• Title/Summary/Keyword: Surface concentration

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Prediction of Optimal Microwave Extraction Conditions for Functional Compounds from Agrimonia pilosa Ledeb Using Response Surface Methodology (반응표면분석법을 이용한 용아초 기능성 성분의 마이크로웨이브 최적 추출조건 예측)

  • Park, Jong Jin;Lee, Won Young
    • Korean Journal of Medicinal Crop Science
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    • v.24 no.4
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    • pp.263-270
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    • 2016
  • Background: In this study, microwave extraction was used, which is an effective method to extract useful bioactive substances as it requires low quantities of solvent and short time periods. The aim of this study was to determine the optimal extraction conditions for Agrimonia pilosa Ledeb. Methods and Results: The independent variables were ethanol concentration, microwave power, and extraction time, each of which had five levels. The dependent variables were total polyphenol and total flavonoid content, and DPPH radical scavenging activity. To determine the optimal extraction conditions for bioactive compounds, a response surface methodology was employed. Contour maps were generated from polynomial equations. The optimal conditions were then assumed by superimposing these contour maps. Based on the resulting graph, the optimal microwave extraction conditions for Agrimonia pilosa Ledeb were determined as 42 - 48% ethanol concentration, 240 - 280W microwave power, and 13 - 20 min of extraction time. Conclusions: Ethanol concentration had a significant effect on microwave extraction, in terms of total polyphenol and total flavonoid content, as well as DPPH radical scavenging activity. Microwave power and extraction time influenced the total polyphenol content, but not the total flavonoid content or the DPPH radical scavenging activity.

Evaluation of Airborne and Surface Lead Concentrations in Preschool Classroom (유아교육시설의 표면 및 공기 중 납 농도 평가)

  • Yoon, Chung-Sik;Paik, Do-Hyeon
    • Journal of Environmental Health Sciences
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    • v.32 no.1 s.88
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    • pp.1-7
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    • 2006
  • This study was performed to investigate airborne lead concentration and surface lead contents in preschool facilities. Arithmetic mean of indoor lead concentration in urban area was $44.7\;ng/m^3$ (Geometric mean $32.1\;ng/m^3$) whereas outdoor concentration was $39.5\;ng/m^3$ (GM $22.8\;ng/m^3$). In rural area, airborne lead concentrations were $14.2\;ng/m^3\;(GM\;7.9 ng/m^3),\;12.6\;ng/m^3\;(GM\;5.6 ng/m^3)$, respectively. There is statistical significance of the lead concentrations among the locations of preschool facilities. About $37\%$ of qualitative lead check samples was positive and mainly was found in lead based paint. Though lead concentrations on the floor and window sill were well below the US EPA and HUD standard (floor $40\;{\mu}g/ft^2\;(4.3\;{\mu}g/100\;cm^2)$, window sill $250\;{\mu}g/ft^2\;(26.9\;{\mu}g/100\;cm^2)$, respectively), there were much samples which exceed the standard, i.e., $29\%$ of surface wall, $20\%$ of the desk and chair, $100\%$ of painted wood box of tested samples. In view of our study and hazard of lead to children, we recommended that the contents of lead in preschool facilities should be lowered as possible.

Effect of non-uniform magnetic field on the thermal behavior and mass transfer in magnetohydrodynamic Czochralski crystal growth of silicon (Magnetic Czochralski 실리콘 단결정 성장에서 열 및 유체유동과 질량전달에 미치는 비균일 자장의 효과)

  • 김창녕
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.555-562
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    • 1998
  • Under the influence of non-uniform magnetic field, melt flow in steady state and oxygen concentration in unsteady state are numerically investigated. The strength of the applied characteristic magnetic fields are B=0.1T, 0.2T, and 0.3T, respectively. The buoyancy effects due to the crucible wall heating and the thermocapillary effects due to the surface tention at the free surface are suppressed differentially by the non-uniform magnetic fields. As the intensity of characteristic magnetic fields is increasing, the recirculation region in the meridional plane is moving toward the growing crystal, and is diminishing. The oxygen concentration on the growing surface of crystals is decreasing and the uniformity of the oxygen concentration is increasing as the intensity of the magnetic fields is increasing.

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Conductivity and Surface Tension Behavior for Binary Mixtures over a Various Concentration of TTAB

  • Ahn, Beom-Shu
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.2
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    • pp.160-168
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    • 2006
  • The conductances of trimethyltetradecylammonium bromide (TTAB) plus triphenyltetradecyl phosphonium bromide (TTPB) and TTAB plus trimethylhexadecylammonium bromide (HTAB) over the entire mole fraction range of TTAB were measured in water and in cyclodextrin plus water mixtures at fixed 4 and 8 mM of cyclodextrin at $30^{\circ}C$. The conductivity plot for both binary mixtures shows a single break from which the mixed critical micelle concentration and degree of micelle ionization were computed. From the slope of the conductivity curve, the equivalent ionic conductivities of the monomeric, associated, and the micelle states were calculated and discussed with respect to the surfactant-cyclodextrin complexation in the whole mole fraction range of both surfactant binary mixtures. The association constant K between the respective monomeric surfactant and cyclodextrin cavity of fixed 4 mM cyclodextrin was computed by considering 1:1 association from the surface tension measurement. A comparison among the K values for HTAB-cyclodetrin, TTAB-cyclodextrin, and TTPB-cyclodextrin shows that the former complexation is significantly stronger in comparison to the other ones due to the longer hydrophobic tail.

The effect of surface texturization on the thermal and electric characteristics of photovoltaic devices (표면 texturizaton에 따른 photovoltaic device의 열적 전기적 특성)

  • Jung, Ji-Chul;Jung, Byung-Eon;Lee, Jung-Ho;Koo, Sang-Mo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.133-133
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    • 2010
  • We studied the thermal and electric effect of 2D and 3D p-n photovoltaic diode structures with and without surface texturing. By analyzing the numerical simulation results of I-V characteristics and lattice temperature distributions, we systematically studied the effect of different texturing structures and different doping concentration on the characteristics of the silicon p-n photovoltaic devices. The, efficiency of the device with the surface texturing shows more than ~ 2% enhancement compared to the reference devices without texturing. The tendency of the efficiency of doping concentration has been studied with boron doping of $10^{14}{\sim}10^{17}cm^{-3}$ and phosphorus doping of $10^{15}cm^{-3}$. In addition to that, the study of changing phosphorus doping of $10^{15}{\sim}10^{18}cm^{-3}$ with boron doping of $10^{14}cm^{-3}$ has been examined. It has been shown that the texturing structure not only improves the light trapping but also plays an important role in the heat radiation.

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The analysis on TMA gas-sensing characteristics of ZnO thin film sensors (ZnO 막막 센서의 TMA 가스 검지 특성 분석)

  • 류지열;박성현;최혁환;김진섭;이명교;권태하
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.34D no.12
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    • pp.46-53
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    • 1997
  • The TMA gas sensors are fabricated with the ZnO-based thin films grown by a RF magnetron sputtering method. The hall effect measurement and AES analysis are carried out to investigate the effects of the sputtering gases and dopants which effect on the electrical resistivity and sensitivity to TMA gas. We measure the cfhanges of the surface carrier concentration, haall electron mobility, electrical resistivity, surface condition, and depth profile of the films. The ZnO-based thin film sensors sputtered in oxygen, or added with dopants showed a high sruface carrier concentration, film sensors sputtered in oxygen and doped with 4.0 wt.% $Al_{2}$O$_{3}$, 1.0 wt.% TiO$_{2}$, and 0.2 wt% v$_{2}$O$_{5}$ showed the highest surface carrier concentration of 5.952 * 10$^{20}$ cm$^{-3}$ , hall electron mobility of 176.7 cm$^{2}$/V.s, lowest electrical resistivity of 6*10$^{-5}$ .ohm.cm and highest sensitivity of 12. These results were measured at a working temperature of 300.deg. C to 8 ppm TMA gas.

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Controlling the Porosity of Particle Stabilized Al2O3 Based Ceramics

  • Pokhrel, Ashish;Park, Jung-Gyu;Jho, Gae-Hyong;Kim, Jin-Young;Kim, Ik-Jin
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.600-603
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    • 2011
  • The microstructure of particle stabilized wet foams can be tailored by using parameters including the amphiphile concentration, contact angle, and surface tension. The influence of these parameters on the porosity is satisfactorily described in terms of a combined influence of the contact angle and surface tension of the initial suspensions that are directly affected by the amphiphile concentration. The resulting macroporous structures exhibited a total porosity of 82%. The foam cells were predominantly closed due to the air bubbles of the original wet foams being completely covered.

Adsorption Characterization of Cd by Activated Carbon containing Hydroxyapatite using Response Surface Methodology (RSM) (반응표면분석법을 이용한 Hydroxyapatite 첨가 활성탄에서의 Cd 흡착특성에 관한 연구)

  • An, Sang-Woo;Yoo, Ji-Young;Choi, Jae-Young;Park, Jae-Woo
    • Journal of Korean Society on Water Environment
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    • v.25 no.6
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    • pp.943-950
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    • 2009
  • Cadmium (Cd) adsorption onto the activated carbon containing hydroxyapatite (HAP) was investigated in batch experiments and response surface methodology (RSM) using the Box-Behnken methods were applied to the experimental results. Cd adsorption with different HAP mass ratio of from 10% to 30%. With more HAP, Cd was more adsorbed. These results suggest that the higher HAP mass causes an increase of the ion exchange potential of the HAP sorbent. Equilibrium experimental results from Cd adsorption was fitted to Langmuir and Freundlich isotherm models. Cd adsorption on HAP sorbent were found to follow the Freundlich isotherm model well in the initial adsorbate concentration range. Also, Cd adsorption was a function of the HAP mass ratio ($x_1$), initial Cd concentration ($x_2$), and initial pH ($x_3$) from the application of the RSM. Statistical results showed the order of significance of the independent variables to be initial Cd concentration > HAP mass ratio > initial pH.

Nanotextured Si Solar Cells on Microtextured Pyramidal Surfaces by Silver-assisted Chemical Etching Process

  • Parida, Bhaskar;Choi, Jaeho;Palei, Srikanta;Kim, Keunjoo;Kwak, Seung Jong
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.4
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    • pp.212-220
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    • 2015
  • We investigated nanotextured Si solar cells using the silver-assisted chemical etching process. The nanotexturing process is very sensitive to the concentration of chemical etching solution. The high concentration process results in a nanowire formation for the nanosurfaces and causes severe surface damage to the top region of the micropyramids. These nanowires show excellent light absorption in photoreflectance spectra and radiative light emission in photoluminescence spectra. However, the low concentration process forms a nano-roughened surface and provides high minority carrier lifetimes. The nano-roughened surfaces of the samples show the improved electrical cell properties of quantum efficiency, conversion efficiency, and cell fill factor due to the reduction in the formation of the over-doped dead layer.

Effect of octadecylamine concentration on adsorption on carbon steel surface

  • Liu, Canshuai;Lin, Genxian;Sun, Yun;Lu, Jundong;Fang, Jun;Yu, Chun;Chi, Lisheng;Sun, Ke
    • Nuclear Engineering and Technology
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    • v.52 no.10
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    • pp.2394-2401
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    • 2020
  • Octadecylamine is an effective film-forming amine that protects carbon steel from corrosion. In the present study, the effect of octadecylamine concentration on adsorption on a carbon steel surface was investigated in anaerobic alkaline solution by using SEM/EDS, TEM and the Materials Studio simulation techniques. TEM morphology observation and EDS elemental detection determine the thicknesses of octadecylamine film on a carbon steel surface, which are confirmed by the in-situ electrochemical impedance spectroscopy measurement and resistance calculation. The Materials Studio simulation reveals the number of octadecylamine film layers at different concentrations. Results obtained in this study indicate that adsorption of octadecylamine film on carbon steel proceeds with the multi-layer adsorption mechanism.