• Title/Summary/Keyword: Supercritical Conditions

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RESEARCH ACTIVITIES ON A SUPERCRITICAL PRESSURE WATER REACTOR IN KOREA

  • Bae, Yoon-Yeong;Jang, Jin-Sung;Kim, Hwan-Yeol;Yoon, Han-Young;Kang, Han-Ok;Bae, Kang-Mok
    • Nuclear Engineering and Technology
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    • v.39 no.4
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    • pp.273-286
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    • 2007
  • This paper presents the research activities performed to date for the development of a supercritical pressure water-cooled reactor (SCWR) in Korea. The research areas include a conceptual design of an SCWR with an internal flow recirculation, a reactor core conceptual design, a heat transfer test with supercritical $CO_2$, an adaptation of an existing safety analysis code to the supercritical pressure condition, and an evaluation of candidate materials through a corrosion study. Methods to reduce the cladding temperature are introduced from two different perspectives, namely, thermal-hydraulics and core neutronics. Briefly described are the results of an experiment on the heat transfer at a supercritical pressure, an experiment that is essential for the analysis of the subchannels of fuel assemblies and the analysis of a system safety. An existing system code has been adapted to SCWR conditions, and the process of a first-hand validation is presented. Finally, the corrosion test results of the candidate materials for an SCWR are introduced.

Aerodynamic Performance Improvement by Divergent Trailing Edge Modification to a Supercritical Airfoil

  • Yoo, Neung-Soo
    • Journal of Mechanical Science and Technology
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    • v.15 no.10
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    • pp.1434-1441
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    • 2001
  • A computational study has been performed to determine the effects of divergent trailing edge (DTE) modification to a supercritical airfoil in transonic flow field. For this, the computational result with the original DLBA 186 supercritical airfoil was compared to that of the modified DLBA 283. A wavier-Stokes code, Fluent 5. 1, was used with Spalart-Allmaras's one-equation turbulence model. Results in this study showed that the reduction in drag due to the DTE modification is associated with weakened shock and delayed shock appearance. The decrease in drag due to the DTE modification is greater than the increase in base drag. The effect of the recirculating flow region on lift increase was also observed. An airfoil with DTE modification achieved the same lift coefficient at a lower angle of attack while giving a lower drag coefficient. Thus, the lift-to-drag ratio increases in transonic flow conditions compared to the original airfoil. The lift coefficient increases considerably whereas the lift slope increases just a little due to DTE modification.

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Saccharification of lignocellulosics by Supercritical Water (초임계수를 이용한 목질바이오매스의 당화 특성)

  • Choi, Joon-Weon;Lim, Hyun-Jin;Jo, Tae-Su;Han, Gyu-Sung;Choi, Don-Ha
    • New & Renewable Energy
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    • v.3 no.1 s.9
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    • pp.38-45
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    • 2007
  • To characterize thermo-chemical feature of sugar conversion of woody biomass, poplar wood ($Populus\;alba{\times}glandulosa$) powder was treated with supercritical water system. Supercritical water treatment (SCWT) was performed for 60 seconds at different temperatures (subcritical zone 350; supercritical zone $300,\;400,\;425^{\circ}C$) under two pressures $230{\pm}10atm$ as well as $330{\pm}10atm$, respectively, using flow type system. After separation of solid residues from SCWT products, the monomeric sugars in aqueous part converted from poplar wood powder were quantitatively determined by high performance anionic exchange chromatography [HPAEC] equipped with PAD detector and Carbo Pac PA10 column. As the temperature treated increased, the degradation of poplar wood powder was enhanced and ca 83% of woody biomass was dissolved into the water at $425^{\circ}C$. However, the pressure didn't help the degradation of biomass components. At subcritical temperature range, xylose was first formed by degradation of xylan, which is main hemicellulose component in hardwood species, while cellulose degradation started at the transition zone between sub and supercritical conditions and was remarkably accelerated at the supercritical temperature. In the supercritical water system the maximum yield of monomeric sugars amounts to ca. 7.3% based on oven dried wood weight at $425^{\circ}C$.

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Antimicrobial, Antioxidative, Elastase and Tyrosinase Inhibitory Effect of Supercritical and Hydrothermal Asparagopsis Armata Extract

  • Lee, Kwang Won;Heo, Soo Hyeon;Lee, Jinseo;Park, Su In;Kim, Miok;Shin, Moon Sam
    • International Journal of Advanced Culture Technology
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    • v.8 no.3
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    • pp.231-240
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    • 2020
  • In this paper, we present to evaluate physiological activity of Asparagopsis armata extraction. After extraction with Asparagopsis armata using hydrothermal and supercritical carbon dioxide, various physiological activities were examined. The total concentration of polyphenol compounds was determined to be 18.85 mg/g of hydrothermal Asparagopsis armata extraction and 14.74 mg/g of supercritical Asparagopsis armata extraction. In DPPH radical scavenging assay, ascorbic acid was used as positive antioxidant control. In ABTS radical scavenging assay, ascorbic acid was used as positive antioxidant control. The percentage of inhibition and IC50 were measured. The IC50 of Asparagopsis armata extraction is 261.44ppm and the IC50 of supercritical Asparagopsis armata extraction is 153.98 ppm. The elastase inhibitory assay showed concentration dependence and the IC50 of hydrothermal Asparagopsis armata extraction is 3387 ppm and the IC50 of supercritical Asparagopsis armata extraction is higher than 2500 ppm. In mushroom tyrosinase inhibition experiments, tyrosinase inhibition's IC50 of supercritical Asparagopsis armata extraction was 248.06. In the SOD-like experiments, the concentration-dependent results were showed and IC50 of hydrothermal Asparagopsis armata extraction is 845.29 ppm. In the antimicrobial experiments, maximum clear zones of supercritical Asparagopsis armata extraction represented 23.00 mm in Propionibacterium acnes. In the other hand, in experiments with the same conditions, hydrothermal Asparagopsis armata extraction had no effect in all strains.

Dynamic Numerical Modeling for LOx Swirl Injector at Supercritical Conditions (초임계 상태에서의 LOx 스월 인젝터에 대한 동적 수치 모델링)

  • Kim, Kuk-Jin;Heo, Jun-Young;Kim, Jong-Chan;Sung, Hong-Gye
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.42-46
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    • 2009
  • For understanding of high performance liquid rocket engine operating at high pressure, dynamic characteristics of liquid oxygen in a swirl injector operating at supercritical conditions has been numerically investigated. Turbulent numerical model is based on large eddy simulation and contains full conservation laws including Soave modification of Redlich-Kwong equation of state and Chung's model. Preconditioning method is applied to get an effective convergence rate. Numerical analysis results are compared with the one that ideal equation of state applied to. Differences of thermodynamic properties and mixing dynamics are investigated at liquid phase area inside injector and combustion chamber.

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Process conditions of valuable compound for benign prostatic hyperplasia(BPH) from saw palmitto by supercritical CO2 (초임계 CO2를 이용한 Saw palmitto로부터 전립선 비대 유효 성분의 추출 조건)

  • 류병호;조경자
    • Journal of Life Science
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    • v.13 no.5
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    • pp.569-575
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    • 2003
  • Supercritical $CO_2$ extraction was applied to extraction of the valuable compound for benign prostatic hyperplasia from saw palmitto. Three levels of parameters, temperature $(35^{\circ}C,\; 60^<\circ}C)$, pressure 22∼30 Mpa and ethanol modified solvent concentration, were used as the independent variables of central composite to rotate the design. The extracting pressure and temperature interaction was significantly affected the extraction of valuable compounds. The ethanol was an efficient modifier to extract valuable compound by supercritical carbon dioxide. The optimal processing conditions were extracting pressure, 30 Mpa, extracting temperature, $60^<\circ}C$, ethanol modifier, 15% for extracts of the valuable compounds from saw palmitto. In conclusion, it was found that supercritical $CO_2$ extraction can successfully be applied to extract high quality extracts from saw palmitto.

Supercritical Fluid Extraction of Safflower Yellow Pigments from Carthamus tinctorius L. (초임계 이산화탄소를 이용한 홍화로부터 황색소 추출)

  • Han, Byung-Seok;Kim, Kong-Hwan;Chung, In-Sik
    • Applied Biological Chemistry
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    • v.41 no.5
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    • pp.363-366
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    • 1998
  • Supercritical fluid(SCF) carbon dioxide was used to extract safflower yellow pigments from Carthamus tinctorius L. In this work, supercritical fluid extractions were performed at various conditions; pressure (2000, 3000, 4000, 5000 psig), temperature $(40,\;50,\;60,\;70,\;80^{\circ}C)$ and co-solvent $(0,\;3,\;6,\;10,\;14\;wt%\;H_2O)$. Total concentrations of safflower yellow pigments extracted were determined by spectrophotometric method. A maximum yield of yellow pigments was obtained at 4000psig, $60^{\circ}C$ and 10% co-solvent. The extraction yield of pigments was also closely related to moisture content of the raw material. Extraction yield of safflower yellow pigments by SCF extraction at optimized conditions was 6% higher than that by solvent extraction. Supercritical carbon dioxide was proved to be suitable for the extraction of safflower yellow pigments from Carthamus tinctorius L.

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Processing of Protein Concentrate and Fatty Acid Extraction from Tuna Viscera using Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 가다랑어 내장으로부터 지방산 추출 및 단백질 농축물의 제조)

  • CHUN Byung-Soo;YOON Sung-Ok;LEE Seung-Jin
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.3
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    • pp.207-212
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    • 2001
  • Supercritical fluid extraction was explored as a method for removing lipids and bad odor from tuna viscera. Selected conditions of extraction pressure, time, temperature and sample size were evaluated for effective removal of lipids and bad odor, Supercritical carbon dioxide was used as a solvent and the extraction was performed at semi-batch flow type. The experimental conditions used in this work was the range of pressure from 1,500 psig to 2,000 psig, the temperature from $25^{\circ}C\;to\;40^{\circ}C$ and dried sample size from 0.2 mm to 1.0 mm. The main fatty acids extracted from tuna viscera were palmitic acid (16: 0) heptadecenoic acid (17: 1) oleic acid (18: 1) and docosahexaenoic acid (22: 6). Protein concentrate was obtained without deformation the optimum condition at $35^{\circ}C$, 1,800 psig and 0.25 mm of the size. In the concentrate after supercritical carbon dioxide extraction, the major amino acids were glutamic acid, leucine and lysine.

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High-pressure rheology of polymer melts containing supercritical carbon dioxide

  • Lee Sang-Myung;Han Jae-Ro;Kim Kyung-Yl;Ahn Young-Joon;Lee Jae-Wook
    • Korea-Australia Rheology Journal
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    • v.18 no.2
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    • pp.83-90
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    • 2006
  • Supercritical carbon dioxide ($scCO_2$) has advantages of being incorporated in polymer with high solubility and of being recovered easily by depressurizing. $scCO_2$ reduces the viscosity of polymer melt and it is expected to be use as a plasticizing agent. In this work, we studied on the effect of $scCO_2$ on the rheological properties of polymer melts during extrusion process. Slit die attached to twin screw extruder was used to measure the viscosity of polymer melts plasticized by supercritical $CO_2$. A gas injection system was devised to accurately meter the supercritical $CO_2$ into the extruder barrel. Measurements of pressure drop within the die, confirmed the presence of a one phase mixture and a fully developed flow during the measurements. The viscosity measurement of polypropylene was performed at experimental conditions of various temperatures, pressures and $CO_2$ concentrations. We observed that melt viscosity of polymer was dramatically reduced by $CO_2$ addition.

Coffee Deodorization with Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 커피의 탈취)

  • Lee, Joo-Hee;Kim, Hyung-Bae;Byun, Sang-Yo
    • KSBB Journal
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    • v.22 no.5
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    • pp.336-340
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    • 2007
  • Supercritical carbon dioxide was used to remove coffee odors. The odor removal efficiency was tested with coffee drink prepared by the espresso extraction method. Five typical odors in coffee were analyzed with GC and these odors in deodorized coffee were compared to those in control. Supercritical carbon dioxide extraction conditions were optimized as 350 bar and 70$^{\circ}C$ because the solvating power of supercritical fluid is depend on the density which is determined by temperature and pressure. A modified head space method was applied to collect coffee odors in coffee drink prepared by the espresso extraction method. Odors generated in coffee drink made with deodorized coffee powder were reduced by 73% in total mass of typical five coffee odors.