• Title/Summary/Keyword: Surface composition

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Study on the Production Methods and Conservation Treatment of the Gold Earrings Excavated from the Ancient Tombs in Seokchon-dong in Seoul (석촌동 고분군 출토 금제이식의 제작기법 연구 및 보존처리)

  • Kim, Yeseung;Jeong, Seri;Lee, Dahye;Jang, Minkyeong;Kim, Naeun;Yang, Seokjin
    • Conservation Science in Museum
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    • v.26
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    • pp.143-160
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    • 2021
  • The Seoul Baekje Museum has been conducting excavations at the Ancient Tomb Complex in Seokchon-dong, Seoul (Historic Site No. 243), known to be tombs of the royal family and the ruling class during the Hanseong period of the Baekje Kingdom. In this study, gold earrings that were revealed during the excavation underwent scientific analysis and conservation treatment. Stereo microscopy, SEM, X-ray imaging, CT, and XRF were applied in the analysis, and the characteristics, internal structure, and composition of the earrings as well as their production method were investigated. The results confirmed that the main hoops of the gilt-bronze earrings were made of copper cores gilt using mercury amalgamation. The findings also revealed that the hexahedron in the middle pendant was made by connecting small rings using molten gold powder, and the pendant sphere at the end was formed by soldering two hemispheres. As for the two thin-hoop earrings, they showed similar surface compositions but were made using different methods, with one made from a copper core wrapped with a gold plate and the other made by bending a gold rod. The gold content varied depending on the item and the place of measurement, but overall the earrings showed a relatively high gold content of approximately 19 to 21K. The purity of the golden earrings and the sophisticated manufacturing techniques applied indicate the high status of the buried person and of the tomb complex in Seokchong-dong.

Lunar Exploration Employing a Quadruped Robot on the Fault of the Rupes Recta for Investigating the Geological Formation History of the Mare Nubium (4족 보행 로봇을 활용한 달의 직선절벽(Rupes Recta)의 단층면 탐사를 통한 구름의 바다(Mare Nubium) 지역의 지질학적 형성 연구)

  • Hong, Ik-Seon;Yi, Yu;Ju, Gwanghyeok
    • Journal of Space Technology and Applications
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    • v.1 no.1
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    • pp.64-75
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    • 2021
  • On the moon as well as the earth, one of the easiest ways to understand geological formation history of any region is to observe the stratigraphy if it is available, the order in which the strata build up. By analyzing stratigraphy, it is possible to infer what geological events have occurred in the past. Mare Nubium also has an unique normal fault called Rupes Recta that shows stratigraphy. However, a rover moving with wheels is incompetent to explore the cliff since the Rupes Recta has an inclination of 10° - 30°. Therefore, a quadruped walking robot must be employed for stable expedition. To exploration a fault with a four-legged walking robot, it is necessary to design an expedition route by taking account of whether the stratigraphy is well displayed, whether the slope of the terrain is moderate, and whether there are obstacles and rough texture in the terrain based on the remote sensing data from the previous lunar missions. For the payloads required for fault surface exploration we propose an optical camera to grasp the actual appearance, a spectrometer to analyze the composition, and a drill to obtain samples that are not exposed outward.

Effect of Curing Solution and Pre-Rust Process on Rebar Corrosion in the Cement Composite (시멘트 복합체 내부 철근 부식에 양생 용액과 철근 사전 부식이 미치는 영향)

  • Du, Rujun;Jang, Indong;Lee, Hyerin;Yi, Chongku
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.2
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    • pp.1-8
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    • 2022
  • The corrosion of reinforcement is the main reason for the performance degradation of concrete structures. The pre-rusted parts of rebar in concrete structures are vulnerable to the corrosion, especially if the structure is exposed to wet or chlorinated environments. In this study, effects of different curing solution on corrosion behavior of the pre-rusted rebars in the cement composites were investigated. HCl(3%) and CaCl2(10%) solution were utilized to accelerate the pre-rust of the rebar, and each pre-rust condition rebar including reference (RE) were placed in mortar cylinder. Three kinds of samples then were cured in CaCl2 (3%) solution and tap water respectively for 120 days. Electrochemical polarization and half-cell potential measurement were used to monitor the influence of curing water on the corrosion behavior of pre-rusted steel bar in cement composite. The surface morphology and composition of corroded steel bar were analyzed by scanning electron microscope and energy dispersive X-ray diffraction. The results show that the corrosion rates of pre-rusted samples in both curing water are higher than that of non-pre-rusted samples. The corrosion rates of RE, CaCl2 and HCl pre-rusted samples in salt water were 8.14, 4.48, 13.81 times higher than those in tap water respectively, on the 120th day.

Degradation of Lead-based Pigments by Atmospheric Environment (납계열 안료의 대기환경에 따른 열화특성)

  • Park, Ju Hyun;Lee, Sun Myung;Kim, Myoung Nam
    • Economic and Environmental Geology
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    • v.55 no.3
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    • pp.281-293
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    • 2022
  • We examined degradation characteristics of lead based pigments(white lead, Red lead, Litharge) according to atmospheric environmet condition, for example atmospheric gas(CO2, NO2) and soluble salt. Painted samples not changed material compositions but were occured the color change(𝚫E 4~31) after exposed UV irradiation. All sample were not affected by CO2 gas not only color but chemical composition. However, samples were remakably changed color exposed NO2 gas and it was formed secondary product like as lead nitrate. Such as red lead and white lead samples' color difference were 𝚫E 2 and 𝚫 10 respectively and became dark, along with litharge became bright and color difference was 𝚫E 5 after react with NO2 gas. It confirm that NO2 was influential factor than CO2 in the case of same concentration. Furthermore salt spray test was taken to figure out soluble salt influence in fine dust. The result showed noticeable color change and secondary product was formed on samples' surface. The glue film peeled off or hole, and color changed around the secondary products. After salt spray, XRD pattern showed decrease peak intensity and lower crystalinity. As a result of salt spray test, white lead was formed new product litharge and litharge was formed litharge and minium. According to the results, influential atmospheric factors for conservation of paint pigments were UV, NO2, soluble salt, and litharge was most weakness throughout lead base pigments.

Material Characteristics and Making Techniques of Pottery by Type from the Oryang-dong Kiln Site in Naju, Korea (나주 오량동 요지 출토 토기의 기종별 재료 특성과 제작기법 연구)

  • Jin, Hong Ju;Jang, Sungyoon;Kim, Su Kyoung;Lee, Myeong Seong
    • Journal of Conservation Science
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    • v.36 no.6
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    • pp.440-455
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    • 2020
  • This study aims to examine the material characteristics of bowls and compare the making techniques of flat cup with cover and jar coffin from the Oryang-dong kiln site, Naju. Bowls, the most frequently excavated small pottery have similar material characteristics, including gray surface, fine-grained texture, and small-sized tempers such as quartz and feldspar, regardless of the excavation slopes. However, the firing temperature of the bowls mostly ranges from 950 to 1,100 ℃. It is estimated that the bowls had formalized making techniques, owing to the similar material composition and firing technique regardless of the excavation slope. The flat cups with cover have similar texture and mineral phases, except their poorly sorted inclusions. However, the jar coffins contain not only fine-grained minerals but also medium-grained quartz, feldspar, and biotite, showing a relatively wide range of firing temperatures. According to the geochemical results of pottery by type, it is assumed that chemical compositions are classified into two groups: small pottery(bowl and falt cup with cover) and jar coffins. In conclusion, small potteries such as bowls and flat cups with cover were made by removing the heavy minerals from raw materials, whereas jar coffins were made by adding medium-grained minerals to raw materials to maintain and support their structures, despite the same source materials. In addition, it is presumed that pottery making proceeded by selecting the source materials, preparing according to their use and controlling the firing temperature and environment.

Evaluation of Shielding Performance of 3D Printer Materials for High-energy Electron Radiation Therapy (고 에너지 전자선 치료를 위한 3D 프린터 물질의 차폐 성능평가)

  • Chang-Woo, Oh;Sang-Il, Bae;Young-Min, Moon;Hyun-Kyoung, Yang
    • Journal of the Korean Society of Radiology
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    • v.16 no.6
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    • pp.687-695
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    • 2022
  • To find a 3D printer material that can replace lead used as a shield for high-energy electron beam treatment, the shielding composites were simulated by using MCNP6 programs. The Percent Depth Dose (PDD), Flatness, and Symmetry of linear accelerators emitting high-energy electron beams were measured, and the linear accelerator was compared with MCNP6 after simulation, confirming that the source term between the actual measurement and simulation was consistent. By simulating the lead shield, the appropriate thickness of the lead shield capable of shielding 95% or more of the absorbed dose was selected. Based on the absorption dose data for lead shield with a thickness of 3 mm, the shielding performance was analyzed by simulating 1, 5, 10, and 15 mm thicknesses of ABS+W (10%), ABS+Bi (10%), and PLA+Fe (10%). Each prototype was manufactured with a 3D printer, measured and analyzed under the same conditions as in the simulation, and found that when ABS+W (10%) material was formed to have a thickness of at least 10mm, it had a shielding performance that could replace lead with a thickness of 3mm. The surface morphology and atomic composition of the ABS+W (10%) material were evaluated using a scanning electron microscope (SEM) and an energy dispersive X-ray spectrometer (EDS). From these results, it was confirmed that replacing the commercialized lead shield with ABS+W (10%) material not only produces a shielding effect such as lead, but also can be customized to patients using a 3D printer, which can be very useful for high-energy electron beam treatment.

Development of a Centrifugal Microreactor for the Generation of Multicompartment Alginate Hydrogel (다중 알긴산 입자제조를 위한 원심력 기반 미세유체 반응기 개발)

  • Ju-Eon, Jung;Kang, Song;Sung-Min, Kang
    • Applied Chemistry for Engineering
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    • v.34 no.1
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    • pp.23-29
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    • 2023
  • Microfluidic reactors have been made to achieve significant development for the generation of new functional materials to apply in a variety of fields. Over the last decade, microfluidic reactors have attracted attention as a user-friendly approach that is enabled to control physicochemical parameters such as size, shape, composition, and surface property. Here, we develop a centrifugal microfluidic reactor that can control the flow of fluid based on centrifugal force and generate multifunctional particles of various sizes and compositions. A centrifugal microfluidic reactor is fabricated by combining microneedles, micro- centrifuge tubes, and conical tubes, which are easily obtained in the laboratory. Depending on the experimental control param- eters, including centrifuge rotation speed, alginate concentration, calcium ion concentration, and distance from the needle to the calcium aqueous solution, this strategy not only enables the generation of size-controlled microparticles in a simple and reproducible manner but also achieves scalable production without the use of complicated skills or advanced equipment. Therefore, we believe that this simple strategy could serve as an on-demand platform for a wide range of industrial and academic applications, particularly for the development of advanced smart materials with new functionalities in biomedical engineering.

Building Information Modeling of Caves (CaveBIM) in Jeju Island at a Specific Site below a Road at Jaeamcheon Lava Tube and at a Broader Scale for Hallim Town (제주도 한림 재암천굴과 도로 교차구간의 CaveBIM 구축)

  • An, Joon-Sang;Kim, Wooram;Baek, Yong;Kim, Jin-Hwan;Lee, Jong-Hyun
    • The Journal of Engineering Geology
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    • v.32 no.4
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    • pp.449-466
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    • 2022
  • The establishment of a complete geological model that includes information about all the various components at a site (such as underground structures and the compositions of rock and soil underground space) is difficult, and geological modeling is a developing field. This study uses commercial software for the relatively easy composition of geological models. Our digital modeling process integrates a model of Jeju Island's 3D geological information, models of cave shapes, and information on the state of a road at the site's upper surface. Among the numerous natural caves that exist in Jeju Island, we studied the Jaeamcheon lava tube near Hallim town, and the selected site lies below a road. We developed a digital model by applying the principles of building information modeling (BIM) to the cave (CaveBIM). The digital model was compiled through gathering and integrating specific data: relevant processes include modeling the cave's shape using a laser scanner, 3D geological modeling using geological information and geophysical exploration data, and modeling the surrounding area using drones. This study developed a global-scale model of the Hallim region and a local-scale model of the Jaeamcheon cave. Cross-validation was performed when constructing the LSM, and the results were compared and analyzed.

Varietal Variation of Pigmentation and Some Nutritive Characteristics in Colored Rices (유색미 색도 및 영양특성의 품종간 변이)

  • Koh, Hee-Jong;Won, Yong-Jae;Wan, Geon-Wan;Heu, Mun-Hue
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.41 no.5
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    • pp.600-607
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    • 1996
  • Colored rices have been used for specific purposes by rice consumers due to the color and nutritive values empirically recognized. In this study, varietal variations of pigmentation and nutritive values were investigated in brown, red, purple and black rices. Pigments were localized in seed coat to pericarp region in all varieties tested. Pigments were slightly residued on the surface of milled rice. Anthocyanin content per g brown rice was 1.63~17.62 $\mu\textrm{g}$ in brown and reddish-brown rices, 3.56~11.10 $\mu\textrm{g}$ in red rices, 28.11~401.22 $\mu\textrm{g}$ in purple rices, and 3, 665.98 $\mu\textrm{g}$ in a black rice. A vatiety DZ 78 showed the highest protein content out of colored rices analyzed for protein. Normal and colored rices were found to have the similiar composition of amino acids, and so was in between brown rice without embryo and milled rice. Colored rices, L $K_1$B-4-12-1-1 and DK 1, showed higher content of vitamin $B_1$ compared with Hwacheongbyeo, a check variety of no specific color, and L $K_1$B-2-1-1 and L $K_1$B-4-12-1-1 showed much higher content of vitamin B2 in brown rice without embryo. Cation contents such as $K^{+}$, $Mg^{2+}$, $Ca^{2+}$ and F $e^{2+}$ were significantly increased in most of the colored rices tested implying that the increase might be associated with color pigmentation.ation.

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Effect of Particle Size of Granular Nitrofen (TOK G) on the Leaf Burning in Rice Plants (Nitrofen입제(TOK G)의 입도가 수도의 약반형성에 미치는 영향)

  • Park, J.K.;Cho, Y.W.;Kwon, Y.W.
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.22 no.2
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    • pp.121-127
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    • 1977
  • Leaf burning due to nitrofenapplication was characterized as brown color spot appearing on the leaf sheath and blade. The spots predominantly appeared around 5-7 cm high above soil surface regardless of different particle size, formulation, application method, or water level. Magnitude and frequency of burn spots increased somewhat as the granular size gets finer, by higher water level, or in transplanted rice compared to directly sown rice when applied at 7 leaf-stage, but there was no indication of increase in leaf burning due to clinging of floating dust to rice plant. When collections from local distributor's stock of TOK 7G, a granular formulation of nitrofen, were analyzed for particle size composition, 98.9% by weight ranged between 9 to 35 meshes, and only about 0.08% by weight was of particles finer than 100 mesh.

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