• Title/Summary/Keyword: Supercritical carbon dioxide

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Recovery of High Unsaturated Fatty Acid from Squid Processing Wastes using Supercritical Carbon Dioxide Extraction Method (초임계 이산화탄소 추출법을 이용한 오징어 가공 부산물로부터 고도불포화 지방산 회수)

  • KANG Seong-Sil;KIM Byung-Jun;CHUN Byung-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.2
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    • pp.217-222
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    • 1999
  • A squid viscera oil contains a high content of EPA, DHA, and other valuable polyunsaturated fatty acids. The extractions of squid viscera oil by supercritical carbon dioxide both with/without $3\%$ (v/v) ethanol were performed in a semicontinuous flow extractor at 8.3 to 13.8 MPa and 25 to $50^{\circ}C$. When ethanol was added to $SC-CO_2$, the extraction ratio of lipid increased. The extracts contained high content of unsaturated oils like DHA and EPA. The highest extraction yield of lipid from squid viscera oil extracted by supercritical carbon dioxide was obtained at 12.4 MPa and $40^{\circ}C$ with/without entrainer. The main fatty acids of squid viscera oil extracted by supercritical carbon dioxide were myristric acid (14:0), palmitic acid (16:0), palmitoleic acid (16:1), oleic acid (18:1), arachidic acid (20:0), eicosapentaenoic acid (20:5), and docosahaxaenoic acid (22:6).

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Chromosome Aberration Test of Water Extract of Decaffeined Green Tea using Supercritical Carbon Dioxide with Mammalian cell line (초임계이산화탄소를 이용한 탈카페인녹차 열수추출물의 포유동물 세포주를 이용한 염색체이상시험)

  • Koo, Yun-Chang;Lee, Hyun-Sun;Park, Byung-Gyu;Kim, Eun-Jin;Lee, Sun-Joo;Kim, Kyoung-Hoen;Kim, Young-Suk;Chung, Young-Shin;Lee, Kwang-Won
    • Environmental Mutagens and Carcinogens
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    • v.26 no.4
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    • pp.119-124
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    • 2006
  • There are $10{\sim}30%$ polyphenol and $2{\sim}4%$ caffeine in green tea. Caffeine is a kind of alkaloid containing nitrogen which cause stimulation, impatience, headache, insomnia, low birth weight infant. Because of these negative effect, decaffeined beverage came out and decaffeined coffee already have a big market since 1970s. Having proving the physiologic functions of green tea, high consumption of coffee is shifting to green tea. Because of the carcinogenic effect of the organic solvents, decaffeine processing with supercritical carbon dioxide has industrialized and have an advantage in environment-friendly and minimized flavor loss. Decaffeined green tea using supercritical carbon dioxide is considered to be safe but there are not enough study. We investigated the chromosome aberration test with mammalian cell line, CHL. When the cells were treated with 5000, 2000, 1000 ${\mu}g/ml$ and compared with the negative controls, there were no significant(P>0.05) increased chromosome aberration. Same results was observed when adding S9 mixture or not. As a result, water extract of decaffeined green tea using supercritical carbon dioxide does not induce chromosome aberration.

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High-pressure rheology of polymer melts containing supercritical carbon dioxide

  • Lee Sang-Myung;Han Jae-Ro;Kim Kyung-Yl;Ahn Young-Joon;Lee Jae-Wook
    • Korea-Australia Rheology Journal
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    • v.18 no.2
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    • pp.83-90
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    • 2006
  • Supercritical carbon dioxide ($scCO_2$) has advantages of being incorporated in polymer with high solubility and of being recovered easily by depressurizing. $scCO_2$ reduces the viscosity of polymer melt and it is expected to be use as a plasticizing agent. In this work, we studied on the effect of $scCO_2$ on the rheological properties of polymer melts during extrusion process. Slit die attached to twin screw extruder was used to measure the viscosity of polymer melts plasticized by supercritical $CO_2$. A gas injection system was devised to accurately meter the supercritical $CO_2$ into the extruder barrel. Measurements of pressure drop within the die, confirmed the presence of a one phase mixture and a fully developed flow during the measurements. The viscosity measurement of polypropylene was performed at experimental conditions of various temperatures, pressures and $CO_2$ concentrations. We observed that melt viscosity of polymer was dramatically reduced by $CO_2$ addition.

Supercritical Dyeing Technology (초임계 염색 기술)

  • Kim, Taewan;Park, Geonhwan;Kong, Wonbae;Lee, Youn-Woo
    • Clean Technology
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    • v.24 no.1
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    • pp.1-8
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    • 2018
  • As the social demands for environmental pollution increase and regulations on the dyeing process wastewater are strengthened, supercritical dyeing process has been attracting attention as an alternative technology to reduce wastewater and energy consumption. In the supercritical dyeing process where carbon dioxide is used as a solvent instead of water as a solvent, there is no wastewater generated. The unfixed dyes can be reused later which makes the process environment-friendly. Also, after dyeing process, dried textiles can be obtained without additional drying process, which makes the process energy efficient. In this article, we have summarized the development of the supercritical dyeing process along with the research in Korea today and compared the principle of supercritical dyeing process with conventional dyeing process. To further explain the principle, studies of the distribution factor and mass transfer of dyes in supercritical carbon dioxide and fibers, as well as solubility between supercritical $CO_2$ and dyes are discussed. The dynamic behavior of dyes in supercritical dyeing apparatus and summary of the supercritical dyeing facilities developed around the world are also discussed. Finally, we suggest the direction of research and development for optimization of supercritical dyeing process and application to synthetic fibers and natural fibers except for polyester.

A Study on Dyeing Ability of Aramid(Nomex) Spun Yarn in Supercritical Carbon Dioxide using Disperse dyes (초임계 이산화탄소에 의한 아라미드(Nomex) 방적사의 분산염료에 대한 염색성에 관한 연구)

  • 용관중;박영환;김한석;유기풍;김인회;남성우
    • Textile Coloration and Finishing
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    • v.15 no.2
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    • pp.93-101
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    • 2003
  • To acquire dyeing ability on aramid(Nomex) spun yarn in supercritical fluid dyeing, supercritical fluid dying(SFD) machine of 3L scale was designed. C. I. Disperse Red 60 and Red 360 were used in this work. It was possible to increase dyeing ability and to get level dyeing of fiber by attaching assistance devices(controlling device of supercritical fluid, nozzle, cover of carrier, etc.) to SFD machine. Physical properties(tensile strength, elongation, shrinkage) of Nomex spun yam treated by SFD were not changed. K/S values of dyed Nomex spun yam with Red 360 were higher than that with Red 60 and color fastness of dyed Nomex spun yam by SFD was similar to that by conventional dyeing method.