• 한국염색가공학회지
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• 제32권4호
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• pp.217-225
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• 2020

In this study, the dyeing characteristics of nylon fabric which is dyed with supercritical fluid were investigated. There were two dyes used in the dyeing experiment: C.I. Disperse Red 167 and C.I. Disperse Violet 93. Dyeing temperature, pressure, and leveling time were fixed at 110℃, 250bar, 60minutes, and the experiment was conducted with dyeing concentration of 0.1, 0.3, 0.5, and 0.85% o.w.f. The analysis of the experimental results was found out through the measurement of washing fastness and color coordinate. In addition, the calibration curve of each dye was drawn up and the amount of remaining dye was checked by measuring the absorbance of the residual dye. As a result of color difference measurement, as the concentration increased, the L⁎ value decreased and the K/S value increased. However, the increase in K/S value compared to the amount of input decreased as the concentration increased. The comparative experiment on the amount of residual dye(C.I. Disperse Red 167) in the pot showed that 99.14% of the amount was dyed at the concentration of 0.1% o.w.f, while it rapidly decreased to 77% at 0.85% o.w.f. C.I. Disperse Violet 93 dye also decreased from 0.5% o.w.f to 93.91%. In the washing fastness experiment of both dyes, the level of washing fastness began to decrease from samples dyed at 0.5% o.w.f. It may be because the simply absorbed dye was produced instead of completely being fixed in the amorphous region of the nylon fiber.

• International Journal of Aeronautical and Space Sciences
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• 제16권2호
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• pp.254-263
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• 2015

In this study, numerical simulations are carried out to investigate the dynamic SGS model effects in a Kerosene-LOx coaxial swirl injector under high pressure conditions. The turbulent model is based on large-eddy simulation (LES) with real-fluid transport and thermodynamics. To assess the effect of the dynamic subgrid-scale (SGS) model, the dynamic SGS model is compared with that of the algebraic SGS model. In a swirl injector under supercritical pressure, the characteristics of temporal pressure fluctuation and power spectral density (PSD) present comparable discrepancies dependant on the SGS models, which affect the mixing characteristics. Mixing efficiency and the probability density (PDF) function are conducted for a statistical description of the turbulent flow fields according to the SGS models. The back-scattering of turbulent kinetic energy is estimated in terms of the film thickness of the swirl injector.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집E
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• pp.524-529
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• 2001

Because of the ozone layer depletion and global wanning, new alternative refrigerants are being developed. Among them, HFC refrigerants are thought promising, but some European countries are arguing that these refrigerants are also harmful to the global wanning. Therefore, natural refrigerants should be considered as an eventual alternative in refrigerators and heat pumps. In the present study, the supercritical gas cooling process are computationally analysed by employing various turbulence models of carbon dioxide in a trans critical refrigeration cycle. The gas cooling process near the critical point experiences a drastic change in thermodynamic and transport properties, thus the heat transfer characteristics would be different from those of two or single phases. Based on the computational results, the correlations to estimate the near-critical heat transfer characteristics will are obtained.

• KSBB Journal
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• 제19권4호
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• pp.284-287
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• 2004

초임계 이산화탄소를 이용하여 가시오갈피로부터 유용성분인 acanthoside-D를 추출하여 다음과 같은 결론을 유추하였다. 에탄올과 물, 그리고 50% 메탄올을 공용매로 사용하여 일정압력과 온도에서 추출한 결과물에서의 수율이 가장 높게 측정되었으며, 압력의 변화에 따른 acanthoside-D의 추출효율을 비교한 결과 300 bar에서 가장 높은 추출효율을 나타내었다. 또한 50% 메탄올을 공용매로 하여 유량을 변화시킨 결과, 높은 유량에서 높은 수율을 나타내었으나 1.5ml/g 이상의 유량에서는 수율의 변화가 없었다.

• KSBB Journal
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• 제27권2호
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• pp.131-135
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• 2012

To develop potential cosmetic ingredients with antimicrobial and antioxidant activities of 4 Korean bamboo species (P. bambusoides, P. nigra var. henonis, P. pubescens and Sasa coreana) using three different extraction methods-water, ethanol and supercritical fluid extraction. Antimicrobial activities and DPPH assay have been examined. Among the antimicrobial activities against two test strains, Escherichia coli and Staphylococcus aureus, ethanol extracts of 3 bamboo trees, P. bambusoides, P. nigra var. henonis, and P. pubescens, showed stronger than those of supercritical extracts. However, 4 bamboo supercritical extracts showed dose-dependent increase in antioxidant activity by DPPH assay. These results suggest that water fraction of bamboo extracts may be useful for the cosmetic ingredient with low cytotoxicity.

• 한국식품영양과학회지
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• 제26권5호
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• pp.860-865
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• 1997

Investigations were performed on the effects of extraction temperature, pressure, time on solubility and selectivity of egg yolk lipid and cholesterol, and color and fatty acid composition of the residue in supercritical carbon dioxide(SC-Co$_2$) extraction. Lipid and cholesterol solubility increased as the increase of Co$_2$ density and was found to strongly depend on the extraction pressure rather than the extraction temperature. The relative concentration of cholesterol in the extract increased with an increase in temperature and decreased with an increase in pressure and extraction time. extraction of dried eg yolk for 3hr at 4$0^{\circ}C$/276 bar removed 46.1% of cholesterol from the residual egg yolk with a yield of 63.2%. SC-Co$_2$ extraction produced a lighter color egg yolk with less redness and yellowness. As the extraction time increased, the resultant residual egg yolk became more saturated with fatty acids. SC-$CO_2$ extraction offers a safe, natural method for removing cholesterol from dried egg yolk.

• Bulletin of the Korean Chemical Society
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• 제25권12호
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• pp.1807-1811
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• 2004

Supercritical fluid chromatography (SFC) was considered for separating racemic ibuprofen. The chromatographic column (3.9 ${\times}$ 150 mm) was packed with Kromasil$^{\circledR}$ CHI-TBB, and the mobile phase was supercritical carbon dioxide with modifier of IPA. The experimental variables were the content of IPA, and temperature and pressure of supercritical mobile phase. To determine the separation condition, the empirical equation of retention factor and resolution was proposed. In the case of retention factor, the empirical equation was in the form, $k\;=\;a{\rho}\;+b/F\;+\;c\;({\rho}/F)\;+\;d$. The empirical equation for resolution was proposed as a linear form, $R\;=\;a{\rho}\;+\;bF\;+\;c$.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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• pp.709-712
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• 2017

극저온 액체 질소가 초임계 상태에서 분사될 때 역광기법(backlight method)을 이용하여 사진을 얻었다. 이 때, 유체의 온도를 함께 측정하였고, 이를 바탕으로 가짜 감압비등이라는 새로운 분열기구를 제안하고자 하였으나, 역광기법은 정성적인 분무의 외관은 보여주지만 분사되는 유체의 큰 밀도로 인하여 밀도 변화를 보여줄 수 없었다.

• KSBB Journal
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• 제19권6호
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• pp.421-426
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• 2004

토종콩으로부터 비배당체 이소플라본을 추출하기 위한 다양한 기계적 및 화학적 방법을 적용하였다. 용매추출법의 침적과 교반, 초음파에너지와 아임계/초임계 수 추출이 포함되었다. 용매의 조성에 의한 추출효율의 증가, 교반에 의한 특정성분의 추출효과의 증대, 초음파에너지에 의한 추출성능의 개선, 용매보다 용해력이 좋은 초임계유체의 적용에 관한 실험을 수행한 결과에 의하면 비배당체 이소플라본의 추출은 초음파에너지에 의한 것이 가장 우수하였다.

• EDISON SW 활용 경진대회 논문집
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• 제2회(2013년)
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• pp.343-348
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• 2013

초임계 익형은 천음속 영역에서 비행하는 상업용 민간 항공기와 전투기 날개의 공력성능을 향상시키기 위해 Whitcomb R. T.가 제안 하였다. 초임계 익형은 상부표면을 평평하게 디자인하여 임계마하수보다 큰 마하수에서 나타나는 익형 주위의 충격파 출현을 지연시킴으로써 항력을 줄일 수 있고, 상부 표면의 평면 설계로 인한 양력 감소를 보정하기 위하여 하부 표면의 꼬리부분에 캠버가 있는 형상을 하고 있다. 본 연구에서는 EDISON CFD를 이용하여, 초임계 익형의 공력특성을 해석하고 Xfoil의 data와 비교 분석하였다. 또한, 초임계 익형의 형상을 변경하여 두께와 뒷전 캠버가 다른 초임계 익형을 설계하였다. 새로운 초임계 익형의 형상은 상용 프로그램 Maple12을 이용하여 Whitcomb Integral Supercritical Airfoil의 형상을 수정하여 구할 수 있다. 초임계 익형 주위의 유동을 2D압축성 유동으로 가정하고 EDISON CFD의 2D_Comp-2.0 솔버를 사용하여 수치해석을 수행하였다.