• Title/Summary/Keyword: Surface coating layer

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A Study on the Functional Electroless Ni Plating for Controled Morphology on the CBN Powder (CBN분말상에 석출형상 제어를 위한 무전해 기능성 니켈합금도금에 관한 연구)

  • Chu, H.S.;Kim, D.K.
    • Journal of the Korean institute of surface engineering
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    • v.41 no.6
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    • pp.312-324
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    • 2008
  • In this study, the functional property as a super abrasive material was secured for CBN powder by the electroless Ni-P plating on the surface of the particle. The plating solution has been prepared to control the surface morphology by regulating surfactants and process conditions. The effects of processing parameters on the surface morphology of CBN powder was discussed. The results are summarized as follows; A stable plating tendency was achieved from 1 hour after quantitatively dropping reducing agent. It was observed that more than 50% of the weight gain was obtained by Ni-P coating on the surface of CBN super abrasive powder. The morphology of the Ni-P coating layer is consisted of botryoidal and spiky type and it could be controlled by regulating processing parameters. Superior characteristic in terms of surface morphology was found in the nonionic surfactant XL-80N. It was found that XL-80N considerably decreased surface tension of CBN powder and Ni-P alloy surface then enhance wettability as well as plating rate. Metal coated CBN powder as a raw material of resin bond wheel has been developed through this investigation.

Hardness and Corrosion Resistance of Surface Composites Fabricated with Fe-based Metamorphic Powders by High-energy Electron Beam Irradiation

  • Nam, Dukhyun;Lee, Kyuhong;Lee, Sunghak;Young, Kyoo
    • Corrosion Science and Technology
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    • v.7 no.6
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    • pp.301-306
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    • 2008
  • Surface composite layers of 1.9~2.9 mm in thickness were fabricated by depositing metamorphic powders on a carbon steel substrate and by irradiating with a high-energy electron beam. In the surface composite layers, 48~64 vol.% of $Cr_{2}B$ or $Cr_{1.65}Fe_{0.35}B_{0.96}$ borides were densely precipitated in the austenite or martensite matrix. These hard borides improved the hardness of the surface composite layer. According to the otentiodynamic polarization test results of the surface composites, coatings, STS304 stainless steel, and carbon steel substrate, the corrosion potential of the surface composite fabricated with 'C+' powders was highest, and its corrosion current density was lowest, while its pitting potential was similar to that of the STS304 steel. This indicated that the overall corrosion resistance of the surface composite fabricated with 'C+' powders was the best among the tested materials. Austenite and martensite phases of the surface composites and coatings was selectively corroded, while borides were retained inside pits. In the coating fabricated with 'C+' powders, the localized corrosion additionally occurred along splat boundaries, and thus the corrosion resistance of the coating was worse than that of the surface composite.

Tribological Characteristics of TiC, TiN and TiC/TiN Coatings (TiC, TiN과 TiC/TiN 코팅의 트라이볼로지 특성)

  • Jeon, Chan Yeal
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.3
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    • pp.1253-1258
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    • 2014
  • The tribological properties of TiC, TiN and TiC/TiN coatings on steels prepared by the cathodic-arc (CA) ion plating technique were investigated. Experiments were carried out on a tribo-test machine using a Falex journal V block system. The friction and wear characteristics of the coatings were determined by varying the applied load and sliding speed. The TiC, TiN and TiC/TiN coatings markedly increased the tribological characteristics of the surface. As far as a single layer coating was concerned, TiN goes better results than TiC. However, the TiC/TiN multilayer coating performed better than either single layer coating. The major factor in the improved performance of the multilayer coating was the role of TiC in improving the adhesion between the external TiN layer and the substrate steel.

Anti-Proliferative Effect of Tetraphenylporphine (TPP) as an Iron Chelator on Vascular Smooth Muscle Cells and its Release Profiles from Polymer Coating Layer (철 킬레이터로서의 tetraphenylporphine의 혈관평활근세포의 성장억제효과와 고분자 코팅막으로부터의 방출 특성)

  • Park, Min-Hee;Kang, Soo-Yong;Park, Hyun-Jeong;Seo, Jin-Seon;Park, Young-A;Kim, Ji-Eun;Kim, Yang-Geun;Whang, Bae-Geon;Munkhjargal, Odonchimeg;Shim, Young-Key;Kho, Weon-Gyu;Lee, Woo-Kyoung
    • Journal of Pharmaceutical Investigation
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    • v.38 no.2
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    • pp.93-98
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    • 2008
  • The drug-eluting stent (DES) implantation is a widely acceptable treatment for coronary heart disease. It was reported that iron chelator had anti-proliferative effect on human vascular smooth muscle cells (HA-VSMCs). In this study, tetraphenylporphine (TPP) was selected as an iron chelator and drug for DES. MTT assay showed that TPP had antiproliferative effect on HA-VSMCs. TPP and polycaprolactone (PCL) were coated onto stainless steel plate using a spraycoating method. From the surface morphology examination of the coated plate by SEM, smooth polymer coating layer could be observed. The thickness of coating layer could be controlled by changing repeating time of coating. From in vitro release test, sustained release of TPP was observed from plate during two weeks. Thus, TPP as iron chelator can be used as drug for stent coating because of its antiproliferative effect and sustain release profile.

Improved Coating Process for Enhanced Wear Resistance of CrAl Coated Claddings for Accident Tolerant Fuel (공정 개선에 따른 사고저항성 CrAl 코팅 피복관의 내마모성 향상)

  • Kim, Sung Eun;Lee, Young-Ho;Kim, Dae Ho;Kim, Hyun-Gil
    • Tribology and Lubricants
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    • v.38 no.4
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    • pp.136-142
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    • 2022
  • This paper investigates the enhanced wear performance of a CrAl coated accident tolerant fuel (ATF) cladding. In the wake of the Fukushima accident, extensive research on ATF with respect to improving the oxidation resistance of cladding materials is ongoing. Since coated Zr claddings can be applied without major changes to the criteria for reactor core design, many researchers are studying coatings for claddings. To improve the quality of the CrAl coating layer, optimization of the manufacturing process is imperative. This study employs arc ion plating to obtain improved CrAl coated claddings using CrAl binary alloy targets through an improved coating method. Surface roughness and adhesion are improved, and droplets are reduced. Furthermore, the coated layer has a dense and fine microstructure. In scratch tests, all the tested CrAl coated claddings exhibit a superior resistance compared to the Zr cladding. In a fretting wear test, the wear volume of the CrAl coated claddings is smaller compared to the Zr cladding. Furthermore, the coated cladding manufactured through the improved process exhibits better wear resistance than other CrAl coated claddings. Based on these results, we suggest that fine microstructure is attributed to a mechanically and microstructurally robust CrAl coating layer, which enhances wear resistance.

Technological Trends in a local anodization (국부적 양극산화 기술 동향)

  • Kwang-Mo Kang;Sumin Choi;Yoon-Chae Nah
    • Journal of the Korean institute of surface engineering
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    • v.56 no.2
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    • pp.115-124
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    • 2023
  • Anodization is an electrochemical process that electrochemically converts a metal surface into an oxide layer, resulting in enhanced corrosion resistance, wear resistance, and improved aesthetic appearance. Local anodization, also known as selective anodization, is a modified process that enables specific regions or patterns on the metal surface to undergo anodization instead of the entire surface. Several methods have been attempted to produce oxide layers via localized anodic oxidation, such as using a mask or pre-patterned substrate. However, these methods are often intricate, time-consuming, and costly. Conversely, the direct writing or patterning approach is a more straightforward and efficient way to fabricate the oxide layers. This review paper intends to enhance our comprehension of local anodization and its potential applications in various fields, including the development of nanotechnologies. The application of anodization is promising in surface engineering, where the anodic oxide layer serves as a protective coating for metals or modifies the surface properties of materials. Furthermore, anodic oxidation can create micro- and nano-scale patterns on metal surfaces. Overall, the development of efficient and cost-effective anodic oxidation methods is essential for the advancement of various industries and technologies.

Study on Application of Urethane Materials for Hardening of Metal Artifacts (금속유물 강화처리를 위한 우레탄 수지의 적용성 연구)

  • Lee, Ho-Yeon;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.27 no.4
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    • pp.415-420
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    • 2011
  • Urethane coating agent was made up in order to prevent corrosion on metal relics. This urethane coating agent was designed to solve problems linked to gloss and discoloration caused by existing acrylic coating agent which is mainly applied to metal relics. For the purpose, the urethane coating agent was made up which has lower gloss and slight color change. This coating agent formed thinner coating layer with excellent adhesion compared to the existing agent and has outstanding resistance to the surface oxidization of metal relics and water repellent on the surface. In addition, the agent is considered a stable coating agent replacing current acrylic coating agent with showing easy dissolution in organic solvents such as acetone, toluene and xylene with excellent result in reversible reaction.

Formation of Multi-Component Boride Coatings Containing V and/or Cr and Evaluation of Their Properties (바나듐 및 크롬을 포함하는 다 성분 Boride 코팅의 생성 및 특성 평가)

  • Lee, Euiyeol;Yoon, Sanghyun;Kim, Jongha
    • Journal of the Korean institute of surface engineering
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    • v.49 no.2
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    • pp.211-217
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    • 2016
  • Boride coating applied on steam turbine parts of power plants has provided good particle erosion resistance under temperature of $550^{\circ}C$, but it isn't able to protect the parts effectively any more in ultra super critical (USC) steam turbine which is being operated up to temperature of $650^{\circ}C$. To ensure stable durability for USC steam turbine parts, an alternative coating replacing boride coating should be developed. In this study, multi-component boride coatings containing elements such as chromium (Cr) and vanadium (V) were formed on base metal (B50A365B) using thermochemical treatment method called by pack cementation. The thermochemical treatments involve consecutive diffusion of boron(B) and Cr or/and V using pack powders containing diffusion element sources, activators and diluents. The top layer of Cr-boride coating is primarily consisted of $Cr_2B_3$ and $Cr_5B_3$, while that of V-boride coating is mostly consisted of $VB_2$ and $V_2B_3$. The (Cr,V)-boride coating is consisted of $Cr_2B_3$, $Cr_5B_3$ and $V_2B_3$ mostly. The top surfaces of 3 multi-component boride coatings show hardness of $3200-3400H_v$, which is much higher than that of boride, about $1600-2000H_v$. In 5 wt.% NaCl solution immersion tests, the multi-component boride coatings show much better corrosion resistance than boride coating.

Thermo mechanical analysis of a ceramic coated piston used in a diesel engine

  • Buyukkaya, Ekrem;Cerit, Muhammet;Coban, Mehmet
    • Steel and Composite Structures
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    • v.21 no.2
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    • pp.429-442
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    • 2016
  • The aim of this paper is to determine temperature and stress distributions in a ceramic based on Partially Stabilized Zirconia coated steel piston crown by using plasma spraying for improving performance of a marine diesel engine. Effects of coating constituent and thickness on temperature and stress distributions were investigated including comparisons with results from an uncoated piston by means of finite element method namely ANSYS. Temperature developed at the coated surface is significantly higher than that of the uncoated piston. The maximum stress components occur between bond coat and adjacent ceramic layer. Provided that coating thickness is constant as 0.5 mm, when numbers of layers increase, magnitude of the normal stress decrease about 34.1% on the base metal surface according to uncoated piston, but the base metal surface temperature of the steel piston increase about 13.1%.

Preparation and Photo Conducting Characteristics of Plasma Polymerized Organic Photorecepter (플라즈마 중합법에 의한 유기 감광체 박막의 제조와 광전도 특성)

  • 박구범
    • Journal of the Korean Institute of Telematics and Electronics T
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    • v.36T no.3
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    • pp.19-25
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    • 1999
  • The photoreceptor films with double layer structure were prepared by the plasma polymerization and the dip-coating method. The blocking layer was coated with A1$_2$O$_3$ on the Al substrate and the charge generation layer was formed by H$_2$ phthalocyanine (H$_2$Pc). Poly 9-Vinylcarbazole was used as a charge transport layer. H$_2$Pc film prepared by the vacuum evaporation had absorption peaks on 613.6[nm] and 694.8[nm], and H$_2$Pc film prepared by the plasma polymerization had a dull peaks between 600 and 700[nm]. The surface potential of PVCz increased with increasing the applied voltage and the thickness of PVCz. The dark decay characteristic, the light decay time and the residual time increased with increasing the thickness of PVCz. The surface charge of PVCz of 15[${\mu}{\textrm}{m}$] thickness was 134[nc/$\textrm{cm}^2$] at the surface potential of -600[V] and the charge generation efficiency of H$_2$Pc was 0.034.

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