• Title/Summary/Keyword: Surface concentration

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Effect of Maunfacturing Conditions of Substrate on Phosphatability (인삼염처리성에 미치는 소재 제조조건 영향)

  • 김형준
    • Journal of the Korean institute of surface engineering
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    • v.30 no.5
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    • pp.310-319
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    • 1997
  • The purpose of this study is to investigate the effect of the specific alloying elements in steel such as Cr, Ni and Cu, and surface roughness of substrate with two different FCS temperature zones in the CAL process on the phosphatability of the cold-rolled sheet used for the drum in order to improve the zinec phosphating property. Phosphatability is dependent of the surface oxide and roughness on the substrate and can be indirectly improved by increasing surface roughness of the steel sheet. Basically, in order to obtain the good phosphatability, the low concentration of the retained elements such as Cr, Ni and Cu among the steel alloy elements should be required. Phosphatability of substrate with high concentration instead of the retained elements and surface roughness, however, can be effectively improved instead of low FSC temperature.

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Surface Chemical Properties of Surface Active Aminocyclitol Derivatives (계면활성(界面活性) 아미노싸이클리톨 유도체(誘導體)의 계면화학적(界面化學的) 성질(性質))

  • Sohn, Joo-Hwan;Lee, Chang-Sup
    • Journal of the Korean Applied Science and Technology
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    • v.4 no.1
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    • pp.45-52
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    • 1987
  • Surface chemical properties including surface tension, Ross-Miles foaming power, foam stabilities, emulsifying properties, emulsion stabilities, effectiveness of dispersion, dispersion stabilites of the quaternary ammonium salt type deoxyaminoimositol derivatives such as sixteen kinds of dimethylafkyl-deoxyscyllo-inosityl- dimethylalkyl-2-deoxy-2-myo-inosityl-, dimethylakyl-2-deoxy-2-epi-inosityl- and dimethylalkyl-4-deoxy-4-myo-inosityl ammonium chlorides are tested. And critical micelle concentration of these compounds are estimated from the curves of surface tension and concentration. The experimental results show that the members of this class of compounds have necessary surface active properties to make them effective surfactants.

Effects of Sb doping on the Characteristis of $SnO_2$ Transparent Electrodes ($SnO_2$ 수용전극특성에 미치는 Sb첨가의 영향)

  • 이정한
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.13 no.3
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    • pp.16-21
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    • 1976
  • Transparent eloctroaes of polycrystalline till-oxide films doped with antimony are prepared on the substrate of microscopic cover g1ass by modified spray method and from SnCl4 Solution. Their electrical and optical properties are investigated in relation to the surface temperature of the substrate glass and to antimony concentration in the starting materials. The sheet.resiststrace of the film electrodes and transmittance for incandescent light depen on tile antimony concentration and surface temperature of substrates at the time of making films. The transmittance increases with decrease of sheet resistance of the film. The optimum sheet.resistance was obtianed in the case of the antimony concentration 0.6(%) approximately , and the max. transmittance was 93(%).

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Fabrication of compact surface structure by molar concentration on Sb-doped SnO2 transparent conducting films (안티몬 도핑된 주석 산화물 투명전도막의 몰 농도에 따른 치밀한 표면 구조 제조)

  • Bae, Ju-Won;Koo, Bon-Ryul;Ahn, Hyo-Jin
    • Journal of Powder Materials
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    • v.25 no.1
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    • pp.54-59
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    • 2018
  • Sb-doped $SnO_2$ (ATO) transparent conducting films are fabricated using horizontal ultrasonic spray pyrolysis deposition (HUSPD) to form uniform and compact film structures with homogeneously supplied precursor solution. To optimize the molar concentration and transparent conducting performance of the ATO films using HUSPD, we use precursor solutions of 0.15, 0.20, 0.25, and 0.30 M. As the molar concentration increases, the resultant ATO films exhibit more compact surface structures because of the larger crystallite sizes and higher ATO crystallinity because of the greater thickness from the accelerated growth of ATO. Thus, the ATO films prepared at 0.25 M have the best transparent conducting performance ($12.60{\pm}0.21{\Omega}/{\square}$ sheet resistance and 80.83% optical transmittance) and the highest figure-of-merit value ($9.44{\pm}0.17{\times}10^{-3}{\Omega}^{-1}$). The improvement in transparent conducting performance is attributed to the enhanced carrier concentration by the improved ATO crystallinity and Hall mobility with the compact surface structure and preferred (211) orientation, ascribed to the accelerated growth of ATO at the optimized molar concentration. Therefore, ATO films fabricated using HUSPD are transparent conducting film candidates for optoelectronic devices.

Distributions and Sources of Polycyclic Aromatic Hydrocarbons in the Tidal Flat Sediments from Incheon Coastal Area (인천연안 갯벌의 다환방향족탄화수소의 농도분포와 발생원 평가)

  • Park, Jung Hwan;Lee, Choong Dae;Kim, Jin Han
    • Journal of Wetlands Research
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    • v.15 no.4
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    • pp.441-451
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    • 2013
  • Samples for estimating concentrations of polycyclic aromatic hydrocargons(PAHs), total petroleum hydrocarbons(TPHs), and benzene-toluene-ethylbenzene-xylene(BTEX) were collected at the tidal flat sediments of 8 coastal sites in Incheon, at seventy-two sampling stations for the surface sediment and twenty-four stations for the sediment core, twice in the spring and fall in 2011. This study was performed to evaluate the distributions of seasonal and spatial concentrations of PAHs, TPHs, and BTEX in the tidal flat sediments. The source origin of PAHs were carried out. The total average concentration of PAHs in the tidal flat sediment was $95.62{\mu}g/kg$. The characteristic of PAHs concentration distributions was observed that the average concentration in the autumn was lower than that in the spring, and higher concentration in the sediment core than the surface sediment, and greater vertical concentration at the top rather than the bottom in the sediment core. The total average concentration of TPHs at all sampling sites was in the value of 46 mg/kg. The characteristic of the TPHs concentration distribution was observed that the average concentration in the fall was much higher than that in the spring, and higher concentration in the surface sediment than the sediment core. The possible source of PAHs inputs were mainly derived from both pyrogenic and petrogenic origin at the surface sediment at Janghwari site and the sediment cores of both Sorae and Okyeon sites, while the rest sites of study areas originated with pyrogenic combustion.

Property Changes of Ni-Co Film with the Change of Co Concentration in Sulfamate-chloride Bath (Sulfamate-Chloride Bath에서 Co 농도의 변화에 따른 Ni-Co 필름의 특성 변화)

  • Yoon, Pilgeun;Park, Deok-Yong
    • Journal of the Korean institute of surface engineering
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    • v.53 no.1
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    • pp.1-8
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    • 2020
  • Sulfamate-chloride baths were fabricated to study the properties of the electrodeposited Ni and NiCo thin films. The dependences of current efficiency, deposit composition of Ni and Co, residual stress, surface morphology and microstructure of electrodeposited Ni and NiCo thin films on CoCl2 concentration in sulfamate-chloride baths were investigated. The current efficiency was measured to be more than about 90%, independent of the changes of CoCl2 concentration in the baths. Residual stress of Ni and NiCo thin films was increased from about 45 to about 250 MPa with varying CoCl2 concentration from 0 to 0.210 M CoCl2 in the baths and then reached to a plateau, about 250 MPa above 0.420 M CoCl2 concentration. Nodular surface morphologies were observed at most CoCl2 concentrations in the baths except 0.210 M. NiCo thin film electrodeposited from the bath with 0.210 M CoCl2 concentration showed an acicular surface morphology. Pure Ni thin film consists of FCC(111), FCC(200), FCC(220), and FCC(311) peaks without any preferred orientation. On the other hand NiCo thin films make up of HCP(100), FCC(111), HCP(101), FCC(200), FCC(220) or HCP(110), FCC(311) or HCP(112) and FCC(222) peaks. It was revealed from the analysis of XRD result that FCC(111) peak at the NiCo thin film electrodeposited from the bath with 0.084 M CoCl2 concentration can be regarded as the preferred orientation. However the peak of the preferred orientation was changed to FCC(220) or HCP(110) above 0.084 M CoCl2 concentration in the baths. Then the intensity of FCC(220) or HCP(110) peak was gradually decreased with increasing CoCl2 concentration further. The crystalline size of pure Ni thin film was observed to be about 53 ㎛ and those of NiCo thin films were in the range of 35~45 ㎛.

The Correlation between Critical Micelle Concentration/Surface of Contact Lens Care Solutions Tension and Their Cleaning Efficacy (콘택트렌즈 관리용액의 미셀임계농도 및 표면장력과 세척력 간의 상관관계)

  • Byun, Hyun Young;Sung, Hyung Kyung;Moon, Joon Sik;Lee, A Young;Kwon, Se Young;Kim, So Ra;Park, Mijung
    • Journal of Korean Ophthalmic Optics Society
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    • v.19 no.1
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    • pp.23-30
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    • 2014
  • Purpose: The present study was aimed to figure out the correlation amongst the evaluation methods for critical micelle concentration, surface tension and protein cleaning efficacy to evaluate cleaning efficacy of contact lens care products. Methods: The critical micelle concentration of surfactants and the actual concentration of surfactants in contact lens care solutions were investigated by employing references published and related information. Surface tension of contact lens care solutions was measured by surface tension device at $25{\pm}1^{\circ}C$, and contact lenses made of lotrafilcon A, comfilcon A and balafilcon A were washed with contact lens care solutions after the incubation in artificial tears for 14 days and their cleaning efficacy was compared. Results: Among the 22 contact lens care products, 9 products provided the label of the concentration of surfactant, and 7 products showed higher concentration of surfactant than the critical micelle concentration reported in references. As a result of measuring surface tension, the surface tension of lens care products for soft contact lens was generally lower than other care products. When examined the removal effect of protein deposited on lens surface, it was known that the care products having lower surface tension showed higher protein removal efficiency. Conclusions: The surface tension is low when surfactant concentration in contact lens care solutions is high, and the removal effect of protein deposited is accordingly increased with the decrease of surface tension. Thus, these indicate the correlation amongst the evaluation methods for cleaning efficacy.

Effect of the Concentration of Cobalt Chloride Solution for the Preparation of Nano-Sized Cobalt Oxide Powder by Spray Pyrolysis Process

  • Yu, Jae Keun;Cha, Kwang Yong;Seo, Dong Jun;Han, Joung Su;Jang, Jae Bum;Lee, Yong Hwa;Kim, Dong Hee
    • Korean Journal of Materials Research
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    • v.24 no.6
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    • pp.277-284
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    • 2014
  • Using the spray pyrolysis process, nano-sized cobalt oxide powder with average particle size below 50 nm was prepared from cobalt chloride solution. The influences of the raw material solution on the properties of the powder formed examined. When the concentration of Co was low(20 g/L), the average particle size of the powder formed was roughly 20 nm, and the cohesion between these particles was significantly strong. When the concentration of Co increased to 100 g/L, the droplets nearly failed to exist in circular form and reflected a severely divided form. Furthermore, the average size of the particles formed was roughly 40 nm, and the particles reflected a polygonal form. When the solution was increased to nearly saturation level (Co at 200 g/L), the particle size distribution reflected significant unevenness due to severe droplet division while the surface also reflected significant unevenness. Furthermore, the average size of the particles formed increased significantly to 70 nm. The results of XRD analysis showed that the strength of the peaks reflected very little change when the concentration of Co was increased from 20 g/L to 50 g/L. Alternatively, when the concentration was increased to 100 g/L, the strength of the peaks increased compared to when the concentration was 50 g/L. However, when the concentration was increased to 200 g/L, the strength of the peaks failed to reflect significant change compared to when the concentration was 100 g/L. The specific surface area dramatically decreased by 30 % when the concentration of Co was increased from 20 g/L to 50 g/L. Alternatively, when the concentration of Co the solution increased to 100 g/L, the specific surface area decreased by roughly 15 %. Furthermore, when the concentration of Co was increased to nearly saturation level(200 g/L), the specific surface area decreased by roughly 35%.

Alteration of Leaf Surface Structures of Poplars under Elevated Air Temperature and Carbon Dioxide Concentration

  • Kim, Ki Woo;Oh, Chang Young;Lee, Jae-Cheon;Lee, Solji;Kim, Pan-Gi
    • Applied Microscopy
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    • v.43 no.3
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    • pp.110-116
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    • 2013
  • Effects of elevated air temperature and carbon dioxide ($CO_2$) concentration on the leaf surface structures were investigated in Liriodendron tulipifera (yellow poplar) and Populus tomentiglandulosa (Suwon poplar). Cuttings of the two tree species were exposed to elevated air temperatures at $27/22^{\circ}C$ (day/night) and $CO_2$ concentrations at 770/790 ppm for three months. The abaxial leaf surface of yellow poplar under an ambient condition ($22/17^{\circ}C$ and 380/400 ppm) had stomata and epicuticular waxes (transversely ridged rodlets). A prominent increase in the density of epicuticular waxes was found on the leaves under the elevated condition. Meanwhile, the abaxial leaf surface of Suwon poplar under an ambient condition was covered with long trichomes. The leaves under the elevated condition possessed a higher amount of long trichomes than those under the ambient condition. These results suggest that the two poplar species may change their leaf surface structures under the elevated air temperature and $CO_2$ concentration condition for acclimation of increased photosynthesis.

Investigation of the Interactions between Anionic Polymer and Nonionic Surfactant with Rheological and Surface Tension Measurements (유변학적 특성과 표면장력측정을 통한 음이온성 폴리머와 비이온성 계면활성제의 상호작용에 대한 연구)

  • Lee, Jung-No;Kim, Dong-Joo;Koh, Ha-Young
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.2
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    • pp.160-166
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    • 2007
  • The rheological properties and surface tensions of polymer solutions and polymer-surfactant mixed solutions were investigated. The polymers used in this study were a homopolymer of acrylic acid crosslinked with an allyl ether of pentaerythritol, an allyl ether of sucrose, or an allyl ether of propylene (CARBOMER), acylate/C10-30 alkyl acylate crosspolymer (AAAC), and ammonium acryloydimethyltaurate/VP copolymer (ADTV). A solubilizing agent PEG-40 hydrogenated castor oil (HCO-40) and an emulsifying agent polyoxyethylene (20) sorbitan monostearate (POLYSORBATE 60) made the micelles intervening between AAAC polymers, resulting in the increase of viscosity. However, HCO-40 made this behavior over the wider range of surfactant concentration than POLYSORBATE 60. From the view point of surface tensions in the same range of surfactant concentration, AAAC/HCO-40 solution showed the area of increasing surface tension with surfactant concentration in contrast to the AAAC/POLYSORBATE 60 solution showing no increasing area.