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http://dx.doi.org/10.12925/jkocs.2007.24.2.7

Investigation of the Interactions between Anionic Polymer and Nonionic Surfactant with Rheological and Surface Tension Measurements  

Lee, Jung-No (Dept. of Bio Quality Control, Korea Bio Polytechnic)
Kim, Dong-Joo (Cosmetics R&D Center, LG Household & Health Care Ltd.)
Koh, Ha-Young (Dept. of Bio Quality Control, Korea Bio Polytechnic)
Publication Information
Journal of the Korean Applied Science and Technology / v.24, no.2, 2007 , pp. 160-166 More about this Journal
Abstract
The rheological properties and surface tensions of polymer solutions and polymer-surfactant mixed solutions were investigated. The polymers used in this study were a homopolymer of acrylic acid crosslinked with an allyl ether of pentaerythritol, an allyl ether of sucrose, or an allyl ether of propylene (CARBOMER), acylate/C10-30 alkyl acylate crosspolymer (AAAC), and ammonium acryloydimethyltaurate/VP copolymer (ADTV). A solubilizing agent PEG-40 hydrogenated castor oil (HCO-40) and an emulsifying agent polyoxyethylene (20) sorbitan monostearate (POLYSORBATE 60) made the micelles intervening between AAAC polymers, resulting in the increase of viscosity. However, HCO-40 made this behavior over the wider range of surfactant concentration than POLYSORBATE 60. From the view point of surface tensions in the same range of surfactant concentration, AAAC/HCO-40 solution showed the area of increasing surface tension with surfactant concentration in contrast to the AAAC/POLYSORBATE 60 solution showing no increasing area.
Keywords
interaction; polymer-surfactant; rheological properties; surface tension;
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  • Reference
1 R. Zana, Polymer-Surfactant Systems, Kwak, J C. T., Marcel Dekker, New York, pp. 409-454 (1998)
2 E. D. Goddard, Principles of Polymer Science and Technology in Cosmetics and Personal Care, E. D. Goddard and J. Gruber, Marcel Dekker, New York, Chapter 4, pp.1l3-180 (1999)
3 S. Panmai, R. Prud'hornrne, D. Peiffer, S. Jochusch and N. Turro, Interactions between Hydrophobically Modified Polymers and Surfactants: A Fluorescence Study, Langmuir, 18, 3860 (2002)   DOI   ScienceOn
4 C. W. Macosko, Rheology: Principles, Measurements and Applications, John Wiley & Sons, New York (1994)
5 K. Hayakawa, J. P. Santerre and J. C. T. Kwak, Study of Surfactant-Polyelectrolyte Interactions. Binding of Dodecyl- and Tetradecyltrimethylammonium Bromide by Some Carboxylic Polyelectrolytes, Macromolecules, 16, 1642 (1983)   DOI
6 J. Lee and Y. Moroi, Solubilization of n-Alkylbenzenes in Aggregates of Sodium Dodecyl Sulfate and a Cationic Polymer of High Charge Density (II), Langmuir, 20, 6116 (2004)   DOI   ScienceOn
7 B. Magny, F. Lafuma and I. Iliopoulos, Determination of Microstructure of Hydrophobically Modified Water-soluble Polymers by 13C N.M.R., Polymer, 33, 3151 (1992)   DOI   ScienceOn
8 K. Hayakawa and J. C. T. Kwak, Cationic Surfactants: Physical Chemistry, D. N. Rubingh and P. M. Holland, Marcel Dekker, New York, Chapter 5, (1990)
9 J. Lee and Y. Moroi, Solubilization Study for Aggregates of Sodium dodecyl Sulfate and Cationic Polymer of High Charge Density, J. Colloid Interface Sci., 273, 645 (2004)   DOI   ScienceOn
10 J. Liu, M. Nakama, N. Takisawa and K. Shirahama, Binding of Dodecyloxyethylpyridiniurn Bromide to Polymer: the Effect of Molecular Geometry of Surfactant, Colloids surf A, 150, 275(1999)   DOI
11 J. Lee and Y. Moroi, Binding of Sodium Dodecyl Sulfate to a Cationic Polymer of High Charge Density, Bull. Chem Soc. Jpn., 76, 2099 (2003)   DOI   ScienceOn
12 C. J. Davidson, P. Meares and D. G. Hall, A Polymeric Electrode for Ionic Surfactants, J. Membr. Sci., 36, 511 (1988)   DOI   ScienceOn
13 K. Shirahama, S. Sato, N. Niino and N. Takisawa, Interaction of Surfactant with Polymer Gel Binding Isotherm and Swelling Ratio, Colloids surf A, 112, 233 (1996)   DOI
14 S. Nilsson, K. Thuresson, P. Hansson and B. Lindman, Mixed Solutions of Surfactant and Hydrophobically Modified Polymer. Controlling Viscosity with Micellar Size, J. Phys. Chem. B, 102, 7099 (1998)   DOI   ScienceOn
15 T. Noda, A. Hashidzume and Y. Morishima, Rheological Properties of Transient Networks Formed from Copolymers of Sodium Acrylate and Methacrylates Substituted with Arnphiphiles: Comparison with Sodium 2-(Aerylamido)-2-methylpropanesulfonate Copolymers, Langmuir, 17, 5984 (2001)
16 S. Sallustio, L.Galantini, G. Gente, G. Masci, and C. La Mesa, Hydrophobically Modified Pullulans : Characterization and Physicochemical Properties, J. Phys. Chem B., 108, 18876 (2004)   DOI   ScienceOn