• 제목/요약/키워드: Surface characteristic

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Simple and Clean Transfer Method for Intrinsic Property of Graphene

  • Choe, Sun-Hyeong;Lee, Jae-Hyeon;;Kim, Byeong-Seong;Choe, Yun-Jeong;Hwang, Jong-Seung;Hwang, Seong-U;Hwang, Dong-Mok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.659-659
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    • 2013
  • Recently, graphene has been intensively studied due to the fascinating physical, chemical and electrical properties. It shows high carrier mobility, high current density, and high thermal conductivity compare with conventional semiconductor materials even it has single atomic thickness. Especially, since graphene has fantastic electrical properties many researchers are believed that graphene will be replacing Si based technology. In order to realize it, we need to prepare the large and uniform graphene. Chemical vapor deposition (CVD) method is the most promising technique for synthesizing large and uniform graphene. Unfortunately, CVD method requires transfer process from metal catalyst. In transfer process, supporting polymer film (Such as poly (methyl methacrylate)) is widely used for protecting graphene. After transfer process, polymer layer is removed by organic solvents. However, it is impossible to remove it completely. These organic residues on graphene surface induce quality degradation of graphene since it disturbs movement of electrons. Thus, in order to get an intrinsic property of graphene completely remove of the organic residues is the most important. Here, we introduce modified wet graphene transfer method without PMMA. First of all, we grow the graphene from Cu foil using CVD method. And then, we deposited several metal films on graphene for transfer layer instead of PMMA. Finally, we fabricate graphene FET devices. Our approaches show low defect density and non-organic residues in comparison with PMMA coated graphene through Raman spectroscopy, SEM and AFM. In addition, clean graphene FET shows intrinsic electrical characteristic and high carrier mobility.

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Fabrication and Characterization of Triboelectric Energy Harvester

  • Sung, Tae-Hoon;Lee, Jun Young;Yeo, Jong-Souk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.631-631
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    • 2013
  • Battery has major drawbacks including its size and life expectancy, and environmental problem. As an alternative, energy harvesting is emerging as a potential solution to replace battery along with more energy-efficient IT devices. The idea of harnessing energy from our living environment is sustainable, semi-permanent, and eco-friendly. Also, unlike battery, energy harvester does not require much space to store energy. Therefore, energy harvesting can provide a better source of power for small, portable, and wireless devices. Among various ways of harvesting energy from our surroundings, triboelectricity is chosen due to its potential to be miniaturized, and efficient. Triboelectric effect occurs as two different materials with different polarity of charge separation come into contact through friction, and then become separated so that electric potential difference is achieved. In this research, such characteristic of triboelectricity is used as a way to convert ambient mechanical energy into electric energy.Series of recent researches have shown promising results that the triboelectric energy harvester can be simple and cost effective. However, sufficient electricity level required to operate mobile devices has not yet been achieved.In this research, our group focuses on the design and optimization of triboelectric energy harvesting device to enhance its output. By using maskless lithography to pattern Kapton film and silicon substrate, which is used as a mold for PDMS thin layer, and sputtering metal electrodes on each side, we fabricate and demonstrate different designs of triboelectric energy harvester that utilizes the contact electrification between a polymer thin film and a metal thin foil. In order to achieve optimized result, the output voltage and current are measured under diverse conditions, which include different surface structure and pattern, material, and the gap between layers.

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Relationship between the East-Asian Cold Anomalies in Winter of 2010/11 and Blocking (2010/11년 겨울의 동아시아 한랭 아노말리와 블로킹의 연관성)

  • Choi, Wookap;Kim, Young-Ah
    • Atmosphere
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    • v.26 no.1
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    • pp.193-201
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    • 2016
  • An anomalous cold-weather period occurred during January 2011 in East Asia, and this study investigates the event by focusing on the blocking phenomena formed at Northeastern Asia. The area of cold weather is determined to represent the characteristic features of abnormal cold temperature. The 2010/11 winter is divided into three periods P1, P2 (cold period), and P3. For the cold area ($30-50^{\circ}N$, $115-135^{\circ}E$) the corresponding cold period P2 is determined to be 39 days from 23 December 2010 through 30 January 2011. During P1 and P3 temperature anomalies from the climatological mean are small with large standard deviation compared to those of P2, which has large negative anomaly and small standard deviation. The period P2 is dominated by blocking, which was determined by distributions of 500-hPa geopotential height and potential temperature on the 2 PVU surface. Correlation-coefficient analyses show that during P2 the temperature in the cold area is related with pressure of Northeastern Asia, while the temperature during P1 and P3 is related with pressure of Northwest of Korea. Also, during P1 and P3 the temperature pattern shows eastward propagation, but during P2, a stationary pattern. All the observations imply that, during the cold period P2, the temperature in the cold area is related with blocking in Northeastern Asia. During P1 and P3 temperature pattern is related with 500-hPa geopotential height in Siberia, and this relationship is also observed in the climatological mean state.

Molecular Effect of PVP on The Release Property of Carvedilol Solid Dispersion

  • Oh, Myeong-Jun;Shim, Jung-Bo;Lee, Eun-Yong;Yoo, Han-Na;Cho, Won-Hyung;Lim, Dong-Kyun;Lee, Dong-Won;Khang, Gil-Son
    • Journal of Pharmaceutical Investigation
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    • v.41 no.3
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    • pp.179-184
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    • 2011
  • This study aimed to confirm the effect of molecular weight (MW) in solid dispersion of carvedilol with poly-vinylpyrrolidone (PVP) of various MW. Solid dispersion of carvedilol with PVP was prepared by spray-drying method. Scanning electron microscopy (SEM) was used to analyze the surface of solid dispersion samples. Differential scanning calorimetry (DSC) and X-ray diffraction (XRD) were used to analyze the crystalline of solid dispersion. Fourier transform infrared spectroscopy (FT-IR) was used to analyze the change of chemical structure characteristic of solid dispersion. DSC and XRD show that drug crystalline was changed. FT-IR revealed that chemical structure of solid dispersion comparing the chemical structure of drug was changed. The dissolution studies of solid dispersion presented at simulated gastric juice (pH 1.2). The dissolution rate of solid dispersion was dramatically enhanced than pure drug and the MW of PVP has an effect on the release property of carvedilol in solid dispersion. In conclusion, the present study has confirmed the effect of MW of PVP on release property of solid dispersion formulation of carvedilol with PVP.

Characterization of Bacterial ${\alpha}-Amylase$ by Determination of Rice Starch Hydrolysis Product (쌀전분(澱粉) 분해물(分解物) 분석(分析)에 의한 세균성(細菌性) ${\alpha}-Amylase$의 작용(作用) 특성(特性))

  • Kim, Hae-Yeong;Park, Kwan-Hwa
    • Applied Biological Chemistry
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    • v.29 no.3
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    • pp.248-254
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    • 1986
  • The product specificity of Bacillus ${\alpha}-amylase$ on raw rice starch has teen studied by using HPLC and scanning electron microscopy (SEM). Analysis of starch degradation products digested by ${\alpha}-amylase$ showed considerable differences between raw and gelatinized rice. The hydrolysis of raw rice starch resulted in formation of more glucose and maltose than those of gelatinized starch. SEM revealed characteristic enzyme degradation patterns. Hollow curvatures were observed in gelatinized starch, indicating the substrate is hydrolyzed in the interior of the starch chain by Bacillus ${\alpha}-amylase$. In contrast, raw starch were hydrolyzed from the end of the substrate, resulting in pinholes over the surface of the starch granules.

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Analysis of Faceted-Reflector Antenna (각면 반사판 안테나의 해석)

  • Kwak, Chang-Soo;Uhm, Man-Seok;Yom, In-Bok
    • Journal of Satellite, Information and Communications
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    • v.5 no.2
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    • pp.34-39
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    • 2010
  • Due to big demand for satellite and communication service using personal handheld terminals, demand for satellites with huge antennas is increasing correspondingly. While such large antennas are realized by various types of deployable antennas, the reflecting surface is made by many facets irrespective of deploying mechanisms. In order to analyze the faceted-reflector more accurately, an existing ray-tracing method is improved. The algorithm allows the rays to cross each other, which is the main characteristic of the faceted-reflector, and takes unevenness of amplitude and phase over the aperture plane into consideration. For the study of the effect of facet configuration, facet generating algorithm is devised. From the analysis algorithm and the facet-generating algorithm, it has been found that the number of facets in a radial direction affects both directivity and sidelobe level. On the other hand, the number of facets in a circumferential direction affects sidelobe level only.

A Degradation Characteristic of FRP Rebars Attacked by Combined Environmental Factors (복합환경인자에 의한 FRP 보강근의 성능저하 특성)

  • Oh, Hong Seob;Moon, Do Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.3
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    • pp.1-10
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    • 2012
  • In spite of high resistant to corrosion and its strength, over the last two decades, concerns still remain about the durability of FRP materials under severe environmental and thermal exposures. In this paper, authors experimentally examine the combined degradation by thermal and chemical attacks in heterogeneous FRP rebar be made up with various fibers and resins. Five types of Carbon, Glass and Hybrid FRP rebars had manufactured by different process and surface patterns are adopted for the experiments such as weight change, interlaminar shear strength, SEM and FT-IR analysis. FRP specimens were immersed in alkaline or distilled solution up to 150 days and then thermal exposed on 60, 100, 150 and $300^{\circ}C$ for 30 minutes. From the test results, the degradation of FRP bars are influnced by the resin type and manufacturing process as well as the fiber, and ILSS of exposed FRP bar in solutions is slightly increased in initial stage and then decresed with the passing of immersed time. But, in this test, it is observed that the discrepancy of ILSS between degraded by alkaline solution and distilled water is negligible value.

Physical Characteristics of Mushroom(Agaricus bisporus) as Influenced by Different Drying Methods (건조방법에 따른 양송이버섯의 물리적 특성에 관한 연구)

  • Ha, Young-Sun;Park, Jong-Won;Lee, Jun-Ho
    • Korean Journal of Food Science and Technology
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    • v.33 no.2
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    • pp.245-251
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    • 2001
  • This research was conducted to study the changes in physical characteristics of mushrooms (Agaricus bisporus) as influenced by drying methods. Samples were dried using either hot air drying, vacuum drying, or freeze drying and changes in the color, browning index, hardness and rehydration rate were evaluated by response surface methodology. Hot air drying resulted in the fastest drying of sample as compared to other methods. The rate of drying was most affected by the environmental temperature rather than air velocity or vacuum pressure. The overall color difference increased as the temperature and air velocity increased. The overall color changes of the freeze dried samples were minimal as compared to those of fresh mushrooms. The hot air dried samples showed the greatest changes in the overall color, browning index as well as hardness. The freeze dried samples showed the best rehydration characteristic and maintained the best overall quality after drying.

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Interfacial Durability and Acoustic Properties of Transparent xGnP/PVDF/xGnP Graphite Composites Film for Acoustic Actuator (음향 작동기를 위한 투명한 xGnP/PVDF/xGnP 그래핀 복합재료 필름의 계면 내구성 및 음향 특성)

  • Gu, Ga-Young;Wang, Zuo-Jia;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.25 no.3
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    • pp.70-75
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    • 2012
  • Interfacial durability and electrical properties of CNT, ITO or xGnP coated PVDF nanocomposites were investigated for acoustic actuator applications. The xGnP coated PVDF nanocomposite exhibited better electrical conductivity than CNT and ITO case due to the unique electrical property of xGnP, and this nanocomposite also showed good sound characteristics. Interfacial adhesion durability between either neat CNT or plasma treated CNT and plasma treated PVDF were measured by static contact angle, surface energy, work of adhesion, and spreading coefficient tests. The optimum acoustic actuation performance of xGnP coated PVDF nanocomposite was measured using sound level meter with changing radius of curvature and coating conditions. As compared to CNT and ITO, the xGnP was known as more appropriate acoustic actuator due to the characteristic electrical property. It is the most appropriate condition when the radius of curvature is 15 degree. Although sound characteristics were different with various coating thicknesses, it is possible to manufacture transparent actuator with good sound quality.

Effect of pH on Pore Characteristics in Synthesis of High Porous AlO(OH) Gel by Hydrolysis of Al2(SO4)3 and Na2SO4 Mixed Solution (Al2(SO4)3와 Na2SO4 혼합용액의 가수분해에 의한 고기공 AlO(OH) 겔의 합성에서 pH가 기공특성에 미치는 영향)

  • Park, Byung-Ki;Choe, Dong-Uk;Lee, Jae-Rock
    • Journal of the Korean Ceramic Society
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    • v.44 no.6 s.301
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    • pp.325-330
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    • 2007
  • High porous AlO(OH) gel is used in precursor of ceramic material, coating material and porous catalyst. For use of these, not only physiochemical control for particle morphology, pore characteristic and peptization but also studies of synthetic method for preparation of high porous AlO(OH) gel were required. In this study, high porous AlO(OH) gel was prepared through the aging and filtration process of aluminum hydroxides gel precipitated by the hydrolysis reaction of $Na_2CO_3$ solution and $Al_2(SO_4)_3$ and $Na_2SO_4$ mixed solution. In this process, optimum synthetic condition of AlO(OH) gel having excellent pore volume as studying the effect of hydrolysis pH on gel precipitates has been studied. Hydrolysis pH brought about numerous changes on crystal morphology, surface area, pore volume and pore size. Physiochemical properties of gel were investigated as using XRD, TEM, TG/DTA, FT-IR and $N_2$ BET method.