• 제목/요약/키워드: Surface concentration

검색결과 6,117건 처리시간 0.036초

인삼염처리성에 미치는 소재 제조조건 영향 (Effect of Maunfacturing Conditions of Substrate on Phosphatability)

  • 김형준
    • 한국표면공학회지
    • /
    • 제30권5호
    • /
    • pp.310-319
    • /
    • 1997
  • The purpose of this study is to investigate the effect of the specific alloying elements in steel such as Cr, Ni and Cu, and surface roughness of substrate with two different FCS temperature zones in the CAL process on the phosphatability of the cold-rolled sheet used for the drum in order to improve the zinec phosphating property. Phosphatability is dependent of the surface oxide and roughness on the substrate and can be indirectly improved by increasing surface roughness of the steel sheet. Basically, in order to obtain the good phosphatability, the low concentration of the retained elements such as Cr, Ni and Cu among the steel alloy elements should be required. Phosphatability of substrate with high concentration instead of the retained elements and surface roughness, however, can be effectively improved instead of low FSC temperature.

  • PDF

계면활성(界面活性) 아미노싸이클리톨 유도체(誘導體)의 계면화학적(界面化學的) 성질(性質) (Surface Chemical Properties of Surface Active Aminocyclitol Derivatives)

  • 손주환;이창섭
    • 한국응용과학기술학회지
    • /
    • 제4권1호
    • /
    • pp.45-52
    • /
    • 1987
  • Surface chemical properties including surface tension, Ross-Miles foaming power, foam stabilities, emulsifying properties, emulsion stabilities, effectiveness of dispersion, dispersion stabilites of the quaternary ammonium salt type deoxyaminoimositol derivatives such as sixteen kinds of dimethylafkyl-deoxyscyllo-inosityl- dimethylalkyl-2-deoxy-2-myo-inosityl-, dimethylakyl-2-deoxy-2-epi-inosityl- and dimethylalkyl-4-deoxy-4-myo-inosityl ammonium chlorides are tested. And critical micelle concentration of these compounds are estimated from the curves of surface tension and concentration. The experimental results show that the members of this class of compounds have necessary surface active properties to make them effective surfactants.

$SnO_2$ 수용전극특성에 미치는 Sb첨가의 영향 (Effects of Sb doping on the Characteristis of $SnO_2$ Transparent Electrodes)

  • 이정한
    • 대한전자공학회논문지
    • /
    • 제13권3호
    • /
    • pp.16-21
    • /
    • 1976
  • 염화제이석을 출발물질로 하여 예열을 병용한 광무부착방식으로 유리 박판 위에 SnOf수명전극을 형성시켜 그의 Sheet 무항과 광투과률에 미치는 Sb연가량와 영향을 실행적으로 검토하였다. Sheet 저항을 전극작성시의 기판유리의 표면 온도가 높을수록 낮아지며 백색광에 대한 투과률을 Sheet 저항저하와 더불어 증가되는데 최대 약 93{%)였다. 기판표면온도는 700(℃) 부근이 적당하며 같은 표이온도의 경우 출발물질에서의 Sb/Sn의 비율이 약 0.6(%)일 경우 최저의 저항치를 얻을 수 있었다. Transparent eloctroaes of polycrystalline till-oxide films doped with antimony are prepared on the substrate of microscopic cover g1ass by modified spray method and from SnCl4 Solution. Their electrical and optical properties are investigated in relation to the surface temperature of the substrate glass and to antimony concentration in the starting materials. The sheet·resiststrace of the film electrodes and transmittance for incandescent light depen on tile antimony concentration and surface temperature of substrates at the time of making films. The transmittance increases with decrease of sheet resistance of the film. The optimum sheet·resistance was obtianed in the case of the antimony concentration 0.6(%) approximately , and the max. transmittance was 93(%).

  • PDF

안티몬 도핑된 주석 산화물 투명전도막의 몰 농도에 따른 치밀한 표면 구조 제조 (Fabrication of compact surface structure by molar concentration on Sb-doped SnO2 transparent conducting films)

  • 배주원;구본율;안효진
    • 한국분말재료학회지
    • /
    • 제25권1호
    • /
    • pp.54-59
    • /
    • 2018
  • Sb-doped $SnO_2$ (ATO) transparent conducting films are fabricated using horizontal ultrasonic spray pyrolysis deposition (HUSPD) to form uniform and compact film structures with homogeneously supplied precursor solution. To optimize the molar concentration and transparent conducting performance of the ATO films using HUSPD, we use precursor solutions of 0.15, 0.20, 0.25, and 0.30 M. As the molar concentration increases, the resultant ATO films exhibit more compact surface structures because of the larger crystallite sizes and higher ATO crystallinity because of the greater thickness from the accelerated growth of ATO. Thus, the ATO films prepared at 0.25 M have the best transparent conducting performance ($12.60{\pm}0.21{\Omega}/{\square}$ sheet resistance and 80.83% optical transmittance) and the highest figure-of-merit value ($9.44{\pm}0.17{\times}10^{-3}{\Omega}^{-1}$). The improvement in transparent conducting performance is attributed to the enhanced carrier concentration by the improved ATO crystallinity and Hall mobility with the compact surface structure and preferred (211) orientation, ascribed to the accelerated growth of ATO at the optimized molar concentration. Therefore, ATO films fabricated using HUSPD are transparent conducting film candidates for optoelectronic devices.

인천연안 갯벌의 다환방향족탄화수소의 농도분포와 발생원 평가 (Distributions and Sources of Polycyclic Aromatic Hydrocarbons in the Tidal Flat Sediments from Incheon Coastal Area)

  • 박정환;이충대;김진한
    • 한국습지학회지
    • /
    • 제15권4호
    • /
    • pp.441-451
    • /
    • 2013
  • 인천연안 8개 지역 갯벌의 72개 지점의 표층퇴적물과 24개 지점의 주상퇴적물 시료를 2011년 봄 가을 2회에 걸쳐 채취하여, 다환방향족탄화수소(PAHs), 석유계총탄화수소(TPHs) 및 벤젠-톨루엔-에틸벤젠-자일렌(BTEX)의 시 공간적 농도분포 특성을 조사하였다. 또한 PAHs 화합물 구성비에 의한 오염발생기원을 평가하였다. 갯벌 전체의 PAHs 평균농도는 $95.62{\mu}g/kg$으로 조사되었고, 계절별 PAHs 농도분포는 가을철이 봄철보다 낮은 특징을 보였다. 주상퇴적물의 PAHs 농도가 표층퇴적물보다 높았으며, 주상퇴적물의 상부가 하부보다 높은 농도분포를 보였다. 전체 갯벌의 TPHs 평균농도는 46 mg/kg으로 조사되었고, TPHs 평균농도 분포 양상은 봄철보다 가을철이 현저하게 높고, 표층퇴적물이 주상퇴적물보다 높게 나타났다. 갯벌 퇴적물내 PAHs의 오염발생 기원을 평가한 결과, 장화리 갯벌의 표층퇴적물과 소래 및 옥련 갯벌의 주상퇴적물의 PAHs 배출원은 연소와 석유류기원으로 조사되었고, 나머지 모든 갯벌은 연소기원으로 나타났다.

Sulfamate-Chloride Bath에서 Co 농도의 변화에 따른 Ni-Co 필름의 특성 변화 (Property Changes of Ni-Co Film with the Change of Co Concentration in Sulfamate-chloride Bath)

  • 윤필근;박덕용
    • 한국표면공학회지
    • /
    • 제53권1호
    • /
    • pp.1-8
    • /
    • 2020
  • Sulfamate-chloride baths were fabricated to study the properties of the electrodeposited Ni and NiCo thin films. The dependences of current efficiency, deposit composition of Ni and Co, residual stress, surface morphology and microstructure of electrodeposited Ni and NiCo thin films on CoCl2 concentration in sulfamate-chloride baths were investigated. The current efficiency was measured to be more than about 90%, independent of the changes of CoCl2 concentration in the baths. Residual stress of Ni and NiCo thin films was increased from about 45 to about 250 MPa with varying CoCl2 concentration from 0 to 0.210 M CoCl2 in the baths and then reached to a plateau, about 250 MPa above 0.420 M CoCl2 concentration. Nodular surface morphologies were observed at most CoCl2 concentrations in the baths except 0.210 M. NiCo thin film electrodeposited from the bath with 0.210 M CoCl2 concentration showed an acicular surface morphology. Pure Ni thin film consists of FCC(111), FCC(200), FCC(220), and FCC(311) peaks without any preferred orientation. On the other hand NiCo thin films make up of HCP(100), FCC(111), HCP(101), FCC(200), FCC(220) or HCP(110), FCC(311) or HCP(112) and FCC(222) peaks. It was revealed from the analysis of XRD result that FCC(111) peak at the NiCo thin film electrodeposited from the bath with 0.084 M CoCl2 concentration can be regarded as the preferred orientation. However the peak of the preferred orientation was changed to FCC(220) or HCP(110) above 0.084 M CoCl2 concentration in the baths. Then the intensity of FCC(220) or HCP(110) peak was gradually decreased with increasing CoCl2 concentration further. The crystalline size of pure Ni thin film was observed to be about 53 ㎛ and those of NiCo thin films were in the range of 35~45 ㎛.

콘택트렌즈 관리용액의 미셀임계농도 및 표면장력과 세척력 간의 상관관계 (The Correlation between Critical Micelle Concentration/Surface of Contact Lens Care Solutions Tension and Their Cleaning Efficacy)

  • 변현영;성형경;문준식;이아영;권세영;김소라;박미정
    • 한국안광학회지
    • /
    • 제19권1호
    • /
    • pp.23-30
    • /
    • 2014
  • 목적: 본 연구에서는 콘택트렌즈 관리용품의 세척력 평가를 위해 미셀임계농도 평가법, 표면장력 평가법 및 단백질세척효율평가법의 상관관계에 대해 알아보고자 하였다. 방법: 계면활성제의 미셀임계농도와 실제 콘택트렌즈 관리용액의 계면활성제 농도를 문헌과 관련 자료들을 이용하여 조사하였다. 표면장력기기로 $25{\pm}1^{\circ}C$에서 콘택트렌즈 관리용액의 표면장력을 측정하였으며, lotrafilcon A, comfilcon A, balafilcon A재질의 렌즈를 인공누액에 14일 동안 침착시킨 후 콘택트렌즈 관리용액으로 세척하여 세척효율을 비교하였다. 결과: 콘택트렌즈 관리용품 22제품 중 계면활성제 농도가 표시된 제품은 9제품이었으며 문헌상의 미셀임계농도보다 계면활성제 농도가 더 높은 제품은 7제품이었다. 표면장력을 측정한 결과 대체적으로 소프트렌즈용 관리용품의 표면장력이 다른 관리용품보다 낮음을 알 수 있었으며, 렌즈에 침착된 단백질 제거효과 분석 결과에서는 표면장력이 더 낮은 제품의 단백질 제거효율이 더 높은 것을 알 수 있었다. 결론: 콘택트렌즈 관리용액의 계면활성제 농도가 높은 경우 표면장력이 낮으며, 표면장력이 낮을수록 침착된 단백질 세척 효율이 높아져 세척력 평가법 간에 서로 상관관계가 있음을 밝혔다.

Effect of the Concentration of Cobalt Chloride Solution for the Preparation of Nano-Sized Cobalt Oxide Powder by Spray Pyrolysis Process

  • Yu, Jae Keun;Cha, Kwang Yong;Seo, Dong Jun;Han, Joung Su;Jang, Jae Bum;Lee, Yong Hwa;Kim, Dong Hee
    • 한국재료학회지
    • /
    • 제24권6호
    • /
    • pp.277-284
    • /
    • 2014
  • Using the spray pyrolysis process, nano-sized cobalt oxide powder with average particle size below 50 nm was prepared from cobalt chloride solution. The influences of the raw material solution on the properties of the powder formed examined. When the concentration of Co was low(20 g/L), the average particle size of the powder formed was roughly 20 nm, and the cohesion between these particles was significantly strong. When the concentration of Co increased to 100 g/L, the droplets nearly failed to exist in circular form and reflected a severely divided form. Furthermore, the average size of the particles formed was roughly 40 nm, and the particles reflected a polygonal form. When the solution was increased to nearly saturation level (Co at 200 g/L), the particle size distribution reflected significant unevenness due to severe droplet division while the surface also reflected significant unevenness. Furthermore, the average size of the particles formed increased significantly to 70 nm. The results of XRD analysis showed that the strength of the peaks reflected very little change when the concentration of Co was increased from 20 g/L to 50 g/L. Alternatively, when the concentration was increased to 100 g/L, the strength of the peaks increased compared to when the concentration was 50 g/L. However, when the concentration was increased to 200 g/L, the strength of the peaks failed to reflect significant change compared to when the concentration was 100 g/L. The specific surface area dramatically decreased by 30 % when the concentration of Co was increased from 20 g/L to 50 g/L. Alternatively, when the concentration of Co the solution increased to 100 g/L, the specific surface area decreased by roughly 15 %. Furthermore, when the concentration of Co was increased to nearly saturation level(200 g/L), the specific surface area decreased by roughly 35%.

Alteration of Leaf Surface Structures of Poplars under Elevated Air Temperature and Carbon Dioxide Concentration

  • Kim, Ki Woo;Oh, Chang Young;Lee, Jae-Cheon;Lee, Solji;Kim, Pan-Gi
    • Applied Microscopy
    • /
    • 제43권3호
    • /
    • pp.110-116
    • /
    • 2013
  • Effects of elevated air temperature and carbon dioxide ($CO_2$) concentration on the leaf surface structures were investigated in Liriodendron tulipifera (yellow poplar) and Populus tomentiglandulosa (Suwon poplar). Cuttings of the two tree species were exposed to elevated air temperatures at $27/22^{\circ}C$ (day/night) and $CO_2$ concentrations at 770/790 ppm for three months. The abaxial leaf surface of yellow poplar under an ambient condition ($22/17^{\circ}C$ and 380/400 ppm) had stomata and epicuticular waxes (transversely ridged rodlets). A prominent increase in the density of epicuticular waxes was found on the leaves under the elevated condition. Meanwhile, the abaxial leaf surface of Suwon poplar under an ambient condition was covered with long trichomes. The leaves under the elevated condition possessed a higher amount of long trichomes than those under the ambient condition. These results suggest that the two poplar species may change their leaf surface structures under the elevated air temperature and $CO_2$ concentration condition for acclimation of increased photosynthesis.

유변학적 특성과 표면장력측정을 통한 음이온성 폴리머와 비이온성 계면활성제의 상호작용에 대한 연구 (Investigation of the Interactions between Anionic Polymer and Nonionic Surfactant with Rheological and Surface Tension Measurements)

  • 이정노;김동주;고하영
    • 한국응용과학기술학회지
    • /
    • 제24권2호
    • /
    • pp.160-166
    • /
    • 2007
  • The rheological properties and surface tensions of polymer solutions and polymer-surfactant mixed solutions were investigated. The polymers used in this study were a homopolymer of acrylic acid crosslinked with an allyl ether of pentaerythritol, an allyl ether of sucrose, or an allyl ether of propylene (CARBOMER), acylate/C10-30 alkyl acylate crosspolymer (AAAC), and ammonium acryloydimethyltaurate/VP copolymer (ADTV). A solubilizing agent PEG-40 hydrogenated castor oil (HCO-40) and an emulsifying agent polyoxyethylene (20) sorbitan monostearate (POLYSORBATE 60) made the micelles intervening between AAAC polymers, resulting in the increase of viscosity. However, HCO-40 made this behavior over the wider range of surfactant concentration than POLYSORBATE 60. From the view point of surface tensions in the same range of surfactant concentration, AAAC/HCO-40 solution showed the area of increasing surface tension with surfactant concentration in contrast to the AAAC/POLYSORBATE 60 solution showing no increasing area.