• 동력기계공학회지
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• 제18권4호
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• pp.60-65
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• 2014

In this paper, cycle performance analysis for heating capacity, compression work and COP of R134a supercritical heat pump is presented to offer the basic design data for the operating parameters of the system. The operating parameters considered in this study include superheating degree, pressure and outlet temperature of gas cooler, compressor efficiency and evaporating temperature in the R134a supercritical heat pump system. The main results were summarized as follows : Superheating degree, pressure and outlet temperature of gas cooler, compressor efficiency and evaporating temperature of R134a heat pump system have an effect on the heating capacity, compression work and COP of this system. With a thorough grasp of these effect, it is necessary to design the supercritical heat pump using R134a. The prediction for COP of R134a supercritical heat pump have been proposed through multiple regression analysis.

• 대한화장품학회지
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• 제34권3호
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• pp.209-215
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• 2008

화장품, 의약품에서 항비듬제로 널리 사용되는 요도프로피닐 부틸카바메이트와 클림바졸을 초임계 유체를 이용하여 미세입자를 제조하였다. 초임계 유체로는 임계온도와 임계압력이 상대적으로 낮은 이산화탄소가 사용되었다. 초임계 이산탄소에 용해력이 있는 요도프로피닐 부틸카마메이트와 클림바졸을 항비듬제로 선택되었다. 초임계 용액 급속팽창법을 이용하여 압력과 온도를 변화시켜 입자크기와 형상에 미치는 영향을 분석하였다.

• 대한기계학회논문집B
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• 제28권11호
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• pp.1302-1314
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• 2004

Turbulent heat transfer to $CO_2$ at supercritical pressure flowing in vertical tubes is investigated using direct numerical simulation (DNS). A conservative space-time discretization scheme for variable-density flows at low Mach numbers is adopted in the present study to treat steep variations of fluid properties at supercritical pressure just above the thermodynamic critical point. The fluid properties at these conditions are obtained using PROPATH and used in the form of tables in the simulations. The buoyancy influence induced by strong variation of density across the pseudo-critical temperature proved to play a major role in turbulent heat transfer at supercritical state. Depending on the degree of buoyancy influence, turbulent heat transfer may be enhanced or significantly deteriorated, resulting in local hot spots along the heated surface. Based on the results of the present DNS combined with theoretical considerations, the physical mechanism of this local heat transfer deterioration is elucidated.

• Korean Chemical Engineering Research
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• 제40권6호
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• pp.715-718
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• 2002

폴리에스터의 염색공정에서 발생하는 폐수문제를 근원적으로 해결하기 위해서 초임계 유체를 이용한 건식염색기술이 관심의 대상이 되고 있다. 본 연구에서는 반 유통형인 초임계유체 평형실험장치를 이용하여 초임계 상태의 HFC-134a에 대한 분산염료인 C. I. disperse red 60의 용해도를 382.2 K와 413.2 K의 온도와 50, 70, 100, 130, 160 bar의 압력에서 측정하였다. 초임계유체를 고압의 액체로 간주하는 확장액체모델에 측정된 데이터들을 상관하면 실험값과 계산값이 잘 일치하였다.

• 한국연초학회지
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• 제18권1호
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• pp.92-99
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• 1996

A mathematical model of the pressure gradient of supercritical CO2 in a vertical tobacco bed was developed in this study. In particular, the compaction of the tobacco as a function of temperature and CO2 flow is included in the model. Downflow of CO2 (low condition is described. At velocities in excess of 0.6 cm/sec at 7$0^{\circ}C$, there is a large increase in pressure gradient for beds deeper than about 0.5 m. The proposed model offers a better understanding of operating the process using supercritical CO2.

• 청정기술
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• 제11권3호
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• pp.147-152
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• 2005

초임계 이산화탄소에서의 이부프로펜의 용해도를 측정하였다. 이부프로펜의 용해도는 variable volume view cell이 장착되어있는 고압장치를 사용하여 cloud point를 관찰하는 방법으로 실험하였다. 온도의 범위는 35, 40, $45^{\circ}C$로 하였고 측정된 실험값은 Peng-Robinson equation of state로 모델링 하였다. 이부프로펜의 물리적 특성은 Lydersen, Ambrose 그리고 Joback의 group contribution method를 사용하여 구한 값을 사용하였고, 각각의 결과를 비교하였다. 이산화탄소는 이부프로펜에 대해 큰 용해력을 가진다는 것을 확인하였고, 150bar 부근에서 retrograde 현상이 일어남을 알 수 있었다. 또한 Lydersen의 group contribution method를 사용하여 얻어진 이부프로펜의 물리적 특성으로 PR-EOS와 함께 모델링 한 결과가 다른 method보다 실험값과 더 잘 일치함을 확인하였다. 결과적으로 이 실험을 통해 초임계 공정으로 이부프로펜의 미세입자화 시킬 경우 용질이 용매에 용해되어야 하는 rapid expansion of supercritical solution (RESS)방법이 적용될 수 있음을 확인하였다.

• 대한기계학회논문집B
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• 제23권1호
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• pp.131-139
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• 1999

Experimental investigations on flame spread in droplet arrays have been conducted under supercritical ambient pressures of fuel droplet. Flame spread rates are measured for n-Decane droplet of diameters of 0.75 and 1.0mm, using high speed images of OH chemiluminescence up to 3.0MPa. The pattern of flame spread is categorized into two: a continuous mode and an intermittent one. There exists a limit droplet spacing, above which flame spread does not occur. Flame spread rate with the decrease of droplet spacing increases and then decreases after takin& a maximum. It is also seen that there exists a limit ambient pressure, above which flame spread does not occur. Flame spread rate decreases monotonically with the increase of ambient pressure. Exceptionally, In the case of a small droplet spacing, flame spread with the increase of ambient pressure is extended to supercritical pressures of fuel droplet. This is caused by enhanced vaporization with the increase of ambient pressure. Consequently, in flame spread with droplet droplet spacing, the relative position of flame to droplet spacing plays an important role. The monotonic decrease with ambient pressure is mainly related to the reduction of flame radius in subcritical pressures and the extension to supercritical pressures of flame spread is caused by the reduction of ignition time of unburnt droplet due to the enhanced vaporization at supercritical pressures.

• Corrosion Science and Technology
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• 제7권4호
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• pp.237-242
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• 2008

Physical properties of water, such as dielectric constant and ionic product, significantly vary with the density of water. In the supercritical conditions, since density of water widely varies with pressure, pressure has a strong influence on physical properties of water. Dielectric constant represents a character of water as a solvent, which determines solubility of an inorganic compound including metal oxides. Dissociation equilibrium of an acid is also strongly dependent on water density. Dissociation constant of acid rises with increased density of water, resulting in drop of pH. Density of water and the density-related physical properties of water, therefore, are the major governing factors of corrosion and environmentally assisted cracking of metals in supercritical aqueous solutions. This paper discusses importance of "physical properties of water" in understanding corrosion and cracking behavior of alloys in supercritical water environments, based on experimental data and estimated solubility of metal oxides. It has been pointed out that the water density can have significant effects on stress corrosion cracking (SCC) susceptibility of metals in supercritical water, when dissolution of metal plays the key role in the cracking phenomena.

• Advances in Energy Research
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• 제8권4호
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• pp.265-273
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• 2022

In this study, a product gas yield and carbon conversion were measured during the coal pyrolysis. The pyrolysis process occurred under two different atmospheres such as subcritical (45 bar, 10℃) and supercritical CO₂ condition (80 bar, 35℃). Under the same pressure (80 bar), the atmosphere temperature increased from 35℃ to 45℃ to further examine temperature effect on the pyrolysis at supercritical CO₂ condition. For all three cases, a power input supplied to heating wire placed below coal bed was controlled to make coal bed temperature constant. The phase change of CO₂ atmosphere and subsequent pyrolysis behaviors of coal bed were observed using high-resolution camcorder. The pressure and temperature in the reactor were controlled by a CO₂ pump and heater. Then, the coal bed was heated by wire heater to proceed the pyrolysis under supercritical CO₂ condition.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1988년도 한국자동제어학술회의논문집(국내학술편); 한국전력공사연수원, 서울; 21-22 Oct. 1988
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• pp.471-475
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• 1988

Pressure and flowrate control systems for a supercritical extraction process are designed and analyzed. To do this, the dynamic model was first set up using the performance equations of control valves, CO2 compressor and the state equation of the supercritical fluid. Using this model, optimum pairs of manipulated and controlled variable which give least steady stat interaction are determined though the relative gain analysis.