• Title/Summary/Keyword: Surface concentration

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Distribution of Nonylphenol in Gwangyang Bay and the Surrounding Streams (광양만 및 주변 하천에서의 노닐페놀 화합물 분포)

  • 이동호;김민선;심원준;임운혁;홍상희;오재룡
    • Korean Journal of Environmental Biology
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    • v.22
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    • pp.71-77
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    • 2004
  • Alkylphenols (8), chlorophenols (2), bisphenol A, eoprostanols (2) and cholesterol compounds were analyzed in the surface water and surface sediment taken from Gwangyang Bay and surrounding streams in 2001. Among the target analytes, nonylphenol and dihydrocholesteyol compounds were detected with high concentration and high frequency. t-Octylphenol, bisphenol A and coprostanols were detected only in some sediment samples from the stream. The highest concentration of nonylphenol was determined in stream sample, and concentrations of nonylphenol in the inner part of Gwangyang Bay were higher than those in the out part. Nonylphenol concentrations in the surface seawater and surface sediment samples ranged from 4.0 to 74.0 ng l$\^$-1/ and from 3.1 to 74.3 ng g$\^$-1/ dry wt., respectively. Partition coefficient (LogK$\_$oc/) of nonylphenol between sediment and water was 4.8. Nonylphenol nnd dihydrocholesteol concentrations in the stream surface sediment samples ranged from 4.6 to 808.6 and from 78.4 to 1133.6 ng g$\^$-1/ dry wt., respectively. Relatively high concentrations of nonylphenol were found in the stream samples which aye flowing through industrial complex area, while dihydrocholesterol concentration was relatively high in the stream samples which are flowing through only municipal area. Seaward decreasing tyend in nonylphenol concentration was observed from the Seomjin River estuary to the Gwanyang Bay. Such trend was best supported by the strong correlation between nonylphenol concentration and salinity in water samples.

Water Quality Model Development for Loading Estimates from Paddy Field (논에서의 오염부하 예측을 위한 범용모형 개발)

  • Jeon, Ji-Hong;Hwang, Ha-Sun;Yoon, Kwang-Sik;Yoon, Chun-Gyeong
    • Korean Journal of Ecology and Environment
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    • v.36 no.3 s.104
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    • pp.344-355
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    • 2003
  • Water quality model applicable paddy field was developed using field experiment during 1999 ${\sim}$ 2002. This model involves inputs from fertilization and sediment release as dirac delta function and continuous source function, respectively, and can simulate various processes such as ponded depth, surface drainage, total nitrogen concentration and total phosphorus concentration in a daily basis. The model was calibrated using data collected from field experiments which was irrigated with ground water and validated from field experiments which was irrigated with surface water. The nutrient concentration of surface water depended on the fertilization and dirac delta function can efficiently explain the valiance of nutrient concentration of surface water by fertilizer. As a result of calibration and validation, this model demonstrates good agreement. The model fit efficiencies ($R^2$) of ponded depth, surface concentration of TN and TP were 0.93,0.98 and 0.95, respectively for calibration, and those of TN and TP were 0.99 and 0.70, respectively for validation. We can apply lake and reservoir model to analysis paddy field considered with shallow ponded system, but it will need so many parameters and have much uncertainty. Fortunately, paddy field have a series of cultural practices yearly basis, such as irrigation-fertilization-forced drain-harvest with a similar time , so simple model may explain the mechanism for paddy field. Water quality model for paddy field developed in this study is simply, needs little parameters, but appeared high applicability to evaluate paddy filed drainage. We recommend this model to estimate nutrient loading from paddy field and establish best management practice.

Effect of Current Density on Nickel Surface Treatment Process (니켈 표면처리공정에서 전류밀도 효과분석)

  • Kim, Yong-Woon;Joeng, Koo-Hyung;Hong, In-Kwon
    • Applied Chemistry for Engineering
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    • v.19 no.2
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    • pp.228-235
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    • 2008
  • Nickel plating thickness increased with the electric current density, and the augmentation was more thick in $6{\sim}10A/dm^2$ than low current. Hull-cell analysis was tested to evaluate the current density. Optimum thickness was obtained at a temperature of $60^{\circ}C$, and the pH fluctuation of 3.5~4.0. Over the Nickel ion concentration of 300 g/L, plating thickness increased with the current density. The rate of decrease in nickel ion concentration was increased with the current density. The quantity of plating electro-deposition was increased at the anode surface, which was correlated with the increase of plating thickness. The plating thickness was increased because of the quick plating speed. However, the condition of the plating surface becomes irregular and the minuteness of nickel plating layer was reduced with the plating rate. After the corrosion test of 25 h, it was resulted in that maintaining low electric current density is desirable for the excellent corrosion resistance in lustered nickel plating. According to the program simulation, the thickness of diffusion layer was increased and the concentration of anode surface was lowered for the higher current densities. The concentration profile showed the regular distribution at low electric current density. The field plating process was controlled by the electric current density and the plating thickness instead of plating time for the productivity. The surface physical property of plating structure or corrosion resistance was excellent in the case of low electric current density.

Surface Morphology and Preferred Orientation of Gold Bump Layer formed by using $Na_3[Au(SO_3)_2]$ (아황산금나트륨염을 이용한 Au 범프용 금도금층의 표면형상 및 우선적 결정 성장방향)

  • Kim, In-Su;Yang, Seong-Hun;Park, Jong-Wan
    • Korean Journal of Materials Research
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    • v.5 no.6
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    • pp.673-681
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    • 1995
  • Surface morphology and preferred orientation of 20${\mu}{\textrm}{m}$ gold electrodeposit formed from aqueous solution of the sodium gold sulfite were studied in terms of current density, plating temperature and Au concentration. As the current density changed from 13.0mA/$\textrm{cm}^2$ to 4.6mA/$\textrm{cm}^2$, the solution temperature from 3$0^{\circ}C$ to 6$0^{\circ}C$, pH from 12.0 to 9.0, agitation speed from 0 rpm to 3200rpm and Au concentration from 10g/1 to 14 g/1, local Au concentration near the cathodic surface increased. With increasing the Au concentration, the surface morphology chanced from porous structure to fine-grained structure. Furthermore, it was observed that the preferred orentation of the Au layer changed from (111) to (220) upon the same variation In the Au concentration. The surface morphology and the preferred orientation of the Au layer were found to be closely related to each other.

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The Long-term Variations of Water Qualities in the Saemangeum Salt-Water Lake after the Sea-dike Construction (방조제 체절이후 새만금호의 장기적인 수질변화)

  • Jeong, Yong Hoon;Yang, Jae Sam
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.18 no.2
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    • pp.51-63
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    • 2015
  • In order to investigation long-term variations of water qualities in the Saemangeum Salt-Water Lake formed after the sea-dike construction, the survey has carried out over 40 time from 2002 to 2010. The decreased salinity in surface water immediately after the dike construction has maintained on equal terms for years. After the dike construction, the early concentration of SPM in surface water has decreased but then it showed the tendency to move up and down due to the changes of water level in the lake. The elevated concentration of Chl-a in surface water initially after the dike construction was kept at the same conditions for years. The concentration of DIN in surface water has not changed before and shortly after the dike construction. However, the concentration of $NH_4-N$ in surface water has increased steadily after the dike construction. Consequently the concentration of DIN in the lake water after years has raised compared to pre-dike construction. The reduced concentration of DIP in surface water soon after the dike construction has increased after years as well as $NH_4-N$ due to the accumulation of organic matter to inside lake. Unlike with the unvaried $NO_3-N$, the concentration of DISi in surface water after the dike construction has immediately increased and maintained the enhanced level indicating the supply from other sources except the freshwater. Since the dike construction, the spatial characteristics of water quality was divided river sides and rest of the lake markedly. Stratification of river sides was more strong than the dike sides. In the warm seasons, hypoxia causing the release of nutrients and metals from sediment was observed downward about 1 m from surface of river sides. We strongly suggest to make some urgent measure to prevent low dissolved oxygen condition in the bottom layer of the river sides.

Recycling of Suspended Particulates by Atmospheric Boundary Depth and Coastal Circulation (대기경계층과 연안순환에 의한 부유입자의 재순환)

  • Choe, Hyo
    • Journal of Environmental Science International
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    • v.13 no.8
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    • pp.721-731
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    • 2004
  • The dispersion of suspended particulates in the coastal complex terrain of mountain-inland basin (city)-sea, considering their recycling was investigated using three-dimensional non-hydrostatic numerical model and lagrangian particle model (or random walk model). Convective boundary layer under synoptic scale westerly wind is developed with a thickness of about I km over the ground in the west of the mountain, while a thickness of thermal internal boundary layer (TIBL) is only confined to less than 200m along the eastern slope of the mountain, below an easterly sea breeze circulation. At the mid of the eastern slop of the mountain, westerly wind confronts easterly sea breeze, which goes to the height of 1700 m above sea level and is finally eastward return flow toward the sea. At this time, particulates floated from the ground surface of the city to the top of TIBL go along the eastern slope of the mountain in the passage of sea breeze, being away the TIBL and reach near the top of the mountain. Then those particulates disperse eastward below the height of sea-breeze circulation and widely spread out over the coastal sea. Total suspended particulate concentration near the ground surface of the city is very low. On the other hand, nighttime radiative cooling produces a shallow nocturnal surface inversion layer (NSIL) of 200 m thickness over the inland surface, but relatively thin thickness less than 100m is found near the mountain surface. As synoptic scale westerly wind should be intensified under the association of mountain wind along the eastern slope of mountain to inland plain and further combine with land-breeze from inland plain toward sea, resulting in strong wind as internal gravity waves with a hydraulic jump motion bounding up to about 1km upper level in the atmosphere in the west of the city and becoming a eastward return flow. Simultaneously, wind near the eastern coastal side of the city was moderate. Since the downward strong wind penetrated into the city, the particulate matters floated near the top of the mountain in the day also moved down along the eastern slope of the mountain, reaching the. downtown and merging in the ground surface inside the NSIL with a maximum ground level concentration of total suspended particulates (TSP) at 0300 LST. Some of them were bounded up from the ground surface to the 1km upper level and the others were forward to the coastal sea surface, showing their dispersions from the coastal NSIL toward the propagation area of internal gravity waves. On the next day at 0600 LST and 0900 LST, the dispersed particulates into the coastal sea could return to the coastal inland area under the influence of sea breeze and the recycled particulates combine with emitted ones from the ground surface, resulting in relatively high TSP concentration. Later, they float again up to the thermal internal boundary layer, following sea breeze circulation.

Statistical Approach for Derivation of Quantitative Acceptance Criteria for Radioactive Wastes to Near Surface Disposal Facility

  • Park Jin Beak;Park Joo Wan;Lee Eun Yong;Kim Chang Lak
    • Nuclear Engineering and Technology
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    • v.35 no.5
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    • pp.387-398
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    • 2003
  • For reference human intrusion scenarios constructed in previous study, a probabilistic safety assessment to derive the radionuclide concentration limits for the low- and intermediate- level radioactive waste disposal facility is conducted. Statistical approach by the Latin Hypercube Sampling method is introduced and new assumptions about the disposal facility system are examined and discussed. In our previous study of deterministic approach, the post construction scenarios appeared as most limiting scenario to derive the radionuclide concentration limits. Whereas, in this statistical approach, the post drilling and the post construction scenarios are mutually competing for the scenario selection according to which radionuclides are more important in safety assessment context. Introduction of new assumption shows that the post drilling scenario can play an important role as the limiting scenario instead of the post-construction scenario. When we compare the concentration limits between the previous and this study, concentrations of radionuclides such as Nb-94, Cs-137 and alpha-emitting radionuclides show elevated values than the case of the previous study. Remaining radionuclides such as Sr-90, Tc-99 I-129, Ni-59 and Ni-63 show lower values than the case of the previous study.

Monitoring of Organoleptic and Physical Properties on Preparation of Oriental Melon Jelly (참외젤리 제조에 따른 관능적 및 물리적 특성 모니터링)

  • Lee, Gee-Dong;Yoon, Sung-Ran;Lee, Myung-Hee
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.8
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    • pp.1373-1380
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    • 2004
  • To prepare oriental melon jelly having highly favorite, oranoleptic and physical properties of jelly with special to the content of glucomannan, oriental melon concentration juice and vinegar was monitored by four-dimensional response surface methodology. Mouth-feel showed maximum sensory score in 0.09% glucomannan, 3.17% oriental melon concentration juice and 1.25% oriental melon vinegar. Organoleptic taste showed maximum sensory score in 0.12% glucomannan, 3.64% oriental melon concentration juice and 0.91% oriental melon vinegar. Overall palatability showed also maximum sensory score in 0.10% glucomannan, 3.07% oriental melon concentration juice and 1.34% oriental melon vinegar. The sensory socore of overall palatability was more than 7.0 in the texture ranges of 0.20~0.31 cm/g (softness) and 8.0~12.5 gㆍcm (jelly strength).

A Study on the Sensitivity Analysis of Line Source Air Quality Models (移動汚染源에 대한 大氣擴散模型의 感應度 分析에 관한 硏究 (HIWAY2, PAL, CALINE3 模型을 對象으로))

  • 김선태;김병태;김정욱
    • Journal of Korean Society for Atmospheric Environment
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    • v.5 no.1
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    • pp.1-10
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    • 1989
  • The sensitivity analysis is a method to quantify to what extent the output of a model changes with the values of input parameters. This will lead to increase model accuracy through measurement validation. Three line source air quality models, HIWAY 2, PAL, and CALINE 3 were selected for this study. The input parameters analysed included wind speed, wind direction, stability, emission rate, mixing height, receptor distance, initial dispersion coefficient, surface roughness, and averaging time. It turned out that PAL model generally showed higher concentration than other two models, and that between CALINE 3 and HIWAY 2, CALINE 3 showed higher concentration than HIWAY 2 model near the line sources, but beyond a certain downwind distances HIWAY 2 model showed higher concentration. The modesl were very sensitive to wind speed especially in the range of 0 $\sim$ 1 m/s and to wind direction near the parallel wind to streets. In case of emission rate, the output concentration was directly proportional to these input parameters. And the sensitivity of the input parameters such as stability, mixing height, initial dispersion coefficient, surface roughness, and averaging time were not very significant.

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Air Quality Modeling of Ozone Concentration According to the Roughness Length on the Complex Terrain (복잡지형에서의 지표면 거칠기에 따른 오존 농도 수치모의)

  • Choi, Hyun-Jung;Lee, Hwa-Woon;Sung, Kyoung-Hee
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.4
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    • pp.430-439
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    • 2007
  • The objective of this work is the air quality modeling according to the practical roughness length using the building information as surface boundary conditions. As accurate wind and temperature field are required to produce realistic urban air quality modeling, comparative simulations by various roughness length are discussed. The prognostic meteorological fields and air quality field over complex areas of Seoul, Korea are generated by the PSU/NCAR mesoscale model (MM5) and the Third Generation Community Multi-scale Air Quality Modeling System (Models-3/CMAQ), respectively. The simulated $O_3$ concentration on complex terrain and their interactions with the weak synoptic flow had relatively strong effects by the roughness length. A comparison of the three meteorological fields of respective roughness length reveals substantial localized differences in surface temperature and wind folds. Under these conditions, the ascended mixing height and weakened wind speed at night which induced the stable boundary stronger, and the difference of simulated $O_3$ concentration is $2{\sim}6\;ppb$.