• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.597-600
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• 2010

Cold flow injection test was conducted to investigate the characteristics of cryogenic liquid nitrogen jet at sub to supercritical condition. Single jet injector element was installed in high pressure chamber to investigate the effect of ambient pressure around the jet, injector geometry and flow conditions. Experimental results showed obvious differences between jet characteristics under subcritical and supercritical condition. Effect of injector inlet shape also was investigated.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.3
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• pp.152-160
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• 2013

The purpose of this study is to enhance the mechanical strength of specimens containing fly ash from fluidized bed type boiler, which the recycling rate will be eventually increased. Specimens containing fly ash in a certain portion were made and aged for 3, 14, and 28 days. Specimens were carbonated under the supercritical condition at $40^{\circ}C$. The carbonation process under the supercritical condition was performed to enhance the mechanical property of specimens by filling the voids and cracks existing inside cement specimen with $CaCO_3$ reactants. The additional aging effect after the supercritical carbonation process on mechanical strength of specimens was also investigated by comparing the compressive strength with and without 7 day extra aging. Under the supercritical condition and additional 7 day aging specimens were very effective for enhancement of mechanical strength and compressive strength increased by 44 %.

• Nuclear Engineering and Technology
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• v.49 no.1
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• pp.103-112
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• 2017

Application of the supercritical condition in reactor core cooling needs to be properly justified based on the extreme level of parameters involved. Therefore, a numerical study is presented to compare the thermalhydraulic performance of supercritical and single-phase natural circulation loops under low-to-intermediate power levels. Carbon dioxide and water are selected as respective working fluids, operating under an identical set of conditions. Accordingly, a three-dimensional computational model was developed, and solved with an appropriate turbulence model and equations of state. Large asymmetry in velocity and temperature profiles was observed in a single cross section due to local buoyancy effect, which is more prominent for supercritical fluids. Mass flow rate in a supercritical loop increases with power until a maximum is reached, which subsequently corresponds to a rapid deterioration in heat transfer coefficient. That can be identified as the limit of operation for such loops to avoid a high temperature, and therefore, the use of a supercritical loop is suggested only until the appearance of such maxima. Flow-induced heat transfer deterioration can be delayed by increasing system pressure or lowering sink temperature. Bulk temperature level throughout the loop with water as working fluid is higher than supercritical carbon dioxide. This is until the heat transfer deterioration, and hence the use of a single-phase loop is prescribed beyond that limit.

• Journal of the Korean Ceramic Society
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• v.37 no.7
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• pp.625-631
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• 2000

In this study, the characteristics and sinterablities of TiO2 powders which were fabricated on sol-gel process and supercritical fluid process were examined. The powders fabricated on sol-gel process were amorphous. The particle size and shape were changed with the amount of water used for hydrolysis of titanium ethoxide. The powders were changed from amorphous to crystalline by heating at 400℃. The crystalline anatase TiO2 powders were directly prepared in ethanol supercritical fluid condition that temperature was 270±3℃ and pressure was 7.3 MPa. It's primary crystalline size was 20 nm and agglomerated as spherical shape whose size was 0.7∼1㎛. The powders prepared on sol-gel process were not sintered densely at 900℃ because of abnormal grain growth. However, the powders which prepared on supercritical fluid process were sintered densely at the comparatively low temperature of 800℃ by ideal growth of grain, which are fired at 900℃.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.803-810
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• 2017

the liquid oxygen transitions to a supercritical state, causing rapid changes in properties and pseudo boiling in supercritical combustion. the combustion reaction operating in a supercritical state depends on the turbulence diffusion caused by difference of density, therefore, a study of the diffusion flow and pseudo boiling is required. Many researchers have studied these phenomena in the supercritical combustion, but A case study by various variables is inadequate. In this study, the flow field and flame structure were investigated numerically by changing the recirculation flow and liquid oxygen core length through oxygen-fuel ratio(O/F), combustor diameter and recess ratio at supercritical pressure condition.

• International Journal of Aeronautical and Space Sciences
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• v.16 no.2
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• pp.254-263
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• 2015

In this study, numerical simulations are carried out to investigate the dynamic SGS model effects in a Kerosene-LOx coaxial swirl injector under high pressure conditions. The turbulent model is based on large-eddy simulation (LES) with real-fluid transport and thermodynamics. To assess the effect of the dynamic subgrid-scale (SGS) model, the dynamic SGS model is compared with that of the algebraic SGS model. In a swirl injector under supercritical pressure, the characteristics of temporal pressure fluctuation and power spectral density (PSD) present comparable discrepancies dependant on the SGS models, which affect the mixing characteristics. Mixing efficiency and the probability density (PDF) function are conducted for a statistical description of the turbulent flow fields according to the SGS models. The back-scattering of turbulent kinetic energy is estimated in terms of the film thickness of the swirl injector.

• Journal of ILASS-Korea
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• v.9 no.3
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• pp.8-14
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• 2004

Characteristics of droplet vaporization at high ambient pressures and temperatures which are supercritical conditions is studied numerically by formulating one dimensional vaporization model in liquid dodecane and air. Modified Soave-Redlich-Kwong state equation is used to condider real gas effect. Non-ideal behavior of properties at near critical and supercritical conditions is considered in the high pressure condition. Characteristic spatial distribution of properties with various conditions of pressure and temperature is evaluated in order to understand vaporizing evolution.

• Clean Technology
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• v.10 no.4
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• pp.215-220
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• 2004

Micronized acetaminophen was precipitated from ethanol solution using supercritical $CO_2$ as antisolvent. A coaxial nozzle was used to introduce the supercritical $CO_2$ and the acetaminophen/ethanol solution. The effects of pressure, temperature, $CO_2$ flow rate and solvent flow rate were studied in the constant pressure and temperature condition. The particle size and morphology were influenced by the variations of precipitation condition. The particle size and morphology were analyzed with scanning electron microscopy.

• Journal of Environmental Science International
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• v.14 no.5
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• pp.513-520
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• 2005

For the destruction of toxic chlorinated organic compounds, this study proposes improved supercritical water oxidation method (multistep oxidation) using sodium nitrate as an oxidizer. This method solves the problems involved in the existing supercritical water oxidation method. Multistep oxidation means that $NaNO_3$ is oxidized to $N_2\;via\;NaNO_2$ and NO. Toxic and hard to destroy organic substances like para-dichlorobenzen(4-DCBz), polychlorinate biphenyl(PCB) ware oxidized to non toxic substances in a condition, in which rapid pressure and temperature rise is restrained as much as possible. 4-dichlorobenzene(4-DCBz) and Polychlorinate biphenyl(PCB) in condition$(450^{\circ}C,\;p_w=0.25g/cm^3,\;30min)$ Was discomposed perfectly.

• Journal of Powder Materials
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• v.21 no.6
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• pp.407-414
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• 2014

The powder injection molding process having advantages in manufacturing three-dimensional precision parts essentially requires a debinding process before sintering to remove the binders used for preparing feedstock. In this study, powder injection molding of translucent alumina was performed, and carbon dioxide ($CO_2$) is used as a supercritical fluid that makes it possible to remove a large amount of binder, which is paraffin wax. The relationship between the optical property of translucent alumina and the debinding condition (temperature and pressure) of supercritical $CO_2$ was investigated. As temperature and pressure increased, extraction rate of the binder showed rising tendency and average grain size after sintering process was relatively fine. On the other hand, optical transmittance was reduced. As a result, the debinding condition at $50^{\circ}C$ and 20 MPa that represents the lowest extraction rate, $8.19{\times}10^{-3}m^2/sec$, corresponds to the largest grain size of $14.7{\mu}m$ and the highest optical transmittance of 45.2%.