equilibrium, rate and rate determining step of uranium adsorption on RGP resins of MR type prepared by varying the degree of crosslinking and the amount of diluent. The equilibrium of uranium adsorption on RGP resins were well explained by Frendrich isotherm as well as Langmuir isotherm model. The amount of adsorption and adsorption rate increase with the adsorption temperature. The heat of the adsorption was 11 kcal/mol. The adsorption rates of uranium on RGP resins were decreased in the order of RGP-10(50)>RGP-1(50)>RGP-2(50)>RGP-5(50)>RGP-0(50) and RGP-2(75)>RGP-2(100)>RGP-2(50)>RGP-2(30)>RGP-2(0). The diffusion resistance of uranium into RGP resin increased as follows; molecular diffusion < pore diffusion < surface diffusion. On the other hand, the surface diffusion was more dominative than the pore diffusion in intraparticle region. Thus, this result indicates that the adsorption mechanism of uranium on RGP resins is intraparticle diffusion controlled.

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Numerical Study of Thermo-hydraulic Boundary Condition for Surface Energy Balance (지표면 열평형의 열-수리적 경계조건에 대한 수치해석)

  • Shin, Hosung;Jeoung, Jae-Hyeung
    • Journal of the Korean Geotechnical Society
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    • v.37 no.12
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    • pp.25-31
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    • 2021
  • Boundary conditions for thermal-hydraulic problems of soils play an essential role in the numerical accuracy. This study presents a boundary condition considering the thermo-hydraulic interaction between the ground and the atmosphere. Ground surface energy balance consists of solar radiation, ground radiation, wind convection, latent heat from water evaporation, and heat conduction to the ground. Equations for each heat flux are presented, and numerical analyses are performed in conjunction with the FEM program for the thermal-hydraulic phenomenon of unsaturated soils. Numerical results using the weather data at the Ulsan Meteorological Observatory are similar to the measured surface temperature. Latent heat caused by water evaporation during the daytime lowers the surface temperature of the bare soil, and a thermal equilibrium is reached at nighttime when the effect of the ground condition is significantly reduced. The temperature change of the surface ground is diminished at the deeper ground due to its thermal diffusion. Numerical analysis where the surface ground temperature is the primary concern requires considering the thermo-hydraulic interaction between the ground and the atmosphere.

Adsorption Characteristics of Endo Ⅱ and Exo Ⅱ Purified from Trichoderma viride on Microcrystalline Celluloses with Different Surface Area

  • 김동원;정영규;장영훈;이재국
    • Bulletin of the Korean Chemical Society
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    • v.16 no.6
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    • pp.498-503
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    • 1995
  • The adsorption behaviors of two major components purified, endo Ⅱ and exo Ⅱ, from Trichoderma viride were investigated using microcrystalline cellulose with different specific surface area as substrates. Adsorption was found to apparently obey the Langmuir isotherm and the thermodynamic parameters, ΔH, ΔS, and ΔG, were calculated from adsorption equilibrium constant,K. The adsorption process was found to be endothermic and an adsorption entropy-controlled reaction. The amount of adsorption of cellulase components increased with specific surface area and decreased with temperature and varied with a change in composition of the cellulase components. The maximum synergistic degradation occurred at the specific weight ratio of the cellulase components at which the maximum affinity of cellulase components obtains. The adsorption entropy and enthalpy for respective enzyme system increased with specific surface area increase. The adsorption entropy was shown to have a larger value with enzyme mixture.

NUMERICAL ANALYSIS OF NON-EQUILIBRIUM HYDRATE PELLET DECOMPOSITION (하이드레이트 펠릿의 비평형 분해과정 수치해석)

  • Kang, Jung-Ho;Nam, Jin-Hyun;Kim, Charn-Jung;Song, Myung-Ho
    • Journal of computational fluids engineering
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    • v.13 no.4
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    • pp.50-57
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    • 2008
  • The prediction of hydrate pellet decomposition characteristics is required to design the regasification process of GTS (gas to solid) technology, which is considered as an economic alternative for LNG technology to transport natural gas produced from small and stranded gas wells. Mathematical model based on the conservation principles, the phase equilibrium relation, equation of gas state and phase change kinetics was set up and numerical solution procedure employing volume averaged fixed grid formulation and extended enthalpy method are implemented. Initially, porous methane hydrate pellet is at uniform temperature and pressure within hydrate stable region. The pressure starts to decrease with a fixed rate down to the final pressure and is kept constant afterwards while the bounding surface of pellet is heated by convection. The predicted convective heat and mass transfer accompanied by the decomposed gas flow through hydrate/ice solid matrix is reported focused on the comparison of spherical and cylindrical pellets having the same effective radius.

NUMERICAL ANALYSIS OF NON-EQUILIBRIUM HYDRATE PELLET DECOMPOSITION (하이드레이트 펠릿의 비평형 분해과정 수치해석)

  • Kang, Jung-Ho;Nam, Jin-Hyun;Kim, Charn-Jung;Song, Myung-Ho
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03a
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    • pp.268-275
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    • 2008
  • The prediction of hydrate pellet decomposition characteristics is required to design the regasification process of GTS (gas to solid) technology, which is considered as an economic alternative for LNG technology to transport natural gas produced from small and stranded gas wells. Mathematical model based on the conservation principles, the phase equilibrium relation, equation of gas state and phase change kinetics was set up and numerical solution procedure employing volume averaged fixed grid formulation and extended enthalpy method are implemented. Initially, porous methane hydrate pellet is at uniform temperature and pressure within hydrate stable region. The pressure starts to decrease with a fixed rate down to the final pressure and is kept constant afterwards while the bounding surface of pellet is heated by convection. The predicted convective heat and mass transfer accompanied by the decomposed gas flow through hydrate/ice solid matrix is reported focused on the comparison of spherical and cylindrical pellets having the same effective radius.

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NUMERICAL ANALYSIS OF NON-EQUILIBRIUM HYDRATE PELLET DECOMPOSITION (하이드레이트 펠릿의 비평형 분해과정 수치해석)

  • Kang, Jung-Ho;Nam, Jin-Hyun;Kim, Charn-Jung;Song, Myung-Ho
    • 한국전산유체공학회:학술대회논문집
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    • 2008.10a
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    • pp.268-275
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    • 2008
  • The prediction of hydrate pellet decomposition characteristics is required to design the regasification process of GTS (gas to solid) technology, which is considered as an economic alternative for LNG technology to transport natural gas produced from small and stranded gas wells. Mathematical model based on the conservation principles, the phase equilibrium relation, equation of gas state and phase change kinetics was set up and numerical solution procedure employing volume averaged fixed grid formulation and extended enthalpy method are implemented. Initially, porous methane hydrate pellet is at uniform temperature and pressure within hydrate stable region. The pressure starts to decrease with a fixed rate down to the final pressure and is kept constant afterwards while the bounding surface of pellet is heated by convection. The predicted convective heat and mass transfer accompanied by the decomposed gas flow through hydrate/ice solid matrix is reported focused on the comparison of spherical and cylindrical pellets having the same effective radius.

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Adsorption properties of activated carbon prepared from pre-carbonized petroleum coke in the removal of organic pollutants from aqueous solution

  • Ahmed, S.A. Sayed;El-Enin, Reham M.M. Abo;El-Nabarawy, Th.
    • Carbon letters
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    • v.12 no.3
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    • pp.152-161
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    • 2011
  • Activated carbon was prepared from pre-carbonized petroleum coke. Textural properties were determined from studies of the adsorption of nitrogen at 77 K and the surface chemistry was obtained using the Fourier-transform infrared spectrometer technique and the Boehm titration process. The adsorption of three aromatic compounds, namely phenol (P), p-nitrophenol (PNP) and benzoic acid (BA) onto APC in aqueous solution was studied in a batch system with respect to contact time, pH, initial concentration of solutes and temperature. Active carbon APC obtained was found to possess a high surface area and a predominantly microporous structure; it also had an acidic surface character. The experimental data fitted the pseudo-second-order kinetic model well; also, the intraparticle diffusion was the only controlling process in determining the adsorption of the three pollutants investigated. The adsorption data fit well with the Langmuir and Freundlich models. The uptake of the three pollutants was found to be strongly dependent on the pH value and the temperature of the solution. Most of the experiments were conducted at pH 7; the $pH_{(PZC)}$ of the active carbon under study was 5.0; the surface of the active carbon was negatively charged. The thermodynamic parameters evaluated for APC revealed that the adsorption of P was spontaneous and exothermic in nature, while PNP and BA showed no-spontaneity of the adsorption process and that process was endothermic in nature.

A Study on the Optimum Conditions in Stainless Steel Arc Spraying (스테인레스강 아이크 용사에 있어서의 최적 용사조건에 관한 연구)

  • 김영식;최영국
    • Journal of Welding and Joining
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    • v.4 no.3
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    • pp.50-57
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    • 1986
  • In this study, the experiments were earried out for the purpose of the clarifying the optimum metal arc spraying conditions, such as spraying distance, wire feed speed, arc current, etc, by using the stainless steel wire ER 308L. Main results obtained are as follows: 1. Optimum spraying distance is closely related to the equilibrium temperature of base material in back surface. 2. The size fused metal particles is increased according to the temperature of fused metal. 3. The maximum adhesion strength of coatings is obtained under the optimum spraying conditions of which the temperature of fundamental is maximum.

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