• Title/Summary/Keyword: Surface active glass

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Development of New Fiber Reinforced Campsite Materials by Reactive Plasma Surface Treatmnt - (I) Improving the Wettability on the Glass Plate by Plasma Surface Treatment - (반응성 플라즈마 표면처리 기법을 도입한 새로운 유리섬유강화 복합재료의 개발 및 물성연구 - (I) Plasma처리에 의한 평판유리표면의 젖음성 개선에 관한 연구 -)

  • Song, I Y.;Byun, S.M.;Kim, S.T.;Cho, J.S.;Kim, G.S.;Park, C.H.
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.581-583
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    • 1993
  • One of the principal problems encountered in the use of fiber reinforced composites is to establish an active fiber surface to achieve maximum adhesion between resin and fiber surface. In order to improve the interface bonding, the surface of glass fiber should be treated with silane coupling agent in ordinary composite manufacturing processes. However, the price of the coupling agent is very high and in the treating process voids are formed, which decreasees electrical and mechanical strength. We want to develope new process that will overcome the disadvantage of the coupling agent and achieve maximum adhesion at the interface between resin and fiber by active plasma treatment on the glass fiber surface. In this study, we investigate the improvement of contact angle on the glass plate surface as the first step in developing new GFRP.

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ANALYSIS OF THIN FILM POLYSILICON ON GLASS SYNTHESIZED BY MAGNETRON SPUTTERING

  • Min J. Jung;Yun M. Chung;Lee, Yong J.;Jeon G. Han
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2001.11a
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    • pp.68-68
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    • 2001
  • Thin films of polycrystalline silicon (poly-Si) is a promising material for use in large-area electronic devices. Especially, the poly-Si can be used in high resolution and integrated active-matrix liquid-crystal displays (AMLCDs) and active matrix organic light-emitting diodes (AMOLEDs) because of its high mobility compared to hydrogenated _amorphous silicon (a-Si:H). A number of techniques have been proposed during the past several years to achieve poly-Si on large-area glass substrate. However, the conventional method for fabrication of poly-Si could not apply for glass instead of wafer or quartz substrate. Because the conventional method, low pressure chemical vapor deposition (LPCVD) has a high deposition temperature ($600^{\circ}C-1000^{\circ}C$) and solid phase crystallization (SPC) has a high annealing temperature ($600^{\circ}C-700^{\circ}C$). And also these are required time-consuming processes, which are too long to prevent the thermal damage of corning glass such as bending and fracture. The deposition of silicon thin films on low-cost foreign substrates has recently become a major objective in the search for processes having energy consumption and reaching a better cost evaluation. Hence, combining inexpensive deposition techniques with the growth of crystalline silicon seems to be a straightforward way of ensuring reduced production costs of large-area electronic devices. We have deposited crystalline poly-Si thin films on soda -lime glass and SiOz glass substrate as deposited by PVD at low substrate temperature using high power, magnetron sputtering method. The epitaxial orientation, microstructual characteristics and surface properties of the films were analyzed by TEM, XRD, and AFM. For the electrical characterization of these films, its properties were obtained from the Hall effect measurement by the Van der Pauw measurement.

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New Glass Fiber Reinforced Composite Insulating Material by Reactive Plasma Surface Treatment (반응성 플라즈마 표면 처리기법을 도입한 새로운 유리섬유 강화 복합재료의 개발 및 물성연구)

  • 성열문;하흥주;문상룡;조정수;김규섭
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.141-143
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    • 1994
  • One of the Principal problems encountered in the use of filer reinforced composites is to establish an active fiber surface to achieve maximum adhesion between resin and fiber surface. Now, we want to develope new process that will overcome the disadvantage of the chemical coupling agent and achieve maximum adhesion at the interface between resin and fiber by active plasma treatment on the glass fiber surface. In this study. we investigated the effect of plasma treatment on the wettability of glans surface .

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Developement of New Glass Fiber Reinforced Composite Insulating Material by Reactive Plasma Surface Treatment(II) (반응성 플라즈마 표면처리기법을 도입한 새로운 유리섬유 강화 복합재료의 개발 및 물성연구(II))

  • 박정후;조정수;성문열;김두환;김규섭
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.216-219
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    • 1995
  • One of the principal problems encountered in the use of glass fiber reinforced Plastic composites(GFRP) is to establish an active fiber surface to achieve maximum adhesion between resin and fiber surface. In order to develope new process to overcome the disadvantage of chemical agent, we have studied the effect of reactive plasma glass surface treatment on the electrical and mechanical properties of glass fiber reinforced epoxy composites. It is found that the electrical and mechanical characteristics of the composites treated with plasma is improved especially in the dielectric strength by 20% and tensile strength by 15%, whereas the tan $\delta$ is decreased significantly.

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Electroless Deposition and Surface-Enhanced Raman Scattering Application of Palladium Thin Films on Glass Substrates

  • Shin, Kuan Soo;Cho, Young Kwan;Kim, Kyung Lock;Kim, Kwan
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.743-748
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    • 2014
  • In this work, we describe a very simple electroless deposition method to prepare moderate-SERS-active nanostructured Pd films deposited on the glass substrates. To the best of our knowledge, this is the first report on the one-pot electroless method to deposit Pd nanostructures on the glass substrates. This method only requires the incubation of negatively charged glass substrates in ethanol-water mixture solutions of $Pd(NO_3)_2$ and butylamine at elevated temperatures. Pd films are then formed exclusively and evenly on glass substrates. Due to the aggregated structures of Pd, the SERS spectra of benzenethiol and organic isonitrile could be clearly identified using the Pd-coated glass as a SERS substrate. This one-step fabrication method of Pd thin film on glass is cost-effective and suitable for the mass production.

${SO_4}^{2-}$ ion Removal from Solution by Crystal Precipitation on Surface Active Glasses (표면활성유리에의 결정석출을 이용한 용액중 황산염 이온 제거)

  • 남명식;김철영
    • Journal of the Korean Ceramic Society
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    • v.35 no.12
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    • pp.1286-1293
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    • 1998
  • ${SO_4}^{2-}$ ions present in industrial waste water if combined with other metal ions in the water can cause serious scale problem in a transporting pipe. In this study therefore ${SO_4}^{2-}$ ions in an acidic solution have been removed by using surface active glasses. Glasses with various compositions of $SiO_2-Na_2O-B_2O_3-RO$ (R=Mg, Ca, Sr, Ba) system were reacted in a ${SO_4}^{2-}$ ion-containing solution with various pHs ranging from 1 to 4 for various time the reacted glass surfaces were analyzed by XRD and SEM and all ions in the reacted solution were also measured ${SO_4}^{2-}$ ions in the solution were combined with divalent ions leached out of glass and precipitated on the glass surface as sulfate crystals. In this was the surface ion could be removed from the acidic solution. The sulfate ion removal capacity is closely related to the solubility product con-stants of the newly formed sulfate crystals. Almost no sulfate crystal was formed on the MgO-containing glass while sulfate crystals were easily formed on the glass containing either SrO or BaO This indicates that those glasses have strong removal efficiency of ${SO_4}^{2-}$ ions from the solution.

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Coating gold nanoparticles to a glass substrate by spin-coat method as a surface-enhanced raman spectroscopy (SERS) plasmonic sensor to detect molecular vibrations of bisphenol-a (BPA)

  • Eskandari, Vahid;Hadi, Amin;Sahbafar, Hossein
    • Advances in nano research
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    • v.13 no.5
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    • pp.417-426
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    • 2022
  • Bisphenol A (BPA) is one of the chemicals used in monomer epoxy resins and polycarbonate plastics. The surface-enhanced Raman spectroscopy (SERS) method is precise for identifying biological materials and chemicals at considerably low concentrations. In the present article, the substrates coated with gold nanoparticles have been studied to identify BPA and control the diseases caused by this chemical. Gold nanoparticles were made by a simple chemical method and by applying gold salt and trisodium citrate dihydrate reductant and were coated on glass substrates by a spin-coat approach. Finally, using these SERS substrates as plasmonic sensors and Raman spectroscopy, the Raman signal enhancement of molecular vibrations of BPA was investigated. Then, the molecular vibrations of BPA in some consumer goods were identified by applying SERS substrates as plasmonic sensors and Raman spectroscopy. The fabricated gold nanoparticles are spherical and quasi-spherical nanoparticles that confirm the formation of gold nanoparticles by observing the plasmon resonance peak at 517 nm. Active SERS substrates have been coated with nanoparticles, which improve the Raman signal. The enhancement of the Raman signal is due to the resonance of the surface plasmons of the nanoparticles. Active SERS substrates, gold nanoparticles deposited on a glass substrate, were fabricated for the detection of BPA; a detection limit of 10-9 M and a relative standard deviation (RSD) equal to 4.17% were obtained for ten repeated measurements in the concentration of 10-9 M. Hence, the Raman results indicate that the active SERS substrates, gold nanoparticles for the detection of BPA along with the developed methods, show promising results for SERS-based studies and can lead to the development of microsensors. In Raman spectroscopy, SERS active substrate coated with gold nanoparticles are of interest, which is larger than gold particles due to the resonance of the surface plasmons of gold nanoparticles and the scattering of light from gold particles since the Raman signal amplifies the molecular vibrations of BPA. By decreasing the concentration of BPA deposited on the active SERS substrates, the Raman signal is also weakened due to the reduction of molecular vibrations. By increasing the surface roughness of the active SERS substrates, the Raman signal can be enhanced due to increased light scattering from rough centers, which are the same as the larger particles created throughout the deposition by the spin-coat method, and as a result, they enhance the signal by increasing the scattering of light. Then, the molecular vibrations of BPA were identified in some consumer goods by SERS substrates as plasmonic sensors and Raman spectroscopy.

Experimental Study on Interaction of Water Sprayed Curtain on Hot Surface of a Window Glass and its Effects on Glass Surface Temperature in Room Fires (구획화재 시 국부복사열에 노출된 유리면의 수막접촉에 따른 급냉파열특성 관한 실험적 연구)

  • 박형주;지남용
    • Fire Science and Engineering
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    • v.17 no.4
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    • pp.124-130
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    • 2003
  • This research focuses on analysis of a interaction fracture of various glasses due to contact of water sprayed curtain on hot glass surface with high temperature produced from convective heat source near glass wall. A large scaled experimental test was done in order to find the range of the glass surface temperature to be able to cause the breakage of the glasses when water droplets reach on the hot surface. This paper shows the allowable temperature of the glass surface for prevention of the cooling down breakage before water curtain droplets contact the surface. Allowable Temperature if $250^{\circ}C$ for the tempered glass but general glass is very relatively low. Therefore if the water curtain spray system was adequately activated by a thermal detector installed below ceiling adjacent glass wall with water curtain nozzle system, all hot glass would not break out by cooling water droplet's contact on the hot surface due to convective heat released by adjacent fire source near the glass wall.

Optimization of Kiln Process Parameters of Low-Temperature Sintering Lightweight Aggregate by Response Surface Analysis (반응표면분석법에 따른 저온소성 경량골재의 킬른공정변수 최적화)

  • Lee, Han-Baek;Seo, Chee-Ho
    • Journal of the Korean Ceramic Society
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    • v.47 no.5
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    • pp.365-372
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    • 2010
  • This paper was to evaluate the influence of kiln process parameter(kiln angle, kiln rotating speed) of lightweight aggregate using waste glass and bottom ash with industrial by-products on thermal conductivity, density, water absorption, fracture load and porosity by response surface analysis. In the results of surface plot and contour plot, it has verified that kiln residence time of lightweight aggregate increase as kiln angle and rotating speed decreases. For this reason, pore size and quantity tend to increase by active reaction of forming agent. It seems to be that increase in pore size and quantity have caused decreasing density, fracture load and thermal conductivity, and increasing water absorption. In conclusion, optimization of kiln process parameter on thermal conductivity, density, water absorption, fracture load and porosity by response surface analysis are kiln angle 2.4646%, kiln rotating speed 40.7089 rpm.

Fabrication and Mixing Characteristics of a Micro-Mixer with a Quasi-Active Rotor (준 능동형 로터를 이용한 마이크로 혼합기의 제작 및 혼합특성)

  • Kim, Young-Dae;Lee, Jong-Kwang;Kwon, Se-Jin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.4
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    • pp.417-424
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    • 2009
  • A micro-mixer with a quasi-active rotor was fabricated, and mixing characteristics were evaluated. The proposed micro-mixer combines an active type micro-mixer with a passive type micro-mixer. The micro-rotor, which is a moving part of an active type micro-mixer, is added in a micro-chamber of a passive type vortex micro-mixer. The rotor rotated by inflows tangent to a chamber, causing strong perturbations. The micro-mixers were fabricated using photosensitive glass. Mixing efficiency of the micro-mixers was measured using an image analysis method. Mixing efficiency and characteristics of the micro-rotor mixer were compared with the vortex micro-mixer without a rotor. Mixing efficiency was reduced as Reynolds number increased at a low Reynolds number due to decrease of residence time. Mixing efficiency at higher Reynolds number, on the other hand, was improved even though residence time decreased since the contact surface between fluids increased by twisted flow. The perturbation induced by rotating rotor at greater than Re 200 improved the efficiency of the rotor mixer.