• Title/Summary/Keyword: Surface characteristic

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Structural, Optical and Photoconductive Properties of Chemically Deposited Nanocrystalline CdS Thin Films

  • Park, Wug-Dong
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.4
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    • pp.164-168
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    • 2011
  • Nanocrystalline cadmium sulphide (CdS) thin films were prepared using chemical bath deposition (CBD), and the structural, optical and photoconductive properties were investigated. The crystal structure of CdS thin film was studied by X-ray diffraction. The crystallite size, dislocation density and lattice constant of CBD CdS thin films were investigated. The dislocation density of CdS thin films initially decreases with increasing film thickness, and it is nearly constant over the thickness of 2,500 ${\AA}$. The dislocation density decreases with increasing the crystallite size. The Urbach energies of CdS thin films are obtained by fitting the optical absorption coefficient. The optical band gap of CdS thin films increases and finally saturates with increasing the lattice constant. The Urbach energy and optical band gap of the 2,900 A-thick CdS thin film prepared for 60 minutes are 0.24 eV and 2.83 eV, respectively. The activation energies of the 2,900 ${\AA}$-thick CdS thin film at low and high temperature regions were 14 meV and 31 meV, respectively. It is considered that these activation energies correspond to donor levels associated with shallow traps or surface states of CdS thin film. Also, the value of ${\gamma}$ was obtained from the light transfer characteristic of CdS thin film. The value of ${\gamma}$ for the 2,900 A-thick CdS thin film was 1 at 10 V, and it saturates with increasing the applied voltage.

The importance of nose, eye, and In-dang(印堂) region in inspecting color diagnosis (망진(望診) 찰색(察色)에 있어서 비(鼻), 안(眼), 인당(印堂)의 중요성)

  • Chang, Jun-Young;Kang, Jung-Soo;Kim, Byoung-Soo
    • Journal of Haehwa Medicine
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    • v.19 no.1
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    • pp.87-98
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    • 2010
  • There are four kinds of diagnosis methods in oriental medicine, and viewing diagnosis(望診) is the most important method among them. There are two ways in viewing diagnosis. These are viewing shape(觀形) and inspecting color(察色). Viewing shape diagnosis includes observation on geometric curve that is made by prominence of bones or lump of flesh, and examination on symmetric disparity and balance of vertical length among three vertical section of face. Inspecting color is literally inspecting several specified region of face. By Viewing shape, we can learn about characteristic physical mechanism of individuals, and basic disposition of reaction from inside and outside infinite stimulations. On the other hand, by inspecting color, we can estimate the very present pathologic and physiologic status of the patient. the estimation is based on principle that inside body changes reveal some reflections on facial skin surface. When you diagnosis patients with inspecting color method, It is important to distinguish color delicately, and to know where to see and what to know from it. The most important and frequently mentioned regions are myong-dang(明堂), eyes(眼) and In-dang(印堂). Myong-dang(明堂) indicates nose. In-dang(印堂) indicates the space between eyebrows. Unlike myong-dang(印堂) and eyes, In-dang(印堂) is occasionally treated as a trivial region then others. But, from research on classical books of facial examination and consideration of it's locational meanings, we've learned In-dang(印堂) is very important in viewing diagnosis, because this region is crossing of the other two regions and this fact means this region expresses the spiritual status as well as physical status in one region.

A Study on Dyeing of Gray Tone Utilizing Green Tea (녹차에 의한 회색계열 염색에 관한 연구)

  • Shin, Nam-Hee;Kim, Sung-Yeon;Cho, Kuyung-Rae
    • Fashion & Textile Research Journal
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    • v.8 no.3
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    • pp.343-348
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    • 2006
  • This study aims to attain gray tone dyed goods by using tannin that is contained in green tea. Tannin is given general name of polyphenol, which has a characteristic that bonds with protein and it is used for food preservative that protects against bacteria, as well as its purpose of black tone dye for silk treatment that has been processed since its early ages. In particular, as tannin reacts with all kinds of metallic mordant and changes to various colors, when tannin acid is combined with iron, it becomes tannin steel and produces gray tone color. Tannin that is contained in green tea is condensed tannins and its structure does not hydrolyze, thus having flavan type structure. In order to find the suitable condition for processing tannin, UV-Vis part absorption spectrum of green tea tannin, dye ability based on temperature and time, reflection rate based on concentration, color changes based on acid treatment and alkali treatment, changes on surface based on concentration or metal mordant condition, and lightfastness were measured. Maximum absorption wavelength (${\lambda}_{max}$) of green tea tannin was at around 273nm, while strong absorption was also observed at below 350 nm. Dye ability of green tea tannin is done more easily on silk rather than cellulose fibers such as cotton, while the optimum condition for dyeing was observed to be at $60^{\circ}C$, for 20 minutes. As a result of acid treatment, the color of dye material consisted highly of gray tones and showed overall gray tone with the combined color of yellow and red after the alkali treatment. While it was observed that as dye concentration and metal mordant concentration increased, the color changed at counter-clockwise direction on the Y-scale of Munsell's scale of colors. Additionally, lightfastness was more on a normal fading.

Experimental Study on Load Transfer Characteristic by Adjacent Slope Excavation in a Jointed Rock Mass (절리암반에서 근접 사면굴착에 의한 하중전이특성에 대한 실험적 연구)

  • Lee, Jin-Wook;Lee, Sang-Duk
    • Journal of the Korean Society for Railway
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    • v.12 no.2
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    • pp.321-328
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    • 2009
  • A optimal reinforcement in the joint rock slope excavation adjacent to an existing tunnel would be influenced by excavation distance from the tunnel, slope angel, and joint conditions but has been empirically determined so far. In this study, large scale model tests were conducted to find out the relationship between load translation on the excavation surface and bebavior of the tunnel according to excavation steps of the jointed rock slope. Consequently, two main parameters, joint dip and sloped angle were investigated in those model tests. From the test results, it was found that tunnel deformation was the largest one when the excavation of joints located closer to the tunnel crown or invert. Stability of the slope and the tunnel were varied in a certain excavation stage related to the angle of slope. In the future, based on results of this study the reinforcement method for the tunnel and slope safety in a jointed rock mass will be demonstrated.

Polyoxyethylene Tocopheryl Ethers; A Series of Novel Surfactants from Tocopherol for Functional Cosmetics (토코페롤에서 유도된 기능성 화장품용의 새로운 계면 활성제)

  • 김영대;김창규
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.18 no.1
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    • pp.1-41
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    • 1992
  • A new and unique class of nonionic surfactants was synthesized by reacting biological a-tocopherol with ethylene oxide for functional cosmetics. The structures were confirmed by Hl-UMR, FT-lR, TLC and elemental analysis. POV and conjugated diene value study for EPO showed POE(n)TE had antioxidative effect similar to tocopheryl acetate Protective effect on cell membrane in photohemolysis of POE(5)TE, POE(10)TE and POE(18)TE were slightly lower than tocopherol but higher than nonoxynol-12, and POE(10)TE had UV absorption power comparable with tocopherol and homosalate. Biological activity of the hydrophobic group of the new surfactants make them unique and different from those of conventional nonionic surfactants Systematic safety evaluations of POE(n)TEs on the skin and eye proved that they are as safe as tocopherol. The results of physicochemical study showed POE(10)TE had the lowest CMC value, POE(18)TE had the maximum surface tension reduction and the highest foam volume and POE(n)TEs had various HLB values by the degree of ethoxylation. The test resul Is of technological and practical applications of these surfactants for cosmetics showed some POE(n)TEs were superior to conventional surfactants. POE(5)TE in W/O emulsions, POE(10)TE and POE(12)TE in O/W emulsions, POE(12)TE in dispersions, POE(18)TE in solubilizations and POE(50)TE in gelations were shown to be excellent which was considered due to the structural characteristic and formation of liquid crystals of POE(n)TEs. By the development and applications of these excel lent multi-functional surfactants, innovative functional cosmetics were successfully formulated.

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Development of Plasma Assisted ALD equipment and Electrical Characteristic of TaN thin film deposited PAALD method (Plasma Assisted ALD 장비 계발과 PAALD법으로 증착 된 TaN 박막의 전기적 특성)

  • Do Kwan Woo;Kim Kyoung Min;Yang Chung Mo;Park Seong Guen;Na Kyoung Il;Lee Jung Hee;Lee Jong Hyun
    • Journal of the Semiconductor & Display Technology
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    • v.4 no.2 s.11
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    • pp.39-43
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    • 2005
  • In the study, in order to deposit TaN thin film for diffusion barrier and bottom electrode we made the Plasma Assisted ALD equipment and confirmed the electrical characteristics of TaN thin films grown PAALD method. Plasma Assisted ALD equipment depositing TaN thin film using PEMAT(pentakis(ethylmethlyamino) tantalum) precursor and NH3 reaction gas is shown that TaN thin film deposited high density and amorphous phase with XRD measurement. The degree of diffusion and reaction taking place in Cu/TaN (deposited using 150W PAALD)/$SiO_{2}$/Si systems with increasing annealing temperature was estimated for MOS capacitor property and the $SiO_{2}$, (600${\AA}$)/Si system surface analysis by C-V measurement and secondary ion material spectrometer (SIMS) after Cu/TaN/$SiO_{2}$ (400 ${\AA}$) layer etching. TaN thin film deposited PAALD method diffusion barrier have a good diffusion barrier property up to 500$^{\circ}C$.

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Estimation of Illuminant Chromaticity from Single Color Image Using Perceived Illumination and Highlight (인지조명과 광휘점을 이용한 단일 색 영상으로부터의 조명색 추정)

  • Kim, Jeong-Yeop;Ha, Yeong-Ho
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.38 no.3
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    • pp.292-303
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    • 2001
  • Object color can be determined by the characteristic of scene illuminant and surface. In this paper, perceived illumination effect is extended and with the highlight analysis, hybrid approach is proposed to estimate the illuminant chromaticity. The perceived illumination approach provides a stable candidate range for the estimation of illuminant chromaticity, however, the accuracy is slightly degraded depending on the image contents. The highlight approach does not depend on the image contents and provides an accurate solution of the scene illuminant chromaticity, however, it is difficult to determine the final solution among many cross-points. These two approaches are in effect mutually compensating. The solution from perceived illumination can be used as a starting point or as base information for the highlight approach to get the final solution.

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Frontier Orbitals of Fifteen C20H17(OH)3 Regioisomers: Hybrid DFT B3LYP Study

  • Lee, Seol;Lee, Ji Young;Lee, Kee Hag
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2403-2407
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    • 2013
  • The hybrid density-functional (B3LYP/6-31G(d,p)) method was used to analyze the substitution effect on the $C_{20}H_{20}$ cage based on calculation of the frontier orbitals of fifteen $C_{20}H_{17}(OH)_3$ derivatives. All substitution products were geometrically optimized without constraints and confirmed by frequency analysis. The results suggest that the cis-1 cis-1 cis-2 regioisomer is the most stable isomer, which implies that hydrogen bonding exerts a stronger effect on the relative energies of the trihydroxide than long-range interactions. Thus, this supports the experimental result in which the bisvicinal tetrol was of particular preparative-synthetic interest. While the LUMO of each of the $C_{20}H_{17}(OH)_3$ regioisomers was equivalently delocalized over the void within the cage, the HOMO was limitedly delocalized on substituents and carbons in close proximity to the substituents. The characteristics of the HOMO of each of the regioisomers vary based on the substitution sites. This indicates that the 15 regioisomers of each $C_{20}H_{20}$ trisubstituted derivative might undergo an entirely different set of characteristic chemical reactions with electrophilic reagents. The results further suggest that the penta-substituted OH groups on the surface of the fullerene cage are more likely to be localized on a pentagon than to be homogeneously delocalized.

RETF 액체산소 공급설비 및 엔진 수류시험

  • Han, Yeoung-Min;Cho, Nam-Kyung;Kim, Seung-Han;Chung, Yong-Ghap;Park, Sung-Jin;Lee, Kwang-Jin;Kim, Young-Han;Moon, Il-Yoon
    • Aerospace Engineering and Technology
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    • v.1 no.2
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    • pp.123-131
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    • 2002
  • In this paper, characteristics of cryogenic liquid oxygen was examined during cold flow of KSR-III main engine at each stage. The effect of venting was examined at the stage of cooling and at the pressurization stage, the interaction between nitrogen gas and liquid oxygen was also examined. The characteristic of liquid oxygen in the engine manifold was analyzed. The results showed that venting was the primary role at the cooling process and the interaction of nitrogen gas and liquid oxygen in the run tank is limited at the surface area. With the sampling rate of 1KHz static and dynamic pressure were measured in the rocket engine manifold and in the LOX supply equipment. 32.5mm and 38mm orifice were installed for the tests and pressure condition of liquid oxygen was 23Bar, 29Bar, 41Bar. Increase of orifice diameter and decrease of supply pressure reduced the perturbation of pressure in engine manifold.

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Finite Element Analysis for Acoustic Characteristics of Piezoelectric Underwater Acoustic Sensors (압전 수중음향센서 음향특성의 유한요소해석)

  • 김재환;손선봉;조철희;조치영
    • The Journal of the Acoustical Society of Korea
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    • v.20 no.1
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    • pp.68-76
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    • 2001
  • Sonar is the system that detects objects and finds their location in water by using the echo ranging technique. In order to have excellent performance in variable environment, acoustic characteristics of this system must be analyzed accurately. In this paper, based on the finite element analysis, modeling and analysis of acoustic characteristics of underwater acoustic sensors are preformed. Couplings between piezoelectric and elastic materials, and fluid and structure systems associated with the modeling of piezoelectric underwater acoustic sensors are formulated. In the finite element modeling of unbounded acoustic fluid, IWEE (Infinite Eave Envelop Element) is adopted to take into account the infinite domain. When an incidence wave excites the surface of Tonpilz underwater acoustic sensor, the scattered wave on the sensor is founded by satisfying the radiation condition at the artificial boundary approximately. Based on this scattering analysis, the electrical response of the underwater acoustic sensor under incidence, so called RVS (Receiving Voltage Signal) is founded accurately. This will devote to design Sonar systems accurately.

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