• 제목/요약/키워드: Superconducting critical temperature

검색결과 382건 처리시간 0.024초

세라믹 YBaCuO계 초전도 선재의 제조 (The Preparation of Ceramic YBaCuO System Superconducting wire)

  • 박성진;한태희;한병성;김양수
    • 대한전기학회논문지
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    • 제40권9호
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    • pp.908-912
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    • 1991
  • YBaCuO oxide superconductor-shows superconductive at Liquid Nitrogen temperature-must be preparate wire or thin film form for utility. The wiring is possible with heat treatment after appropriate mixture of polymeric binder and YBaCuO oxide superconductor has fabricated. This study, analyzed the characteristics of fabricated superconductor and extruded wire after application to each of a mixed at different rate in the superconductor and compared with an original pure sample. From the result, we knew that the binder component influences superconducting characteristics. The best condition for superconductivity occurred at a criticla temperature of 86.4K (8:2 rate) and at a critical current density of 100.27A/cmy with a binder packing ratio of about 20~25 percent.

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Crystal growth and pinning enhancement of directionally melt-textured$(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_2Cu_3O_y$ oxides in air

  • Kim So-Jung
    • 한국결정성장학회지
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    • 제15권5호
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    • pp.188-192
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    • 2005
  • High $T_c(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_2Cu_3O_y[(YNS)-123]$ superconductors with/without $CeO_2$ additive were systematically investigated by the zone melt growth process in air. Cylindrical green rods of (YNS)-123 oxides were fabricated by cold isostatic pressing (CIP) method using rubber mould. A sample prepared by this method showed well-textured microstructure, and $(Y_{0.5}Nd_{0.25}Sm_{0.25})_2BaCuO_5[(YNS)211]$ nonsuperconducting inclusions were uniformly dispersed in large $(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_2Cu_3O_y$[(YNS)123] superconducting matrix. In this study, optimum melting temperature and growth rate were $1100^{\circ}C$ and 3 mm/hr, respectively. The directionally melt-textured (YNS)-123 sample with $CeO_2$ additive showed an onset critical temperature $(T_c)\;T_c{\geq}93K$ and sharp superconducting transition.

Bi계 산화물 초전도체 2212상에 있어서 Bi 자리에 Ge 치환에 따른 초전도 특성 (Superconducting Properties of Ge Substitution for the Bi Site in the 2212 Phase of Bi-Sr-Ca-Cu-O Superconductors)

  • 신재수;이민수;최봉수;송승용;송기영
    • 한국세라믹학회지
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    • 제37권8호
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    • pp.787-791
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    • 2000
  • Samples with the nominal composition, Bi2-xGexSr2CaCu2O8+$\delta$ (x=0, 0.1, 0.2, 0.3, 0.4, 0.5) were prepared by the solid-state reaction method. We have studied the effect of substitution Ge for Bi and investigated the superconducting properties by changing oxygen content with Ge substitution. It was found that temperature difference, ΔK, between TCon and TCzero was considerably smaller in the samples prepared by the intermediate pressing method than that in the samples by the solid-state reaction method. We found the solubility limit of Ge to the 80 K single phase was around x=0.3. Within the solubility limit, lattice constant c decreased with the increase of x. In the region of the 80K single phase, the onset critical temperature TCon increased and excess oxygen content decreased with increase of x.

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Bi-(Pb)-Sr-Ca-Cu-O계 초전도체의 Sb 첨가 효과 (Effect of Sb doppd in Bi-Pb-Sr-Ca-O Superconductor)

  • 한태희;김민기;최성환;최효상;황종선
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1992년도 춘계학술대회 논문집
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    • pp.64-69
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    • 1992
  • Bi-Sr-Ca-Cu-O superconducting system have the low and high Tc phases. In order to get the superconductor above crtitical temperature 100K, we added with Pb and sintered for a long time about 200 hrs. In this study, the influence of superconducting characteristics on the Bi(Pb)SrCaCuO system characteristics on the Bi(Pb)SrCaCuO system dopped Sb was investigate too. Adding Sb of 0.1 mol, the sintering time is short than that dopped Pb only. We could get the critical temperature 102 K at sintered for 24 hrs and 109 K for 210 hrs.

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에멀젼 건조법에 의한 Bi-2223 초전도 분말과 테이프 제조 (The Preparation of Bi-2223 Superconducting Powder and Tape by Emulsion Drying Method)

  • 장중철;이응상;이희균;홍계원
    • 한국세라믹학회지
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    • 제34권2호
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    • pp.115-122
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    • 1997
  • 액상 분말 합성법 중의 하나인 에멀젼 건조 방법에 의한 분말 합성은 조성 조절이 용이하고 균질한 미립자 분말을 제조할 수 있는 장점을 지니고 있다. 에멀젼 건조법을 사용하여 합성 분체의 초기 형상과 입도를 제어하고 근본적으로 더욱 개선된 homogeneity를 얻었다. 에멀젼의 분리를 억제시킬 수 있는 계면활성제, 오일상 및 수용액의 혼합비를 조절함으로써 Bi(Pb)-Sr-Ca-Cu-O 초전도 분말을 제조할 수 있었다. 이 방법에 의하여 합성된 산화물 초전도체 분말의 특성 및 pellet으로 성형한 시편을 열처리하여 미세구조와 전기적 특성을 조사하였다. 또한, OPIT(Oxide Powder-in-tube)법에 의해 테이프를 제작하여 미세구조와 전기적 특성을 관찰하였다. 합성된 분말의 입자크기는 1$\mu$m이하의 구형이었으나 대부분이 2~5$\mu$m크기로 응집되어 있었다. Ar분위기의 1/13atm 산소분압(Po2)에서 84$0^{\circ}C$로 72시간 동안 열처리한 덩어리형 시편의 임계저항온도는 108K이었으며, 1차와 2차 열처리한 테이프의 임계전류는 각각 0.4A와 1.5A이었다.

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상온상압 초전도체(LK-99) 개발을 위한 고찰 (Consideration for the development of room-temperature ambient-pressure superconductor (LK-99))

  • 이석배;김지훈;임성연;안수민;권영완;오근호
    • 한국결정성장학회지
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    • 제33권2호
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    • pp.61-70
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    • 2023
  • 이 논문에서는 기존의 초전도 현상을 바라보는 물리학자들의 생각의 흐름과 한계들을 살펴보고, 통계 열역학적 액체론의 관점에서 제시한 이론적 배경을 통해 상온 상압 초전도체가 개발될 수 있음을 약술하였다. 이것이 가능 할 방안은, 전자들이 돌아다닐 수 있는 상태수가 현저히 제한되는 1-Dimension에 가까운 전자 상태이어야 한다는 것과 그 상태에 있는 전자들이 액체적 특성이 나타날 수 있을 정도로 전자-전자 상호작용이 빈번한 상태이어야 한다는 것이다. 이러한 실행 예로서 우연한 기회에 실마리를 얻어 수많은 실험으로 구조를 밝혀낸 LK-99(본 연구에서 개발한 상온 상압 초전도체의 이름)의 개발 자료를 보고하며, 이에 세계 최초로 상압에서 임계온도가 97℃를 능가하는 초전도 물질의 특성과 발견에 대한 이론적, 실험적 근거를 요약하였다.

용융온도와 유지시간이 용융법으로 제작한 고온초전도체의 임계특성에 미치는 영향 (The Effects of Melting Temperature and Holding Time on Critical Characteristics of HTSC Fabricated by Melting Method)

  • 임성훈;한태희;박경국;임성우;조동언;한병성
    • 한국전기전자재료학회논문지
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    • 제11권2호
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    • pp.154-161
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    • 1998
  • The effects of melting temperature and holding time on the critical current density($J_c$) of $YBa_2Cu_3O_x$ based superconducting bulk fabricated by MPMG process were investigated. The amount of the formed $Y_2BaCuO_5$ phases increased with the melting temperature. However, the value of critical current density was highest at 1120 $^{\circ}C$. With this proper melting temperature, the effect of holding time on the critical characteristics was also investigated. In the case of Ag addition, the volume of the formed $Y_2BaCuO_5$ phase when the amount of Ag addition was 10 wt% and 20 wt% was observed to be highest at 20 minute and 40 minute respectively. But in the specimen without Ag, volume of $Y_2BaCuO_5$ phase increased as the holding time increased. The proper melting temperature and the holding time obtained were 1120 $^{\circ}C$ and 20 minute. The long holding time was not effective for the $J_c$ improvement as well as the formation of $Y_2BaCuO_5$.

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Synthesis and Structural Properties of YBa2Cu3O7-x Films/ZnO Nanorods on SrTiO3 Substrates

  • Jin, Zhenlan;Park, C.I.;Song, K.J.;Han, S.W.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.169-169
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    • 2012
  • The high-temperature superconductor YBa2Cu3O7-x (YBCO) have attached attentions because of a high superconducting transition temperature, low surface resistance, high superconducting critical current density (Jc), and superior superconducting capability under magnetic field. Moreover, the Jc of YBCO superconductors can be enhanced by adding impurities to the YBCO films for vortex-pinning. Understanding and controlling pinning centers are key factors to realize high Jc superconductors. We synthesized vertically-aligned ZnO nanorods on SrTiO3 (STO) substrates by catalyst-free metal-organic chemical vapor deposition (MOCVD), and subsequently, deposited YBCO films on the ZnO nanorods/STO templates using pulsed laser deposition (PLD). The various techniques were used to analyze the structural and interfacial properties of the YBCO/ZnO nanorods/STO hybrid structures. SEM, TEM, and XRD measurements demonstrated that YBCO films on ZnO nanorods/STO were well crystallized with the (001) orientation. EXAFS measurements from YBCO/ZnO nanorods/STO at Cu K edge demonstrated that the local structural properties around Cu atoms in YBCO were quite similar to those of YBCO/STO.

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고온초전도 마이크로스트립 안테나의 온도 종속 초고주파 특성 (Microwave Properties of High Tc Superconducting Microstrip Antenna with Temperature Dependence)

  • 정동철;최명호;강형곤;임성훈;한병성
    • 한국초전도학회:학술대회논문집
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    • 한국초전도학회 1999년도 High Temperature Superconductivity Vol.IX
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    • pp.124-128
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    • 1999
  • We report microwave properties of high-T$_c$ superconducting (HTS) microstrip antennas without impedance matching circuits, where the impedance mismatching is obvious under the critical temperature (T$_c$). The superconducting thin films used in this report were YBa$_2Cu_3O_{7-x}$ (YBCO) films deposited on MgO substrates produced by pulse laser deposition (PLD) technique. At around T$_c$, 86 K the reflection coefficient rapidly drops, and the standing wave ratio (SWR) becomes almost unity, and the characteristic impedance based on the Smith chart is nearly 50 ${\Omega}$. The reflection coefficient and the SWR of the HTS microstrip antenna were - 62.52 dB and 1.0015, respectively, at the resonant frequency of 11.812 CHz at 86 K.

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Iron Core Design of 3-Phase 40MVA HTS Power Transformer Considering Voltages per Turn

  • Lee, Chan-joo;Seok, Bok-yeol
    • KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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    • 제4B권2호
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    • pp.54-58
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    • 2004
  • This paper presents the iron core design method of a high temperature superconducting (HTS) transformer considering voltages per turn (V/T). In this research, solenoid type HTS coils were selected for low voltage (LV) winding and double pancake coils for high voltage (HV) winding, just as in conventional large power transformers. V/T is one of the most fundamental elements used in designing transformers, as it decides the core cross sectional area and the number of primary and secondary winding turns. By controlling the V/T, the core dimension and core loss can be changed diversely. The leakage flux is another serious consideration in core design. The magnetic field perpendicular to the HTS wire causes its critical current to fall rapidly as the magnitude of the field increases slowly. Therefore in the design of iron core as well as superconducting windings, contemplation of leakage flux should be preceded. In this paper, the relationship between the V/T and core loss was observed and also, through computational calculations, the leakage magnetic fields perpendicular to the windings were found and their critical current decrement effects were considered in relation to the core design. The % impedance was calculated by way of the numerical method. Finally, various models were suggested.