• 제목/요약/키워드: Surface concentration

검색결과 6,117건 처리시간 0.035초

Studying the influence of the concentration of alkaline solution to the formation of TiO2 nanotube prepared by microwave-assisted hydrothermal method

  • Hao, Nguyen Huy;Cho, Sung Hun;Lee, Soo W.
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2014년도 추계학술대회 논문집
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    • pp.260-261
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    • 2014
  • $TiO_2$ nanotubes (TNT) synthesized by microwave-assisted hydrothermal method by using $TiO_2-P25$ as a precursor at hydrothermal temperature $150^{\circ}C$ in 4 hours. The concentration of alkaline solution is between 4M and 10M. Samples were characterized by X-ray diffraction (XRD), Raman spectroscopy (RS), Transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET) and UV-vis DRS spectroscopy. The results demonstrated the effects of the alkali concentration to the formation of nanotubes. The photocatalytic activity was investigated by degradation of Methylene Blue (MB).

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농촌유역에서의 SS, COD 및 T-P간의 상관관계 분석(지역환경 \circled1) (Analysis of relationship between SS, COD, and T-P in rural area)

  • 함종화;윤춘경
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 2000년도 학술발표회 발표논문집
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    • pp.525-530
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    • 2000
  • The loss of soil and nutrients from land surfaces to surface water supplies continues to be an important source of nonpoint source pollution. This study was initiate to develop an empirical relationship among the contaminants. SS, COD, T-N, and T-P were collected from agricultural surface water quality studies carried out in Hwasung-Gun, Kyonggi-Do. Correlation analysis, regression analysis, and reliability analysis were conducted. The regression equations were developed between SS and COD, SS and T-P, COD and T-P, and the resulting r$\^$2/ value was over 0.78. The regression equation enables a reasonable prediction of phosphorus concentration and COD concentration for known suspended solid concentration.

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부숙처리된 축산분뇨슬러리 살포지역의 강우에 의한 영양물질 유출에 관한 연구 (Study on Nutrient Loss in Surface Runoff by Rainfall from Slurrigated Area Using Digested Animal Manure)

  • 김선주;김형중;;;여운식
    • 한국농공학회지
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    • 제39권3호
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    • pp.43-51
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    • 1997
  • The nutrients runoff including nitrogen and phosphorous was investigated to find out the characteristics of nutrient discharge from the slurrigated area using digested animal manure. The results obtained are summarized as follows: 1.The concentrations of T-N, $NH_4$- N, EC, T- P and Cl- were high in flood runoff. 2.The concentration of nutrients by the surface runoff, except for $NO_3$-N, showed a tendency of increasing when the period of dry days before the rain fall was long. And the concentration of N$NO_3$-N increased in the inflow section where subsurface drainage flowed in. 3.The quality of water was generally influenced by the discharge of water quantity from slurrigated area. However the runoff concentration influenced the water quality when it was high enough. 4.To reduce loss of the nutrients and improve the fertilization effect, it is not recommended to apply slurry in rainy season.

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Nafion-DTPA-Glycerol이 수식된 유리탄소전극을 사용한 미분펄스 전압전류법에 의한 구리(II)이온의 측정 (Differential Pulse Voltammetric Determination of Copper(II) Using Glassy Carbon Electrodes Modified with Nafion-DTPA-Glycerol)

  • 박찬주;박은희;정근호
    • 한국환경보건학회지
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    • 제30권2호
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    • pp.115-122
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    • 2004
  • A glassy carbon electrode(GCE) modified with nafion-DTPA (diethylene triamine-pentaacetic acid)-glycerol is used for the highly selective and sensitive determination of a trace amount of Cu(II). Various experimental parameters, which influenced the response of nafion-DTPA-glycerol modified electrode to Cu(II), are optimized. The Copper(II) is accumulated on the electrode surface by the formation of the complex in an open circuit, and the resulting surface is characterized by medium exchange, electrochemical reduction, and differential pulse voltammetry(DPV). The electrochemical response is evaluated with respect to concentration of modifier, pH and preconcentration time, quiet time, copper(II) concentration, and other variables. A linear range is obtained in the concentration range 1.0${\times}$10$^{-8}$ M-1.0${\times}$10$^{-6}$ MCu(II) with 7 min preconcentration time. The detection limit(3s) is as low as 2.36${\times}$10$^{-8}$ M (1.50 ppb).

Facile Syntheses of Metal-organic Framework Cu3(BTC)2(H2O)3 under Ultrasound

  • Khan, Nazmul Abedin;Jhung, Sung-Hwa
    • Bulletin of the Korean Chemical Society
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    • 제30권12호
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    • pp.2921-2926
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    • 2009
  • Cu-BTC[$Cu_3(BTC)_2(H_2O)_3$, BTC = 1,3,5-benzenetricarboxylate], one of the most well-known metal-organic framework materials (MOF), has been synthesized under atmospheric pressure and room temperature by using ultrasound. The Cu-BTC can be obtained in 1 min in the presence of DMF (N,N-dimethylformamide), suggesting the possibility of continuous production of Cu-BTC. Moreover, the surface area and pore volume show that the concentration of DMF is important for the synthesis of Cu-BTC having high porosity. The morphology and phase also depend on the concentration of DMF : Cu-BTC cannot be obtained at room temperature in the absence of DMF and aggregated Cu-BTC (with low surface area) is produced in the presence of high concentration of DMF. It seems that the deprotonation of benzenetricarboxylic acid by base (such as DMF) is inevitable for the room temperature syntheses.

SOx노점의 전기적 측정 (Electrical Measurement of SOx Dew Point)

  • 전영남;용기중;채지우
    • 설비공학논문집
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    • 제7권4호
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    • pp.600-610
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    • 1995
  • When combustion gas is cooled down below the dew point of sulfuric acid vapor in the heat recovery systems, condensation occurs. Since the condensed sulfuric acid solution causes low-temperature corrosion in materials, it is important to measure the SOx dew point by electric measurement. In this study, two kinds of probes having electric gaps of 1mm or 2mm were used. and experiments were carried out by the parameters of sulfuric acid vapor and water vapor concentration. The changes of electric current caused by sulfuric acid condensed on the surface of probe according to the cooling rate and the probe head surface temperature were sudied. The opimum cooling rate was decreased with the increasing of water vaper concentration regardless of sulfuric acid concentration. The sensitivity of electric current is improved for the narrower gap(1mm) of ring electrodes, but it rarely affects the SOx dew point measuring of different probes according to the change of cooling rate.

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대구지역 CO농도에 미치는 기상효과에 관한 연구 (On the Meteorological Influence on the Automobile Air Pollution in Daegu)

  • 김해동;박명희;이정영
    • 한국환경과학회지
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    • 제12권9호
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    • pp.987-996
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    • 2003
  • In this study, we analyzed the relationship between the time-variation trend of air pollution concentration index and the meteorological conditions with CO(carbon monoxide) concentration and meteorological observation data in high-CO episode days. CO is a representative automobile air pollutant. The results are as follows; 1. Most of the high-CO episode days within 30 classes appeared in winter season. 2. Most of them appeared under the surface weather conditions with east-west high-pressure system. The surface winds in this high-pressure area were very light. 3. The high-CO episode days were due to unusual accumulation within urban atmosphere in the morning. 4. The Atmospheric stabilities were more stable, and then the wind-ventilation conditions were worse than yearly mean atmospheric condition in Daegu.

ELECTRICAL PROPERTIES OF ELECTROCHROMIC INDIUM NITRIDE THIN FILMS PREPARED BY RF ION PLATING

  • Asai, N.;Inoue, Y.;Sugimura, H.;Takai, O.
    • 한국표면공학회지
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    • 제32권3호
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    • pp.276-280
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    • 1999
  • Electrical properties of electrochromic (EC) InN thin films prepared by rf ion plating were studied. There was a correlation between the electrical properties and the electrochromism in the InN films, particularly, carrier concentration changes were responsible for the electrical resistivity changes of the films due to the electrochromism. These carrier concentration changes were caused by chemisorbed hydroxyl groups and protons. From these results, it was proved that the carrier concentration changes of the InN films was responsible for the electrochromism in the visible and near-infrared region.

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Optical Properties of Soluble Polythiophene for Flexible Solar Cell

  • Kim, Byoung-Ju;Park, Eun-Hye;Kang, Kwang-Sun
    • Current Photovoltaic Research
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    • 제6권4호
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    • pp.91-93
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    • 2018
  • Polythiophene-$TiO_2$ composite was synthesized with different molar ratios of thiophene and titaniumisopropoxide ($Ti(OPr)_4$) for flexible solar cell application as a flexible electrode or an active material. The $Ti(OPr)_4$ was stabilized by thiophene. The thiophene was polymerized by ferric chloride catalyst. The synthesized polythiophene exhibited strong UV-visible absorption in the range of the wavelength shorter than 500 nm. Field emission scanning electron microscope (FESEM) image of low concentration of $TiO_2$ film showed smooth surface. However, FESEM image of high concentration of $TiO_2$ film exhibited relatively rough surface. Polythiophene concentration dependent strong photoluminescence quenching of surfrhodamine-B was observed.

Adsorption behaviour of film-forming amine on pre-oxidized carbon steel surface

  • Genxian, Lin;Yun, Sun;Canshuai, Liu;Jun, Fang;Lijun, Song;Bin, Liu
    • Nuclear Engineering and Technology
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    • 제54권4호
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    • pp.1185-1194
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    • 2022
  • The maintenance of condenser main pipe is the key to achieve film-forming amine maintenance effectiveness. In this work, oxygen content, pH and temperature of the solution were controlled to simulate the condition of condenser main pipe, and magnetite coated carbon steel sample was prepared by pre-oxidization. CAM was used to characterize the hydrophobicity of film formed samples. Hydrophobic film was formed on pre-oxidized carbon steel samples when octadecylamine concentration reaches 20 mg/kg. SEM, EDS, EIS, and PD were used to characterize the influence of octadecylamine concentration on maintenance effectiveness. It was found that the maintenance effectiveness was enhanced and the corrosion rate was suppressed with the increase of octadecylamine concentration. FIB and TEM were used to detect the adsorbed octadecylamine film thickness founding that octadecylamine adsorbed onto the surface of pre-oxidized carbon steel by multi-layer adsorption mechanism.