• 제목/요약/키워드: Surface active glass

검색결과 45건 처리시간 0.022초

반응성 플라즈마 표면처리 기법을 도입한 새로운 유리섬유강화 복합재료의 개발 및 물성연구 - (I) Plasma처리에 의한 평판유리표면의 젖음성 개선에 관한 연구 - (Development of New Fiber Reinforced Campsite Materials by Reactive Plasma Surface Treatmnt - (I) Improving the Wettability on the Glass Plate by Plasma Surface Treatment -)

  • 손인용;변성만;김순태;조정수;김규섭;박정후
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1993년도 하계학술대회 논문집 B
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    • pp.581-583
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    • 1993
  • One of the principal problems encountered in the use of fiber reinforced composites is to establish an active fiber surface to achieve maximum adhesion between resin and fiber surface. In order to improve the interface bonding, the surface of glass fiber should be treated with silane coupling agent in ordinary composite manufacturing processes. However, the price of the coupling agent is very high and in the treating process voids are formed, which decreasees electrical and mechanical strength. We want to develope new process that will overcome the disadvantage of the coupling agent and achieve maximum adhesion at the interface between resin and fiber by active plasma treatment on the glass fiber surface. In this study, we investigate the improvement of contact angle on the glass plate surface as the first step in developing new GFRP.

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ANALYSIS OF THIN FILM POLYSILICON ON GLASS SYNTHESIZED BY MAGNETRON SPUTTERING

  • Min J. Jung;Yun M. Chung;Lee, Yong J.;Jeon G. Han
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2001년도 추계학술발표회 초록집
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    • pp.68-68
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    • 2001
  • Thin films of polycrystalline silicon (poly-Si) is a promising material for use in large-area electronic devices. Especially, the poly-Si can be used in high resolution and integrated active-matrix liquid-crystal displays (AMLCDs) and active matrix organic light-emitting diodes (AMOLEDs) because of its high mobility compared to hydrogenated _amorphous silicon (a-Si:H). A number of techniques have been proposed during the past several years to achieve poly-Si on large-area glass substrate. However, the conventional method for fabrication of poly-Si could not apply for glass instead of wafer or quartz substrate. Because the conventional method, low pressure chemical vapor deposition (LPCVD) has a high deposition temperature ($600^{\circ}C-1000^{\circ}C$) and solid phase crystallization (SPC) has a high annealing temperature ($600^{\circ}C-700^{\circ}C$). And also these are required time-consuming processes, which are too long to prevent the thermal damage of corning glass such as bending and fracture. The deposition of silicon thin films on low-cost foreign substrates has recently become a major objective in the search for processes having energy consumption and reaching a better cost evaluation. Hence, combining inexpensive deposition techniques with the growth of crystalline silicon seems to be a straightforward way of ensuring reduced production costs of large-area electronic devices. We have deposited crystalline poly-Si thin films on soda -lime glass and SiOz glass substrate as deposited by PVD at low substrate temperature using high power, magnetron sputtering method. The epitaxial orientation, microstructual characteristics and surface properties of the films were analyzed by TEM, XRD, and AFM. For the electrical characterization of these films, its properties were obtained from the Hall effect measurement by the Van der Pauw measurement.

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반응성 플라즈마 표면 처리기법을 도입한 새로운 유리섬유 강화 복합재료의 개발 및 물성연구 (New Glass Fiber Reinforced Composite Insulating Material by Reactive Plasma Surface Treatment)

  • 성열문;하흥주;문상룡;조정수;김규섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1994년도 춘계학술대회 논문집
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    • pp.141-143
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    • 1994
  • One of the Principal problems encountered in the use of filer reinforced composites is to establish an active fiber surface to achieve maximum adhesion between resin and fiber surface. Now, we want to develope new process that will overcome the disadvantage of the chemical coupling agent and achieve maximum adhesion at the interface between resin and fiber by active plasma treatment on the glass fiber surface. In this study. we investigated the effect of plasma treatment on the wettability of glans surface .

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반응성 플라즈마 표면처리기법을 도입한 새로운 유리섬유 강화 복합재료의 개발 및 물성연구(II) (Developement of New Glass Fiber Reinforced Composite Insulating Material by Reactive Plasma Surface Treatment(II))

  • 박정후;조정수;성문열;김두환;김규섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 춘계학술대회 논문집
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    • pp.216-219
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    • 1995
  • One of the principal problems encountered in the use of glass fiber reinforced Plastic composites(GFRP) is to establish an active fiber surface to achieve maximum adhesion between resin and fiber surface. In order to develope new process to overcome the disadvantage of chemical agent, we have studied the effect of reactive plasma glass surface treatment on the electrical and mechanical properties of glass fiber reinforced epoxy composites. It is found that the electrical and mechanical characteristics of the composites treated with plasma is improved especially in the dielectric strength by 20% and tensile strength by 15%, whereas the tan $\delta$ is decreased significantly.

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Electroless Deposition and Surface-Enhanced Raman Scattering Application of Palladium Thin Films on Glass Substrates

  • Shin, Kuan Soo;Cho, Young Kwan;Kim, Kyung Lock;Kim, Kwan
    • Bulletin of the Korean Chemical Society
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    • 제35권3호
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    • pp.743-748
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    • 2014
  • In this work, we describe a very simple electroless deposition method to prepare moderate-SERS-active nanostructured Pd films deposited on the glass substrates. To the best of our knowledge, this is the first report on the one-pot electroless method to deposit Pd nanostructures on the glass substrates. This method only requires the incubation of negatively charged glass substrates in ethanol-water mixture solutions of $Pd(NO_3)_2$ and butylamine at elevated temperatures. Pd films are then formed exclusively and evenly on glass substrates. Due to the aggregated structures of Pd, the SERS spectra of benzenethiol and organic isonitrile could be clearly identified using the Pd-coated glass as a SERS substrate. This one-step fabrication method of Pd thin film on glass is cost-effective and suitable for the mass production.

표면활성유리에의 결정석출을 이용한 용액중 황산염 이온 제거 (${SO_4}^{2-}$ ion Removal from Solution by Crystal Precipitation on Surface Active Glasses)

  • 남명식;김철영
    • 한국세라믹학회지
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    • 제35권12호
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    • pp.1286-1293
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    • 1998
  • 폐수 중에 존재하는 황산염 이온은 여러 금속 이온과의 반응으로 폐수 운송관 내에서 스케일 현상을 일으켜 문제점을 발생시킬 수 있다. 본 실험에서는 여러 조성의 표면활성유리를 이용하여 산성 용액 중에 있는 황산염 이온을 제저하려 하였다. pH 1~4까지의 황산염 이온이 함유된 산성 용액과 $SiO_2-Na_2O-B_2O_3-RO$(R=Mg, Ca, Sr, Ba)계조성의 표면활성유리를 여러 시간 반응시킨 후 표면을 XRD,SEM으로 관찰하였고 용액내에 존재하는 모든 이온을 정량 분석하였다. 용액 중의 황산염 이온은 유리에서 공급한 2가 양이온과 결합하여 유리 표면에 황산염 결정으로 석출되면서 용액으로부터 제거되었다. 이들 황산염 이온 제거 능률은 유리표면에 석출되는 황산염 결정의 용해도곱 상수와 큰 연관을 갖고 있었으며, MgO가 포함된 유리에서는 황산염 결정 석출이 크지 않은 반면 SrO, BaO를 함유한 유리조성에서는 황산염 결정 석출이 쉬워서 황산염 이온 제거 효율이 매우 높게 나타났다.

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Coating gold nanoparticles to a glass substrate by spin-coat method as a surface-enhanced raman spectroscopy (SERS) plasmonic sensor to detect molecular vibrations of bisphenol-a (BPA)

  • Eskandari, Vahid;Hadi, Amin;Sahbafar, Hossein
    • Advances in nano research
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    • 제13권5호
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    • pp.417-426
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    • 2022
  • Bisphenol A (BPA) is one of the chemicals used in monomer epoxy resins and polycarbonate plastics. The surface-enhanced Raman spectroscopy (SERS) method is precise for identifying biological materials and chemicals at considerably low concentrations. In the present article, the substrates coated with gold nanoparticles have been studied to identify BPA and control the diseases caused by this chemical. Gold nanoparticles were made by a simple chemical method and by applying gold salt and trisodium citrate dihydrate reductant and were coated on glass substrates by a spin-coat approach. Finally, using these SERS substrates as plasmonic sensors and Raman spectroscopy, the Raman signal enhancement of molecular vibrations of BPA was investigated. Then, the molecular vibrations of BPA in some consumer goods were identified by applying SERS substrates as plasmonic sensors and Raman spectroscopy. The fabricated gold nanoparticles are spherical and quasi-spherical nanoparticles that confirm the formation of gold nanoparticles by observing the plasmon resonance peak at 517 nm. Active SERS substrates have been coated with nanoparticles, which improve the Raman signal. The enhancement of the Raman signal is due to the resonance of the surface plasmons of the nanoparticles. Active SERS substrates, gold nanoparticles deposited on a glass substrate, were fabricated for the detection of BPA; a detection limit of 10-9 M and a relative standard deviation (RSD) equal to 4.17% were obtained for ten repeated measurements in the concentration of 10-9 M. Hence, the Raman results indicate that the active SERS substrates, gold nanoparticles for the detection of BPA along with the developed methods, show promising results for SERS-based studies and can lead to the development of microsensors. In Raman spectroscopy, SERS active substrate coated with gold nanoparticles are of interest, which is larger than gold particles due to the resonance of the surface plasmons of gold nanoparticles and the scattering of light from gold particles since the Raman signal amplifies the molecular vibrations of BPA. By decreasing the concentration of BPA deposited on the active SERS substrates, the Raman signal is also weakened due to the reduction of molecular vibrations. By increasing the surface roughness of the active SERS substrates, the Raman signal can be enhanced due to increased light scattering from rough centers, which are the same as the larger particles created throughout the deposition by the spin-coat method, and as a result, they enhance the signal by increasing the scattering of light. Then, the molecular vibrations of BPA were identified in some consumer goods by SERS substrates as plasmonic sensors and Raman spectroscopy.

구획화재 시 국부복사열에 노출된 유리면의 수막접촉에 따른 급냉파열특성 관한 실험적 연구 (Experimental Study on Interaction of Water Sprayed Curtain on Hot Surface of a Window Glass and its Effects on Glass Surface Temperature in Room Fires)

  • 박형주;지남용
    • 한국화재소방학회논문지
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    • 제17권4호
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    • pp.124-130
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    • 2003
  • 본 연구는 방화구획에 적용 가능한 수막형성유리벽에의 직근에 화원이 위치하는 경우 국부복사열에 의해 수막형성전 유리면이 가열된 상태에서 상부 수막분사노즐에서 분사되는 수막이 접촉함에 따른 급냉파열현상을 규명하기 위한 연구이다. 유리면 직근에서 국부복사열을 주는 실화재실험을 실시하여 분석하면 보통유리는 유리면 포면온도(가열측)가 $100^{\circ}C$를 넘는 경우에 수막을 접촉시킬 경우 파열이 발생하며, 강화유리는 유리 가열면 온도가 $250^{\circ}C$이상일 때 수막형성에 의한 급냉 파열이 발생함을 알 수 있었다. 향후 강화유리에 수막을 도포시키는 현재 방화구획에 사용되고 있는 유리의 대다수가 강화유리인 것을 감안하면 수막의 도포이전에 강화유리면의 온도가 $300^{\circ}C$이내에서는 수막을 유리면에 급속히 접촉시켜도 유리면의 급냉 파열이 일어나지 않음을 발견하였다. 따라서 일정한 공간구획 내에서 화재발생시 유리면의 직근에 화원이 위치하여 국부적으로 복사열을 가할 경우에도 화원상부 천정면에 설치된 감지시스템에 의해 한계온도이전에 수막형성시스템을 작동시켜 급냉파열현상을 발생시키지 않는다면 수막형성유리벽을 실제 방화구획의 경계벽으로 사용하는데 있어서 예측가능한 장애요인을 제거하는 데 비약적인 공헌을 한 것에 그 의미를 둔다.

반응표면분석법에 따른 저온소성 경량골재의 킬른공정변수 최적화 (Optimization of Kiln Process Parameters of Low-Temperature Sintering Lightweight Aggregate by Response Surface Analysis)

  • 이한백;서치호
    • 한국세라믹학회지
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    • 제47권5호
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    • pp.365-372
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    • 2010
  • This paper was to evaluate the influence of kiln process parameter(kiln angle, kiln rotating speed) of lightweight aggregate using waste glass and bottom ash with industrial by-products on thermal conductivity, density, water absorption, fracture load and porosity by response surface analysis. In the results of surface plot and contour plot, it has verified that kiln residence time of lightweight aggregate increase as kiln angle and rotating speed decreases. For this reason, pore size and quantity tend to increase by active reaction of forming agent. It seems to be that increase in pore size and quantity have caused decreasing density, fracture load and thermal conductivity, and increasing water absorption. In conclusion, optimization of kiln process parameter on thermal conductivity, density, water absorption, fracture load and porosity by response surface analysis are kiln angle 2.4646%, kiln rotating speed 40.7089 rpm.

준 능동형 로터를 이용한 마이크로 혼합기의 제작 및 혼합특성 (Fabrication and Mixing Characteristics of a Micro-Mixer with a Quasi-Active Rotor)

  • 김용대;이종광;권세진
    • 대한기계학회논문집A
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    • 제33권4호
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    • pp.417-424
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    • 2009
  • A micro-mixer with a quasi-active rotor was fabricated, and mixing characteristics were evaluated. The proposed micro-mixer combines an active type micro-mixer with a passive type micro-mixer. The micro-rotor, which is a moving part of an active type micro-mixer, is added in a micro-chamber of a passive type vortex micro-mixer. The rotor rotated by inflows tangent to a chamber, causing strong perturbations. The micro-mixers were fabricated using photosensitive glass. Mixing efficiency of the micro-mixers was measured using an image analysis method. Mixing efficiency and characteristics of the micro-rotor mixer were compared with the vortex micro-mixer without a rotor. Mixing efficiency was reduced as Reynolds number increased at a low Reynolds number due to decrease of residence time. Mixing efficiency at higher Reynolds number, on the other hand, was improved even though residence time decreased since the contact surface between fluids increased by twisted flow. The perturbation induced by rotating rotor at greater than Re 200 improved the efficiency of the rotor mixer.